Suppression of molten salt corrosion by plasma sprayed Ni3Al coatings

Corrosion behaviour of stainless steel 347 was investigated in a molten nitrate salt (60 wt% NaNO3 + 40 wt% KNO3) immersion at 565 °C for up to 3000 h. A growth of stratified oxide layers consisting of NaFeO2, Fe2O3 and Fe3O4 was observed on the stainless steel surface with a constant gravimetric corrosion rate of ~ 0.4 µm/year. The feasibility of using Ni3Al coatings deposited by means of air plasma spray for suppression of corrosion was investigated. Ni3Al coatings were observed to undergo a fast oxidation with a corrosion rate of ~ 2.7 µm/year in the first 500 h, and subsequently stabilise between 500 and 3000 h with no observable changes in microstructure, composition and weight at a corrosion rate of ~ 0.02 µm/year. The results presented in this study strongly suggest that Ni3Al coating suppresses the formation of oxide layers on the surface of stainless steel substrates and can be used as protection against corrosion in the presence of molten nitrate salts, which is of relevance to thermal energy storage applications.

Fretting study of an impregnated graphite bearing/nitrided stainless steel in a dry contact submitted to severe thermal-vibratory loading

Some industrial applications require the use of self-lubricating materials when fluid lubrication cannot be used. Carbon-based materials and in particular graphites are usually a used solution. However, the application of these materials is limited at high temperature; these materials are exposed to significant degradation and to high friction due to their high sensitivity to the air humidity and to the desorption phenomenon. This study determines the influence of a specific metallic impregnation on the graphite bearing, which is submitted to a severe thermo-vibratory loading by fretting against a stainless steel surface. The stainless steel surface has undergone a nitriding treatment by plasma. During the fretting contact, a strong transfer of the impregnant takes place from the impregnated graphite bearing to the steel conterface by adhesion; this deposit film allows a significant improvement in the tribological properties of the contact surfaces at high temperature.

Vacuum brazing of titanium alloy to stainless steel enhance by fiber laser surface texturing

A method for improving the brazing joining strength of Titanium alloy/Stainless steel fabricated through fibre laser surface texturing is introduced because it is a simple process that does not require the fabrication of complicated interlayers. However, previous research shows that a milimeter scale was fabricated by surface modification for dissimilar brazing join, yielding insignificant results and limiting the application and degree of enhancement. Fiber laser ablation was used in this study to create microscale periodic patterns (grooves) on a stainless steel surface. No defect or damage induced during laser surface texturing process. The groove dimension was tunable by controlling the laser parameters. Vacuum brazing of Ti6Al4V to 316L stainless steel with surface texturing, the average joint strength was 22.1 MPa, 34% of increase of joining strength compared to unprocessed flat surface. The combination of laser surface texturing and brazing proven effectively on joining strength enhancement.

Surface and corrosion properties of Type 430 ferritic stainless steel in parsley (Petroselinum Sativum) essential oil-containing sulphuric acid solution

This study examined the corrosion inhibiting properties of parsley (petroselinum sativum) essential oils, for Type 430 ferritic stainless steel in 0.5 molar sulphuric acid solutions. In this study, weight loss, electrochemical and scanning electron microscope techniques were used in gaining a detailed understanding of inhibition effects of parsley (petroselinum sativum) essential oils (PEO) on Type 430 ferritic stainless steel corrosion. The inhibitor studied exhibits good anti-corrosion performance with 98.65 % inhibition efficiency. This result could be ascribed to the adsorbed PEO on the surface of the stainless steel, and this was verified by surface visualization using optical and scanning electron microscope techniques while the crystallographic variation of the inhibited sample is studied by X-ray diffraction (XRD). The adsorption of PEO onto stainless steel surface is controlled by Langmuir adsorption isotherms. Optical images of non-inhibited specimens showed a severely corroded surface with a visible macro pit on the stainless steel from sulphuric solutions. The inhibited sample shows improved surface owing to the surface protection effect of PEO molecules. The corrosion inhibition performance of PEO is due to the presence of active constituents which enhanced the film formation over the surface of the metal, thus, mitigating corrosion.

Deposition of fluoropolymer coating on stainless steel surface from plasma of glow discharge

The present work investigates the application of the plasma of glow discharge to deposit the fluoropolymer coatings. Two series of experiments were carried out in which the influence of pressure and current strength on surface coatings morphology during its surface treatment with glow discharge plasma was investigated. The surface morphology is investigated by a scanning electron microscope (SEM), and the water contact angle (WCA) is measured. The fact that the choice of pressure significantly affects the morphology and properties of the deposited coating is established.