scholarly journals The contribution of oceanic halocarbons to marine and free tropospheric air over the tropical West Pacific

2016 ◽  
Vol 16 (12) ◽  
pp. 7569-7585 ◽  
Author(s):  
Steffen Fuhlbrügge ◽  
Birgit Quack ◽  
Susann Tegtmeier ◽  
Elliot Atlas ◽  
Helmke Hepach ◽  
...  
Keyword(s):  
Methyl Iodide ◽  
South China ◽  
Stratospheric Ozone ◽  
Tropical Region ◽  
West Pacific ◽  
Mixing Ratios ◽  
Source Regions ◽  
Strong Source ◽  
Oceanic Emissions ◽  
Sea Area

Abstract. Emissions of halogenated very-short-lived substances (VSLSs) from the oceans contribute to the atmospheric halogen budget and affect tropospheric and stratospheric ozone. Here, we investigate the contribution of natural oceanic VSLS emissions to the marine atmospheric boundary layer (MABL) and their transport into the free troposphere (FT) over the tropical West Pacific. The study concentrates on bromoform, dibromomethane and methyl iodide measured on ship and aircraft during the SHIVA (Stratospheric Ozone: Halogen Impacts in a Varying Atmosphere) campaign in the South China and Sulu seas in November 2011. Elevated oceanic concentrations for bromoform, dibromomethane and methyl iodide of on average 19.9, 5.0 and 3.8 pmol L−1, in particular close to Singapore and to the coast of Borneo, with high corresponding oceanic emissions of 1486, 405 and 433 pmol m−2 h−1 respectively, characterise this tropical region as a strong source of these compounds. Atmospheric mixing ratios in the MABL were unexpectedly relatively low with 2.08, 1.17 and 0.39 ppt for bromoform, dibromomethane and methyl iodide. We use meteorological and chemical ship and aircraft observations, FLEXPART trajectory calculations and source-loss estimates to identify the oceanic VSLS contribution to the MABL and to the FT. Our results show that the well-ventilated MABL and intense convection led to the low atmospheric mixing ratios in the MABL despite the high oceanic emissions. Up to 45 % of the accumulated bromoform in the FT above the region originates from the local South China Sea area, while dibromomethane is largely advected from distant source regions and the local ocean only contributes 20 %. The accumulated methyl iodide in the FT is higher than can be explained with local contributions. Possible reasons, uncertainties and consequences of our observations and model estimates are discussed.

scholarly journals The contribution of oceanic halocarbons to marine and free troposphere air over the tropical West Pacific

2015 ◽  
Vol 15 (13) ◽  
pp. 17887-17943 ◽  
Author(s):  
S. Fuhlbrügge ◽  
B. Quack ◽  
S. Tegtmeier ◽  
E. Atlas ◽  
H. Hepach ◽  
...  
Keyword(s):  
Methyl Iodide ◽  
South China ◽  
Stratospheric Ozone ◽  
Tropical Region ◽  
Free Troposphere ◽  
The South ◽  
West Pacific ◽  
Mixing Ratios ◽  
Strong Source ◽  
Oceanic Emissions

Abstract. Emissions of halogenated very short lived substances (VSLS) from the tropical oceans contribute to the atmospheric halogen budget and affect tropospheric and stratospheric ozone. Here we investigate the contribution of natural oceanic VSLS emissions to the Marine Atmospheric Boundary Layer (MABL) and their transport into the Free Troposphere (FT) over the tropical West Pacific. The study concentrates in particular on ship and aircraft measurements of the VSLS bromoform, dibromomethane and methyl iodide and meteorological parameters during the SHIVA (Stratospheric Ozone: Halogen Impacts in a Varying Atmosphere) campaign in the South China and Sulu Seas in November 2011. Elevated oceanic concentrations of 19.9 (2.80–136.91) pmol L−1 for bromoform, 5.0 (2.43–21.82) pmol L−1 for dibromomethane and 3.8 (0.55–18.83) pmol L−1 for methyl iodide in particular close to Singapore and at the coast of Borneo with high corresponding oceanic emissions of 1486 ± 1718 pmol m−2 h−1 for bromoform, 405 ± 349 pmol m−2 h−1 for dibromomethane and 433 ± 482 pmol m−2 h−1 for methyl iodide characterize this tropical region as a strong source of these compounds. Unexpectedly atmospheric mixing ratios in the MABL were relatively low with 2.08 ± 2.08 ppt for bromoform, 1.17 ± 1.17 ppt for dibromomethane and 0.39 ± 0.09 ppt for methyl iodide. We use meteorological and chemical ship and aircraft observations, FLEXPART trajectory calculations and source-loss estimates to identify the oceanic VSLS contribution to the MABL and to the FT. Our results show that a convective, well-ventilated MABL and intense convection led to the low atmospheric mixing ratios in the MABL despite the high oceanic emissions in coastal areas of the South-China and Sulu Seas. While the accumulated bromoform in the FT above the region origins almost entirely from the local South China Sea area, dibromomethane is largely advected from distant source regions. The accumulated FT mixing ratio of methyl iodide is higher than can be explained with the local oceanic or MABL contributions. Possible reasons, uncertainties and consequences of our observations and model estimates are discussed.

scholarly journals Importance of seasonally resolved oceanic emissions for bromoform delivery from the tropical Indian Ocean and west Pacific to the stratosphere

2018 ◽  
Vol 18 (16) ◽  
pp. 11973-11990 ◽  
Author(s):  
Alina Fiehn ◽  
Birgit Quack ◽  
Irene Stemmler ◽  
Franziska Ziska ◽  
Kirstin Krüger
Keyword(s):  
Indian Ocean ◽  
Summer Monsoon ◽  
Tropical Indian Ocean ◽  
Boreal Summer ◽  
Boreal Winter ◽  
The West ◽  
West Pacific ◽  
Mixing Ratios ◽  
The Indian Ocean ◽  
Oceanic Emissions

Abstract. Oceanic very short-lived substances (VSLSs), such as bromoform (CHBr3), contribute to stratospheric halogen loading and, thus, to ozone depletion. However, the amount, timing, and region of bromine delivery to the stratosphere through one of the main entrance gates, the Indian summer monsoon circulation, are still uncertain. In this study, we created two bromoform emission inventories with monthly resolution for the tropical Indian Ocean and west Pacific based on new in situ bromoform measurements and novel ocean biogeochemistry modeling. The mass transport and atmospheric mixing ratios of bromoform were modeled for the year 2014 with the particle dispersion model FLEXPART driven by ERA-Interim reanalysis. We compare results between two emission scenarios: (1) monthly averaged and (2) annually averaged emissions. Both simulations reproduce the atmospheric distribution of bromoform from ship- and aircraft-based observations in the boundary layer and upper troposphere above the Indian Ocean reasonably well. Using monthly resolved emissions, the main oceanic source regions for the stratosphere include the Arabian Sea and Bay of Bengal in boreal summer and the tropical west Pacific Ocean in boreal winter. The main stratospheric injection in boreal summer occurs over the southern tip of India associated with the high local oceanic sources and strong convection of the summer monsoon. In boreal winter more bromoform is entrained over the west Pacific than over the Indian Ocean. The annually averaged stratospheric injection of bromoform is in the same range whether using monthly averaged or annually averaged emissions in our Lagrangian calculations. However, monthly averaged emissions result in the highest mixing ratios within the Asian monsoon anticyclone in boreal summer and above the central Indian Ocean in boreal winter, while annually averaged emissions display a maximum above the west Indian Ocean in boreal spring. In the Asian summer monsoon anticyclone bromoform atmospheric mixing ratios vary by up to 50 % between using monthly averaged and annually averaged oceanic emissions. Our results underline that the seasonal and regional stratospheric bromine injection from the tropical Indian Ocean and west Pacific critically depend on the seasonality and spatial distribution of the VSLS emissions.

scholarly journals The contribution of oceanic methyl iodide to stratospheric iodine

2013 ◽  
Vol 13 (4) ◽  
pp. 11427-11471 ◽  
Author(s):  
S. Tegtmeier ◽  
K. Krüger ◽  
B. Quack ◽  
E. Atlas ◽  
D. R. Blake ◽  
...  
Keyword(s):  
Methyl Iodide ◽  
Transport Model ◽  
The Other ◽  
Simultaneous Occurrence ◽  
West Pacific ◽  
Tropical Regions ◽  
Convective Systems ◽  
Mixing Ratios ◽  
Tropical Tropopause ◽  
Cold Point

Abstract. We investigate the contribution of oceanic methyl iodide (CH3I) to the stratospheric iodine budget. Based on CH3I measurements during three tropical ship campaigns and the Lagrangian transport model FLEXPART we provide a detailed analysis of CH3I transport from the ocean surface to the cold point in the upper tropical tropopause layer (TTL). While average oceanic emissions differ by less than 50% from campaign to campaign, the measurements show much stronger variations within each campaign. A positive correlation between the oceanic CH3I emissions and the efficiency of CH3I troposphere–stratosphere transport has been identified for some cruise sections. The mechanism of strong horizontal surface winds triggering large emissions on the one hand and being associated with tropical convective systems, such as developing typhoons, on the other hand, could explain the identified correlations. As a result of the simultaneous occurrence of large CH3I emissions and strong vertical uplift, localized maximum mixing ratios of 0.6 ppt CH3I at the cold point have been determined for observed peak emissions during the SHIVA-Sonne campaign in the coastal West Pacific. The other two campaigns give considerable smaller maxima of 0.1 ppt CH3I for the TransBrom campaign in the open West Pacific and 0.03 ppt for emissions from the coastal East Atlantic during the DRIVE campaign. In order to assess the representativeness of the large local mixing ratios we use climatological emission scenarios to derive global upper air estimates of CH3I abundances. The model results are compared to available upper air measurements including data from the recent ATTREX and HIPPO2 aircraft campaigns. In the East Pacific region, the location of the available measurement campaigns in the upper TTL, the comparisons give a good agreement indicating that around 0.01 to 0.02 ppt of CH3I enter the stratosphere. However, other tropical regions, which are subject to stronger convective activity show larger CH3I entrainment, e.g., 0.08 ppt in the West Pacific. The strong variations in the geographical distribution of CH3I entrainment suggest that currently available upper air measurements are not representative of global estimates and further campaigns will be necessary in order to better understand the CH3I contribution to stratospheric iodine.

scholarly journals Importance of seasonally resolved oceanic emissions for bromoform delivery from the tropical Indian Ocean and west Pacific to the stratosphere

2018 ◽  
Author(s):  
Alina Fiehn ◽  
Birgit Quack ◽  
Irene Stemmler ◽  
Franziska Ziska ◽  
Kirstin Krüger
Keyword(s):  
Indian Ocean ◽  
Asian Monsoon ◽  
Tropical Indian Ocean ◽  
Boreal Summer ◽  
Boreal Winter ◽  
The West ◽  
West Pacific ◽  
Mixing Ratios ◽  
The Indian Ocean ◽  
Oceanic Emissions

Abstract. Oceanic very short-lived substances (VSLS), such as bromoform (CHBr3), contribute to stratospheric halogen loading and, thus, to ozone depletion. However, the amount, timing, and region of bromine delivery to the stratosphere through one of the main entrance gates, the Asian monsoon circulation, are still uncertain. In this study, we created two bromoform emission inventories with monthly resolution for the tropical Indian Ocean and west Pacific based on new in situ bromoform measurements and novel ocean biogeochemistry modeling. The mass transport and atmospheric mixing ratios of bromoform were modeled for the year 2014 with the particle dispersion model FLEXPART driven by ERA-Interim reanalysis. We compare results between two emission scenarios: (1) monthly and (2) annually averaged emissions. Both simulations reproduce the atmospheric distribution of bromoform from ship- and aircraft-based observations in the boundary layer and upper troposphere above the Indian Ocean well. Using monthly resolved emissions, main oceanic source regions for the stratosphere include the Arabian Sea and Bay of Bengal in boreal summer and the tropical west Pacific Ocean in boreal winter. The main stratospheric entrainment in boreal summer occurs over the southern tip of India associated with the high local oceanic sources and strong convection of the summer monsoon. In boreal winter more bromoform is entrained over the west Pacific than over the Indian Ocean. The annually averaged stratospheric entrainment of bromoform is in the same range whether using monthly or annually averaged emissions in our Lagrangian calculations. However, monthly averaged emissions result in highest mixing ratios within the Asian monsoon anticyclone in boreal summer and above the central Indian Ocean in boreal winter, while annually averaged emissions display a maximum above the west Indian Ocean in boreal spring. In the Asian summer monsoon anticyclone bromoform atmospheric mixing ratios vary up to 50 % between using monthly and annually averaged oceanic emissions. Our results underline that the seasonal and regional stratospheric bromine entrainment from the tropical Indian Ocean and west Pacific critically depends on the seasonality and spatial distribution of the VSLS emissions.

scholarly journals Meteorological constraints on oceanic halocarbons above the Peruvian upwelling

2016 ◽  
Vol 16 (18) ◽  
pp. 12205-12217 ◽  
Author(s):  
Steffen Fuhlbrügge ◽  
Birgit Quack ◽  
Elliot Atlas ◽  
Alina Fiehn ◽  
Helmke Hepach ◽  
...  
Keyword(s):  
Methyl Iodide ◽  
Coastal Upwelling ◽  
Trace Gases ◽  
Trade Wind ◽  
Atmospheric Conditions ◽  
Mixing Ratios ◽  
Regional Sources ◽  
Oceanic Emissions ◽  
Oceanic Upwelling ◽  
Atmospheric Concentrations

Abstract. During a cruise of R/V METEOR in December 2012 the oceanic sources and emissions of various halogenated trace gases and their mixing ratios in the marine atmospheric boundary layer (MABL) were investigated above the Peruvian upwelling. This study presents novel observations of the three very short lived substances (VSLSs) – bromoform, dibromomethane and methyl iodide – together with high-resolution meteorological measurements, Lagrangian transport and source–loss calculations. Oceanic emissions of bromoform and dibromomethane were relatively low compared to other upwelling regions, while those for methyl iodide were very high. Radiosonde launches during the cruise revealed a low, stable MABL and a distinct trade inversion above acting as strong barriers for convection and vertical transport of trace gases in this region. Observed atmospheric VSLS abundances, sea surface temperature, relative humidity and MABL height correlated well during the cruise. We used a simple source–loss estimate to quantify the contribution of oceanic emissions along the cruise track to the observed atmospheric concentrations. This analysis showed that averaged, instantaneous emissions could not support the observed atmospheric mixing ratios of VSLSs and that the marine background abundances below the trade inversion were significantly influenced by advection of regional sources. Adding to this background, the observed maximum emissions of halocarbons in the coastal upwelling could explain the high atmospheric VSLS concentrations in combination with their accumulation under the distinct MABL and trade inversions. Stronger emissions along the nearshore coastline likely added to the elevated abundances under the steady atmospheric conditions. This study underscores the importance of oceanic upwelling and trade wind systems on the atmospheric distribution of marine VSLS emissions.

scholarly journals Meteorological constraints on oceanic halocarbons above the Peruvian Upwelling

2015 ◽  
Vol 15 (14) ◽  
pp. 20597-20628 ◽  
Author(s):  
S. Fuhlbrügge ◽  
B. Quack ◽  
E. Atlas ◽  
A. Fiehn ◽  
H. Hepach ◽  
...  
Keyword(s):  
Methyl Iodide ◽  
Lower Atmosphere ◽  
Trade Wind ◽  
Transport Modelling ◽  
Mixing Ratios ◽  
Transport Barriers ◽  
Oceanic Emissions ◽  
Oceanic Upwelling ◽  
First Time ◽  
Atmospheric Concentrations

Abstract. Halogenated very short lived substances (VSLS) are naturally produced in the ocean and emitted to the atmosphere. Recently, oceanic upwelling regions in the tropical East Atlantic were identified as strong sources of brominated halocarbons to the atmosphere. During a cruise of R/V METEOR in December 2012 the oceanic sources and emissions of various halogenated trace gases and their mixing ratios in the marine atmospheric boundary layer (MABL) were investigated above the Peruvian Upwelling for the first time. This study presents novel observations of the three VSLS bromoform, dibromomethane and methyl iodide together with high resolution meteorological measurements and Lagrangian transport modelling. Although relatively low oceanic emissions were observed, except for methyl iodide, surface atmospheric abundances were elevated. Radiosonde launches during the cruise revealed a low, stable MABL and a distinct trade inversion above acting both as strong barriers for convection and trace gas transport in this region. Significant correlations between observed atmospheric VSLS abundances, sea surface temperature, relative humidity and MABL height were found. We used a simple source-loss estimate to identify the contribution of oceanic emissions to observed atmospheric concentrations which revealed that the observed marine VSLS abundances were dominated by horizontal advection below the trade inversion. The observed VSLS variations can be explained by the low emissions and their accumulation under different MABL and trade inversion conditions. This study confirms the importance of oceanic upwelling and trade wind systems on creating effective transport barriers in the lower atmosphere controlling the distribution of VSLS abundances above ocean upwelling regions.

scholarly journals The contribution of oceanic methyl iodide to stratospheric iodine

2013 ◽  
Vol 13 (23) ◽  
pp. 11869-11886 ◽  
Author(s):  
S. Tegtmeier ◽  
K. Krüger ◽  
B. Quack ◽  
E. Atlas ◽  
D. R. Blake ◽  
...  
Keyword(s):  
Methyl Iodide ◽  
Transport Model ◽  
Stratospheric Ozone ◽  
The Other ◽  
Western Pacific ◽  
Simultaneous Occurrence ◽  
Tropical Regions ◽  
Mixing Ratios ◽  
Tropical Tropopause ◽  
Cold Point

Abstract. We investigate the contribution of oceanic methyl iodide (CH3I) to the stratospheric iodine budget. Based on CH3I measurements from three tropical ship campaigns and the Lagrangian transport model FLEXPART, we provide a detailed analysis of CH3I transport from the ocean surface to the cold point in the upper tropical tropopause layer (TTL). While average oceanic emissions differ by less than 50% from campaign to campaign, the measurements show much stronger variations within each campaign. A positive correlation between the oceanic CH3I emissions and the efficiency of CH3I troposphere–stratosphere transport has been identified for some cruise sections. The mechanism of strong horizontal surface winds triggering large emissions on the one hand and being associated with tropical convective systems, such as developing typhoons, on the other hand, could explain the identified correlations. As a result of the simultaneous occurrence of large CH3I emissions and strong vertical uplift, localized maximum mixing ratios of 0.6 ppt CH3I at the cold point have been determined for observed peak emissions during the SHIVA (Stratospheric Ozone: Halogen Impacts in a Varying Atmosphere)-Sonne research vessel campaign in the coastal western Pacific. The other two campaigns give considerably smaller maxima of 0.1 ppt CH3I in the open western Pacific and 0.03 ppt in the coastal eastern Atlantic. In order to assess the representativeness of the large local mixing ratios, we use climatological emission scenarios to derive global upper air estimates of CH3I abundances. The model results are compared with available upper air measurements, including data from the recent ATTREX and HIPPO2 aircraft campaigns. In the eastern Pacific region, the location of the available measurement campaigns in the upper TTL, the comparisons give a good agreement, indicating that around 0.01 to 0.02 ppt of CH3I enter the stratosphere. However, other tropical regions that are subject to stronger convective activity show larger CH3I entrainment, e.g., 0.08 ppt in the western Pacific. Overall our model results give a tropical contribution of 0.04 ppt CH3I to the stratospheric iodine budget. The strong variations in the geographical distribution of CH3I entrainment suggest that currently available upper air measurements are not representative of global estimates and further campaigns will be necessary in order to better understand the CH3I contribution to stratospheric iodine.

Taxonomic notes on the genus Salmoneus Holthuis, 1955 (Decapoda, Caridea, Alpheidae) from the South China Sea

Crustaceana ◽  
2016 ◽  
Vol 89 (14) ◽  
pp. 1585-1609 ◽  
Author(s):  
Yanrong Wang ◽  
Zhongli Sha
Keyword(s):  
South China Sea ◽  
South China ◽  
The South China Sea ◽  
The South ◽  
West Pacific ◽  
China Sea ◽  
Pacific Species

Four species of the genusSalmoneusHolthuis, 1955 are described and illustrated in the present paper, including two newly recorded species,Salmoneus cristatus(Coutière, 1897) andSalmoneus tricristatusBanner, 1959. The mouthparts of these two species are illustrated herein. A key to all Indo-West Pacific species of the genusSalmoneusis provided as well.

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