A Crustal Control on the Fe Isotope Systematics of Volcanic Arcs Revealed in Plutonic Xenoliths From the Lesser Antilles

Lavas produced at subduction zones represent the integration of both source heterogeneity and an array of crustal processes, such as: differentiation; mixing; homogenisation; assimilation. Therefore, unravelling the relative contribution of the sub-arc mantle source versus these crustal processes is difficult when using the amalgamated end products in isolation. In contrast, plutonic xenoliths provide a complementary record of the deeper roots of the magmatic plumbing system and provide a unique record of the true chemical diversity of arc crust. Here, we present the δ56Fe record from well characterised plutonic xenoliths from two distinct volcanic centres in the Lesser Antilles volcanic arc–the islands of Martinique and Statia. The primary objective of this study is to test if the Fe isotope systematics of arc lavas are controlled by sub-arc mantle inputs or during subsequent differentiation processes during a magma’s journey through volcanic arc crust. The Fe isotopic record, coupled to petrology, trace element chemistry and radiogenic isotopes of plutonic xenoliths from the two islands reveal a hidden crustal reservoir of heavy Fe that previously hasn’t been considered. Iron isotopes are decoupled from radiogenic isotopes, suggesting that crustal and/or sediment assimilation does not control the Fe systematics of arc magmas. In contrast to arc lavas, the cumulates from both islands record MORB-like δ56Fe values. In Statia, δ56Fe decreases with major and trace element indicators of differentiation (SiO2, Na2O + K2O, Eu/Eu*, Dy/Yb), consistent with fractionating mineral assemblages along a line of liquid descent. In Martinique, δ56Fe shows no clear relationship with most indicators of differentiation (apart from Dy/Yb), suggesting that the δ56Fe signature of the plutonic xenoliths has been overprinted by later stage processes, such as percolating reactive melts. Together, these data suggest that magmatic processes within the sub-arc crust overprint any source variation of the sub-arc mantle and that a light Fe source is not a requirement to produce the light Fe isotopic compositions recorded in volcanic arc lavas. Therefore, whenever possible, the complimentary plutonic record should be considered in isotopic studies to understand the relative control of the mantle source versus magmatic processes in the crust.

Molybdenum isotopes unmask slab dehydration and melting beneath the Mariana arc

How serpentinites in the forearc mantle and subducted lithosphere become involved in enriching the subarc mantle source of arc magmas is controversial. Here we report molybdenum isotopes for primitive submarine lavas and serpentinites from active volcanoes and serpentinite mud volcanoes in the Mariana arc. These data, in combination with radiogenic isotopes and elemental ratios, allow development of a model whereby shallow, partially serpentinized and subducted forearc mantle transfers fluid and melt from the subducted slab into the subarc mantle. These entrained forearc mantle fragments are further metasomatized by slab fluids/melts derived from the dehydration of serpentinites in the subducted lithospheric slab. Multistage breakdown of serpentinites in the subduction channel ultimately releases fluids/melts that trigger Mariana volcanic front volcanism. Serpentinites dragged down from the forearc mantle are likely exhausted at >200 km depth, after which slab-derived serpentinites are responsible for generating slab melts.

Archaeometry of a Roman Millstone from Santa Maria Arabona, Manoppello (Abruzzo, Central Italy)

A well-preserved Pompeiian-type millstone fragment was retrieved from the chance discovery of Roman ovens dating to the V-VI century BCE in the area of Santa Arabona Manoppello in Italy. This is the first evidence of an hourglass millstone in Abruzzo. This fragment was analyzed through petrography, geochemistry, statistical analyses, and radiogenic isotopes at the University G. d’Annunzio. The source location of the stones was narrowed down to the areas of Etna, Roccamonfina, and Vulsini due to the petrography, geochemistry, and statistical data elaboration of leuicititic and basaltic rocks from Central Italy and Sicily. The accurate identification of the provenance of the stone used to produce the millstone results in a better understanding of commercial trade routes and Roman entrepreneurship throughout Italy. The correlation between the production site and its stones’ dispersion throughout the Roman Empire is of great interest for understanding the vast network of Roman roads, their manageability of commerce, and the organization of their products to the outlying areas of their Empire and in the case of this discovery, specifically to the area of Abruzzo Italy.

A heterogeneous subcontinental mantle under the African–Arabian Plate boundary revealed by boron and radiogenic isotopes

The northern and northwestern margins of the Arabian Plate are a locus of a diffuse and long-lasting (early Miocene to Pleistocene) Na-alkali basaltic volcanism, sourced in the asthenosphere mantle. The upwelling asthenosphere at the Africa–Arabia margin produces very limited magma volumes in the axial zone. Therefore, portions of hot, fertile mantle continue their eastward migration and are stored at shallower depths under the 100-km thick Arabian lithosphere, which is much thinner than the African one (≈175 km): this causes the occurrence and 20-Ma persistence of magma supply under the study area. Erupted basalts sampled a continuous variation of the mantle source, with a striking correlation among temperature, pressure and isotopic composition shifting between two end members: a 100 km-deep, more depleted source, and a 60 km-deep, more enriched one. In particular, we observed an unusual variation in boron isotopes, which in the oceanic domain does not vary between more depleted and more enriched mantle sources. This study shows that, at least in the considered region, subcontinental mantle is more heterogeneous than the suboceanic one, and able to record for very long times recycling of shallow material.

Numerical Modelling of Radiogenic Ingrowth and Diffusion of Pb in Apatite Inclusions with Variable Shape and U-Th Zonation

The fundamental premise of apatite U-Th-Pb thermochronology is that radiogenic Pb is redistributed by volume diffusion. In practice, it is often additionally assumed that crystals (1) lose radiogenic Pb to an infinite reservoir, (2) have a simple geometry and (3) are chemically homogeneous. Here we explore the significance of the latter three assumptions by numerical modelling of Pb radiogenic ingrowth and diffusion in apatite inclusions within other minerals. Our results indicate that the host minerals are likely to hamper diffusive Pb loss from the apatite inclusions by limiting the Pb flux across their boundaries, and thus the thermal histories that are reconstructed assuming a fully open boundary may be significantly inaccurate, precluding a meaningful interpretation. We also find that when apatite boundaries are flux-limited, heterogeneities in U and Th concertation within apatite have subordinate effect on bulk-grain U-Th-Pb dates and can cause intra-grain U-Th-Pb dates to increase towards the boundaries. Finally, we show that it is important to correctly account for crystal geometry when modelling intra-grain U-Th-Pb dates. We suggest that the effect of surrounding minerals on diffusive Pb loss from apatite (and loss of other radiogenic isotopes from other minerals) should be examined more closely in future research.

A Multi-Elements Isotope Approach to Assess the Geographic Provenance of Manila Clams (Ruditapes philippinarum) via Recombining Appropriate Elements

The increasing global consumption of seafood has led to increased trade among nations, accompanied by mislabeling and fraudulent practices that have rendered authentication crucial. The multi-isotope ratio analysis is considered as applicable tool for evaluating geographical authentications but requires information and experience to select target elements such as isotopes, through a distinction method based on differences in habitat and physiology due to origin. The present study examined recombination conditions of multi-elements that facilitated geographically distinct classifications of the clams to sort out appropriate elements. Briefly, linear discriminant analysis (LDA) analysis was performed according to several combinations of five stable isotopes (carbon (δ13C), nitrogen (δ15N), oxygen (δ18O), hydrogen (δD), and sulfur (δ34S)) and two radiogenic elements (strontium (87Sr/86Sr) and neodymium (143Nd/144Nd)), and the geographical classification results of the Manila clam Ruditapes philippinarum from Democratic People’s Republic of Korea (DPR Korea), Korea and China were compared. In conclusion, linear discriminant analysis (LDA) with at least four elements (C, N, O, and S) including S revealed a remarkable cluster distribution of the clams. These findings expanded the application of systematic multi-elements analyses, including stable and radiogenic isotopes, to trace the origins of R. philippinarum collected from the Korea, China, and DPR Korea.

“Missing links” for the long-lived Macdonald and Arago hotspots, South Pacific Ocean

The Cook-Austral volcanic lineament extends from Macdonald Seamount (east) to Aitutaki Island (west) in the South Pacific Ocean and consists of hotspot-related volcanic islands, seamounts, and atolls. The Cook-Austral volcanic lineament has been characterized as multiple overlapping, age-progressive hotspot tracks generated by at least two mantle plumes, including the Arago and Macdonald plumes, which have fed volcano construction for ~20 m.y. The Arago and Macdonald hotspot tracks are argued to have been active for at least 70 m.y. and to extend northwest of the Cook-Austral volcanic lineament into the Cretaceous-aged Tuvalu-Gilbert and Tokelau Island chains, respectively. Large gaps in sampling exist along the predicted hotspot tracks, complicating efforts seeking to show that the Arago and Macdonald hotspots have been continuous, long-lived sources of hotspot volcanism back into the Cretaceous. We present new major- and trace-element concentrations and radiogenic isotopes for three seamounts (Moki, Malulu, Dino) and one atoll (Rose), and new clinopyroxene 40Ar/39Ar ages for Rose (24.81 ± 1.02 Ma) and Moki (44.53 ± 10.05 Ma). All volcanoes are located in the poorly sampled region between the younger Cook-Austral and the older, Cretaceous portions of the Arago and Macdonald hotspot tracks. Absolute plate motion modeling indicates that the Rose and Moki volcanoes lie on or near the reconstructed traces of the Arago and Macdonald hotspots, respectively, and the 40Ar/39Ar ages for Rose and Moki align with the predicted age progression for the Arago (Rose) and Macdonald (Moki) hotspots, thereby linking the younger Cook-Austral and older Cretaceous portions of the long-lived (>70 m.y.) Arago and Macdonald hotspot tracks.