Porous, multi-layered piezoelectric composites based on highly oriented PZT/PVDF electrospinning fibers for high-performance piezoelectric nanogenerators

Piezoelectric nanogenerators (PENGs) that can harvest mechanical energy from ambient environment have broad prospects for multi-functional applications. Here, multi-layered piezoelectric composites with a porous structure based on highly oriented Pb(Zr0.52Ti0.48)O3/PVDF (PZT/PVDF) electrospinning fibers are prepared via a laminating method to construct high-performance PENGs. PZT particles as piezoelectric reinforcing phases are embedded in PVDF fibers and facilitate the formation of polar β phase in PVDF. The multi-layered, porous structure effectively promotes the overall polarization and surface bound charge density, resulting in a highly efficient electromechanical conversion. The PENG based on 10 wt% PZT/PVDF composite fibers with a 220 µm film thickness outputs an optimal voltage of 62.0 V and a power of 136.9 µW, which are 3.4 and 6.5 times those of 10 wt% PZT/PVDF casting film-based PENG, respectively. Importantly, the PENG shows a high sensitivity of 12.4 V·N−1, presenting a significant advantage in comparison to PENGs with other porous structures. In addition, the composites show excellent flexibility with a Young’s modulus of 227.2 MPa and an elongation of 262.3%. This study shows a great potential application of piezoelectric fiber composites in flexible energy harvesting devices.

Self-Healing Materials for Electronics Applications

Self-healing materials have been attracting the attention of the scientists over the past few decades because of their effectiveness in detecting damage and their autonomic healing response. Self-healing materials are an evolving and intriguing field of study that could lead to a substantial increase in the lifespan of materials, improve the reliability of materials, increase product safety, and lower product replacement costs. Within the past few years, various autonomic and non-autonomic self-healing systems have been developed using various approaches for a variety of applications. The inclusion of appropriate functionalities into these materials by various chemistries has enhanced their repair mechanisms activated by crack formation. This review article summarizes various self-healing techniques that are currently being explored and the associated chemistries that are involved in the preparation of self-healing composite materials. This paper further surveys the electronic applications of self-healing materials in the fields of energy harvesting devices, energy storage devices, and sensors. We expect this article to provide the reader with a far deeper understanding of self-healing materials and their healing mechanisms in various electronics applications.

High-k dielectric screen-printed inks for mechanical energy harvesting devices

There are a range of promising applications for devices that can convert mechanical energy from their local environment into useful electrical energy. Here, mechanical energy harvesting devices have been developed...

Maximum Electrical Power Extraction from Sources by Load Matching

This paper describes the matching of various loads to sources (including nonlinear ones). The purpose of matching is to extract the maximum available power from the source. This has particular importance for renewable sources and energy-harvesting devices, in which unused energy is just wasted. The main innovations in this paper include (and followed by examples) simplified calculation of the matching parameter for a controllable load and matching by means of a family of power-conservative two-port networks, denoted POPI (Pin = Pout), such as transformers, gyrators, loss-free resistors (LFRs) and series LFRs (SLFRs). An additional innovation described in this paper is a new, simplified model of an HF power amplifier based on the series LFR concept. This model predicts that the efficiency of the HF power amplifier operated under the matched-mode condition can significantly exceed the 50% efficiency limit that is predicted by the conventional model. As HF power amplifiers drive antennas in transmission and some wireless power transfer (which uses radiative techniques) systems, it is clear that the operation of such systems in the matched-mode condition is not restricted to a 50% efficiency limit.

Intercalation in 2D transition metal chalcogenides: interlayer engineering and applications

Intercalation is basically a process of putting one or multiple guest elements in the van der Waals (vdW) gaps of a parent crystal in a reversible way. Two-dimensional (2D) materials showed great promise for different intercalant species ranging from organic molecules to ions. Apart from graphene, the most studied 2D materials are the transition metal di-chalcogenides (TMDs). The intercalation in TMDs has reinvented the strategies beyond graphene in 2D structure in material science, materials engineering, chemistry, and physics. This review deals with the possible mechanism as well as the window that intercalation can open for compact and ultrathin device technology. Modulation of the physicochemical properties in the intercalated TMDs has been thoroughly reviewed. Finally, the device performance, especially energy storage and energy harvesting devices, has been evaluated, and specific issues have been chalked out that need attention for future development.