Emission Features and Structure of an Electron Beam versus Gas Pressure and Magnetic Field in a Cold-Cathode Coaxial Diode

The structure of the emission surface of a cold tubular cathode and electron beam was investigated as a function of the magnetic field in the coaxial diode of the high-current accelerator. The runaway mode of magnetized electrons in atmospheric air enabled registering the instantaneous structure of activated field-emission centers at the cathode edge. The region of air pressure (about 3 Torr) was determined experimentally and via analysis, where the explosive emission mechanism of the appearance of fast electrons with energies above 100 keV is replaced by the runaway electrons in a gas.

Intrareticular charge transfer regulated electrochemiluminescence of donor–acceptor covalent organic frameworks

The control of charge transfer between radical anions and cations is a promising way for decoding the emission mechanism in electrochemiluminescence (ECL) systems. Herein, a type of donor-acceptor (D-A) covalent organic framework (COF) with triphenylamine and triazine units is designed as a highly efficient ECL emitter with tunable intrareticular charge transfer (IRCT). The D-A COF demonstrates 123 folds enhancement in ECL intensity compared with its benzene-based COF with small D-A contrast. Further, the COF’s crystallinity- and protonation-modulated ECL behaviors confirm ECL dependence on intrareticular charge transfer between donor and acceptor units, which is rationalized by density functional theory. Significantly, dual-peaked ECL patterns of COFs are achieved through an IRCT mediated competitive oxidation mechanism: the coreactant-mediated oxidation at lower potential and the direct oxidation at higher potential. This work provides a new fundamental and approach to improve the ECL efficiency for designing next-generation ECL devices.

The Emission Mechanism of Gold Nanoclusters Capped with 11-Mercaptoundecanoic Acid, and the Detection of Methanol in Adulterated Wine Model

The absorption and emission mechanisms of gold nanoclusters (AuNCs) have yet to be understood. In this article, 11-Mercaptoundecanoic acid (MUA) capped AuNCs (AuNC@MUA) were synthesized using the chemical etching method. Compared with MUA, AuNC@MUA had three obvious absorption peaks at 280 nm, 360 nm, and 390 nm; its photoluminescence excitation (PLE) peak and photoluminescence (PL) peak were located at 285 nm and 600 nm, respectively. The AuNC@MUA was hardly emissive when 360 nm and 390 nm were chosen as excitation wavelengths. The extremely large stokes-shift (>300 nm), and the mismatch between the excitation peaks and absorption peaks of AuNC@MUA, make it a particularly suitable model for studying the emission mechanism. When the ligands were partially removed by a small amount of sodium hypochlorite (NaClO) solution, the absorption peak showed a remarkable rise at 288 nm and declines at 360 nm and 390 nm. These experimental results illustrated that the absorption peak at 288 nm was mainly from metal-to-metal charge transfer (MMCT), while the absorption peaks at 360 nm and 390 nm were mainly from ligand-to-metal charge transfer (LMCT). The PLE peak coincided with the former absorption peak, which implied that the emission of the AuNC@MUA was originally from MMCT. It was also interesting that the emission mechanism could be switched to LMCT from MMCT by decreasing the size of the nanoclusters using 16-mercaptohexadecanoic acid (MHA), which possesses a stronger etching ability. Moreover, due to the different PL intensities of AuNC@MUA in methanol, ethanol, and water, it has been successfully applied in detecting methanol in adulterated wine models (methanol-ethanol-water mixtures).

Narrow-band giant pulses from the Crab pulsar

ABSTRACT We used a new spectral-fitting technique to identify a subpopulation of 6 narrow-band giant pulses from the Crab pulsar out of a total of 1578. These giant pulses were detected in 77 min of observations with the 46-m dish at the Algonquin Radio Observatory at 400–800 MHz. The narrow-band giant pulses consist of both main- and inter-pulses, thereby being more likely to be caused by an intrinsic emission mechanism as opposed to a propagation effect. Fast radio bursts (FRBs) have demonstrated similar narrow-band features, while only little has been observed in the giant pulses of pulsars. We report the narrow-band giant pulses with Δν/ν of the order of 0.1, which is close to the value of 0.05 reported for the repeater FRB 20190711A. Hence, the connection between FRBs and giant pulses of pulsars is further established.