Mercury concentrations in thermal waters of the Bolshoi Semyachik hydrothermal system, Russia, Kamchatka.

Author(s):  
Anton Nuzhdaev

<p>The study of mercury receipt within volcanic activity zones and large hydrothermal systems recently causes the big interest connected with attempts of an estimation of volumes of natural mercury receipt on a daily surface.</p><p>The hydrothermal system connected with volcanic massif Big Semyachik is one of the largest on the territory of Kamchatka peninsula. On the surface, the hydrothermal system is manifested by three large hydrothermal fields - the Verhnee Field, the parychay Dolina, and the Northern Crater of the Central Semyachik, the heat export from which is estimated at 300 MW (Vakin, 1976). On the surface of the thermal fields hot thermal waters and powerful steam-gas jets are unloaded.  At the same time, due to the inaccessibility of thermal fields remain poorly studied, and in particular, there is no information on the concentrations of mercury in hydrothermal solutions.</p><p>During fieldwork in 2020 all types of thermal waters were sampled, chemical types of waters were established, concentrations of mercury in hydrothermal solutions: for hot thermal waters the average value of mercury was - 0.44 mcg / L, and in steam-gas jets - the average value of mercury was - 4.60 mcg / L.</p><p>Thus, in the course of the work the data on concentrations of mercury in hydrothermal solutions of one of the largest hydrothermal systems of Kamchatka were received for the first time.</p><p> </p>

2019 ◽  
Vol 98 ◽  
pp. 12008
Author(s):  
Elena Kalacheva

Many active and dormant volcanoes of the Kuril Islands host hydrothermal systems which discharge acid to ultra-acid SO4-Cl (Cl-SO4) and SO4 waters. On some island, hot near-neutral Na-Cl waters can be found discharging in coastal hot springs. Four main different isotopic shifts relative to the local meteoric water line can be observed in the corresponding δD vs. δ18O diagram. For the acid Cl-SO4 waters discharging within thermal fields on volcano slopes, there is a clear mixing trend between meteoric water and volcanic vapor. Steam-heated SO4 waters demonstrate trends indicating kinetic fractionation at temperatures close to the boiling-point. For the coastal springs, the trend is apparently a mixing line between meteoric and seawater. The δ18O-shift for deep thermal waters is related to isotopic exchange with host rock but there is also a clear latitude effect in the isotopic composition of the meteoric endmember.


2020 ◽  
Vol 8 ◽  
Author(s):  
Toshihiro Yoshimura ◽  
Shigeyuki Wakaki ◽  
Tsuyoshi Ishikawa ◽  
Toshitaka Gamo ◽  
Daisuke Araoka ◽  
...  

Variations in the stable isotopic composition of seawater Sr (δ88Sr) is a new tool for estimating the rates of global carbonate sedimentation over geologic time, yet the isotope compositions of the major sources and sinks of Sr to the world oceans are still in need of further constraint. We report δ88Sr values of vent fluids from arc/back-arc seafloor hydrothermal systems in the western Pacific. In the sediment-starved hydrothermal fields of the Manus Basin, Izu-Bonin Arc, and Mariana Trough, the δ88Sr values of end-member fluids for each site showed little variation (0.29–0.30‰) and were close to the average value of oceanic volcanic rocks, reflecting dissolved Sr sourced from host rocks. Chlorine-depleted fluids from phase-separated hydrothermal systems in the North Fiji Basin had the end-member δ88Sr values of 0.26, 0.28, and 0.29‰. Thus, both sediment-starved and phase-separated vent fluids had the end-member δ88Sr values indistinguishable from or very close to the range of oceanic volcanic rocks. Therefore, the δ88Sr compositions in these hydrothermal sites are controlled predominantly by Sr sourced from host rock with a small influence from secondary mineral precipitation/re-dissolution. Fluids from the sediment-hosted hydrothermal fields of the Okinawa Trough, however, were characterized by low δ88Sr values of approximately 0.22‰ and high 87Sr/86Sr ratios, indicating interactions with sedimentary carbonates. As for the modern oceanic δ88Sr budget, the sediment-hosted sites lower the global hydrothermal δ88Sr. Since both sediment-starved and -hosted hydrothermal systems provide a long-term control on the global Sr cycle, the end-member δ88Sr value is an important constraint on the evolution of Sr cycling in past oceans.


Author(s):  
G. A. Chelnokov ◽  
N. A. Kharitonova ◽  
I. V. Bragin ◽  
A. V. Aseeva ◽  
K. Yu. Bushkareva ◽  
...  

A study of the distribution of rare-earth elements in surface and underground waters, waterbearing rocks, as well as secondary mineral formed by the thermal waters of the Paratunka and Viluchinsky hydrothermal systems of Kamchatka was carried out. It was found that the REE content, their distribution and fractionation differ depending on the geochemical type of water, as well as the pH–Eh of the aquifer. All waters are characterized by the predominance of the dissolved form of the REE water transfer, which exceeds the transfer of REE with colloids by a factor of a thousand. It has been shown that in the discharge areas of the studied thermal waters carbonates, sulfates and silicates, including calcite, gypsum, and amorphous opal, are widespread. The intensity of the REE redistribution process in the rock-water-secondary deposits system is very weak in waters where REEs are associated with sulfates. At the same time, REEs bound in water with carbonate complexes most actively accumulate in newly formed mineral phases.


2019 ◽  
Vol 53 (1) ◽  
pp. 107-142 ◽  
Author(s):  
D. E. Himelbrant ◽  
I. S. Stepanchikova ◽  
T. Ahti ◽  
V. Yu. Neshataeva

The first lichenological inventory in Koryakia has resulted in the list of 315 species reported from Parapolsky Dale, within and in vicinities of the Koryak State Reserve. Altogether 46 species are published from the Kamchatka Territory for the first time, including Lecanographa grumulosa new to Russia, East Asia and Beringia; Cercidospora trypetheliza, Lecania dubitans, Pertusaria borealis, Piccolia ochrophora, Protoparmelia cupreobadia, Rimularia badioatra and Strangospora moriformis new to Russian Far East; Abrothallus bertianus, Cladonia strepsilis, Physciella melanchra, Rimularia badioatra, Sclerococcum parasiticum, Sphinctrina leucopoda and Strangospora moriformis new to Beringia. The lichen diversity of the study area is relatively poor due to natural reasons. Comparison with neighboring regions (Kamchatka Peninsula, Chukotka, Magadan Region, Yakutia and Alaska) shows that the lichen flora of Parapolsky Dale contains almost no specific species. The majority of the species recorded here are also known from neighboring regions, especially Alaska and Kamchatka Peninsula.


Author(s):  
Hsin-Fu Yeh ◽  
Hung-Hsiang Hsu

The Tatun Volcano Group (TVG) is located in northern Taiwan and consists of many springs and fumaroles. The Tayukeng (TYK) area is the most active fumarole site in the TVG. In this study, we analyzed the long-term geochemical variations of hydrothermal fluids and proposed a mechanism responsible for the variation in TYK. There are two different aquifers beneath the TYK area: a shallow SO42−-rich aquifer and a deeper aquifer rich in Cl−. TYK thermal water was mainly supplied by the shallow SO42−-rich aquifer; therefore, the thermal water showed high SO42− concentrations. After 2015, the inflow of deep thermal water increased, causing the Cl− concentrations of the TYK to increase. Notably, the inferred reservoir temperatures based on quartz geothermometry increased; however, the surface temperature of the spring decreased. We inferred that the enthalpy was lost during transportation to the surface. Therefore, the surface temperature of the spring does not increase with an increased inflow of deep hydrothermal fluid. The results can serve as a reference for understanding the complex evolution of the magma-hydrothermal system in the TVG.


2009 ◽  
Vol 11 (1) ◽  
pp. 65-78 ◽  
Author(s):  
Xiaohui Yuan ◽  
Hao Nie ◽  
Yanbin Yuan ◽  
Anjun Su ◽  
Liang Wang

This paper proposes an enhanced cultural algorithm to solve the short-term generation scheduling of hydrothermal systems problem, in which differential evolution is embedded into a cultural algorithm and applies two knowledge sources to influence the variation operator of differential evolution and couples with simple selection criteria based on feasibility rules and heuristic search strategies to handle constraints in the cultural algorithm effectively. A test hydrothermal system is used to verify the feasibility and effectiveness of the proposed method. Results are compared with those of other optimization methods reported in the literature. It is shown that the proposed method is capable of yielding higher quality solutions.


2021 ◽  
Author(s):  
Pedro A. Hernández ◽  
Gladys Melian ◽  
María Asensio-Ramos ◽  
Eleazar Padron ◽  
Hirochicka Sumino ◽  
...  

<p>Significant temporal variations in the chemical and isotopic composition of Taal fumarolic gas as well as in diffuse CO<sub>2</sub> emission from Taal Main Crater Lake (TMLC) have been observed across the ~12 years of geochemical monitoring (Arpa et al., 2013; Hernández et a., 2017), with significant high CO<sub>2 </sub>degassing rates, typical of plume degassing volcanoes, measured in 2011 and 2017. In addition to these CO<sub>2</sub> surveys at the TCML, soil CO<sub>2</sub> efflux continuous monitoring was implemented at Taal volcano since 2016 and a clear increasing trend of the soil CO<sub>2</sub> efflux in 2017 was also observed. Increasing trends on the fumarolic CO<sub>2</sub>/St, He/CO<sub>2</sub>, CO/CO<sub>2</sub> and CO<sub>2</sub>/CH<sub>4</sub> ratios were recorded during the period 2010-2011 whereas increasing SO<sub>2</sub>/H<sub>2</sub>S, H<sub>2</sub>/CO<sub>2</sub> ratios were recorded during the period 2017-2018. A decreasing on the CO<sub>2</sub>/CH<sub>4</sub> and CO<sub>2</sub>/St ratios was observed for 2017-2018. These changes are attributed to an increased contribution of magmatic fluids to the hydrothermal system in both periods. Observed changes in H<sub>2</sub> and CO contents suggest increases in temperature and pressure in the upper parts of the hydrothermal system of Taal volcano. The <sup>3</sup>He/<sup>4</sup>He ratios corrected (Rc/Ra), and δ<sup>13</sup>C of fumarolic gases also increased during the periods 2010-2011 and 2017-2018 before the eruption onset. During this study, diffuse CO<sub>2</sub> emission values measured at TMCL showed a wide range of values from >0.5 g m<sup>−2</sup> d<sup>−1</sup> up to 84,902 g m<sup>−2</sup> d<sup>−1</sup>. The observed relatively high and anomalous diffuse CO<sub>2</sub> emission rate across the ~12 years reached values of 4,670 ± 159 t d<sup>-1 </sup>on March 24, 2011, and 3,858 ± 584 t d<sup>-1</sup> on November 11, 2017. The average value of the soil CO<sub>2</sub> efflux data measured by the geochemical station showed oscillations around background values until 14 March, 2017. Since then at 22:00 hours, a sharp increase of soil CO<sub>2</sub> efflux from ~0.1 up to 1.1 kg m<sup>-2</sup> d<sup>-1</sup> was measured in 9 hours and continued to show a sustained increase in time up to 2.9 kg m<sup>-2</sup> d<sup>-1</sup> in 2 November, that represents the main long-term variation of the soil CO<sub>2</sub> emission time series. All the above variations might be produced by two episodes of magmatic intrusion which favored degassing of a gas-rich magma at depth. During the 2010-2011 the magmatic intrusion of volatile-rich magma might have occurred from the mid-crustal storage region at shallower depths producing important changes in pressure and temperature conditions, whereas a new injection of more degassed magma into the deepest zone of the hydrothermal system occurring in 2017-2018 might have favored the accumulation of gases in the subsurface, promoting conditions leading to a phreatic eruption. These geochemical observations are most simply explained by magma recharge to the system, and represent the earliest warning precursor signals to the January 2020 eruptive activity.</p><p>Arpa, M.C., et al., 2013. Bull. Volcanol. 75, 747. https://doi.org/10.1007/s00445-013-0747-9.</p><p>Hernández, P.A., et al.,  2017. Geol. Soc. Lond. Spec. Publ. 437:131–152. https://doi.org/10.1144/SP437.17.</p>


2021 ◽  
Author(s):  
Mirja Pavić ◽  
Staša Borović ◽  
Maja Briški ◽  
Tihomir Frangen ◽  
Kosta Urumović

<p>The increase in thermal water utilisation is foreseen by many European and Croatian strategic documents regulating energetics, tourism, environmental protection and sustainable development. Croatian Geological Survey wishes to establish a multidisciplinary group for hydrothermal systems research which will contribute to responsible geothermal development in our country through a 5-year research project HyTheC which started in 2020.</p><p>Pannonian part of Croatia has favourable geothermal characteristics and natural thermal water springs emerge at two dozen localities, with temperatures up to 65 °C. These waters have been used for millennia, and in the past fifty years they are a basis for the development of tourism and health care centres which use the thermal water resource for heating, therapy and recreation (Borović & Marković, 2015). As their water demand increased, higher quantities were abstracted and additional intake structures and wells were constructed.</p><p>Thermal springs are part of hydrothermal systems which include: recharge areas in the mountainous hinterlands of the springs; geothermal aquifers - in Croatia mostly fractured and karstified Mesozoic carbonate rocks (Borović et al., 2016) - in which water resides and gets heated due to heat flow from the Earth; and discharge areas in places with favourable structural characteristics of higher permeability. The continuous functioning of such systems depends on a delicate balance between groundwater flow velocities, precipitation/dissolution processes and structural framework.</p><p>In order to maintain that balance and use thermal water resources in a sustainable manner, a system-level understanding is required. Multidisciplinary methodology (structural geology, hydrogeology, geothermal, hydrogeochemical and geophysical research and remote sensing) will be used to construct conceptual models of systems, perform 3D geological modelling, hydrogeological and thermal parametrisation of the geological units involved in the thermal fluid flow, and conduct numerical simulations of system functioning in undisturbed conditions and with different extraction scenarios.</p><p>This methodology will be tested in three pilot areas in Croatia where thermal water is being utilized (Daruvar, Hrvatsko zagorje and Topusko). These three areas have significantly different levels of initial data availability and it shall therefore be determined which methodology and order of application of different methods should be applied while researching the systems with considerable existing data, medium amount of data and very scarce data, respectively.</p><p>Keywords : hydrothermal system, natural thermal spring, multidisciplinary research, Croatia</p><p>References</p><p>Borović, S. & Marković, T. 2015 : Utilization and tourism valorisation of geothermal waters in Croatia. Renewable and Sustainable Energy Reviews, 44, pp. 52-63.</p><p>Borović, S., Marković, T., Larva, O., Brkić, Ž. & Mraz, V. 2016 : Mineral and Thermal Waters in the Croatian Part of the Pannonian Basin. U: Papić, P., ur., Mineral and Thermal Waters of Southeastern Europe. Cham: Springer, pp. 31-45.</p><p> </p><p>ACKNOWLEDGMENT</p><p>The Installation Research project HyTheC (UIP-2019-04-1218) is funded by the Croatian Science Foundation.</p>


Minerals ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 127
Author(s):  
Giovanna Rizzo ◽  
Maria Carmela Dichicco ◽  
Pedro Castiñeiras ◽  
Fausto Grassa ◽  
Salvatore Laurita ◽  
...  

A comprehensive study of the serpentinite and associated veins belonging to the Frido Unit in the Pollino Massif (southern Italy) is presented here with the aim to provide new constraints about the hydrothermal system hosted by the accretionary wedge of the southern Apennines. The studied serpentinites are from two different sites: Fosso Arcangelo and Pietrapica. In both sites, the rocks show mylonitic-cataclastic structures and pseudomorphic and patch textures and are traversing by pervasive carbonate and quartz-carbonate veins. The mineralogical assemblage of serpentinites consists of serpentine group minerals (with a predominance of lizardite), amphiboles, pyroxene, chlorite, titanite, magnetite, and talc. In some samples, hydro-garnet was also detected and documented here for the first time. As for cutting veins, different mineralogical compositions were observed in the two sites: calcite characterizes the veins from Fosso Arcangelo, whereas quartz and dolomite are the principal minerals of the Pietrapica veins infill, suggesting a different composition of mineralizing fluids. Stable isotopes of C and O also indicate such a different chemistry. In detail, samples from the Pietrapica site are characterized by δ13C fluctuations coupled with a δ18O shift documenting calcite formation in an open-system where mixing between deep and shallow fluids occurred. Conversely, δ13C and δ18O of the Fosso Arcangelo veins show a decarbonation trend, suggesting their developing in a closed-system at deeper crustal conditions. Precipitation temperature calculated for both sites indicates a similar range (80 °C to 120 °C), thus suggesting carbonate precipitation within the same thermal system.


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