The role of phyllosilicate partial melting in segregating tungsten and tin deposits in W-Sn metallogenic provinces

Most tungsten (W) and tin (Sn) deposits are associated with highly evolved granites derived from the anatexis of metasedimentary rocks. They are commonly separated in both space and time, and in the rare cases where the W and Sn mineralization are part of a single deposit, the two metals are temporally separate. The factors controlling this behavior, however, are not well understood. Our compilation of whole-rock geochemical data for W- and Sn-related granites in major W-Sn metallogenic belts shows that the Sn-related granites are generally the products of higher-temperature partial melting (~800 °C) than the W-related granites (~750 °C). Thermodynamic modeling of partial melting and metal partitioning shows that W is incorporated into the magma formed during low-temperature muscovite-dehydration melting, whereas most of the Sn is released into the magma at a higher temperature during biotite-dehydration melting; the Sn of the magma may be increased significantly if melt is extracted prior to biotite melting. At the same degree of partial melting, the concentrations of the two metals in the partial melt are controlled by their concentration in the protolith. Thus, the nature of the protolith and the melting temperature and subsequent evolution of the magma all influence the metallogenic potential of a magma and, in combination, helped control the spatial and temporal segregation of W and Sn deposits in all major W-Sn metallogenic belts.

Tracking slab surface temperatures with electrical conductivity of glaucophane

Slab surface temperature is one of the key parameters that incur first-order changes in subduction dynamics. However, the current thermal models are based on empirical thermal parameters and do not accurately capture the complex pressure–temperature paths of the subducting slab, prompting significant uncertainties on slab temperature estimations. In this study, we investigate whether the dehydration-melting of glaucophane can be used to benchmark the temperature in the slab. We observe that dehydration and melting of glaucophane occur at relatively low temperatures compared to the principal hydrous phases in the slab and produce highly conductive Na-rich melt. The electrical properties of glaucophane and its dehydration products are notably different from the hydrous minerals and silicate melts. Hence, we conclude that the thermodynamic instability of glaucophane in the slab provides a unique petrological criterion for tracking temperature in the present-day subduction systems through magnetotelluric profiles.

Geodynamic Setting and Cu-Ni Potential of Late Permian Xiwanggou Mafic-Ultramafic Rocks, East Kunlun Orogenic Belt, NW China

Several magmatic Cu–Ni sulfide deposits have recently been explored along the deep Middle Kunlun fault related to the extension of the East Kunlun orogenic belt in Qinghai Province, NW China. The Xiwanggou mafic–ultramafic rocks associated with Cu–Ni sulfide mineralization are first to be dated as late Permian compared to most of the deposits formed during late Silurian–early Devonian in this region. The Xiwanggou complexes located in the junction area between the East Kunlun and West Qinling belts, are composed of gabbros, olivine-gabbros, pyroxenites, olivine-pyroxenites, and peridotites. The Cu–Ni mineralization are mainly hosted in the olivine-pyroxenites and pyroxenites, whereas the sulfide-poor mineralization distributed in gabbros and olivine-gabbros. Zircon LA-ICP-MS U–Pb dating of the gabbro and olivine-pyroxenite revealed their crystallized ages of 250.8 ± 0.8 Ma and 257.3 ± 0.7 Ma, respectively. The trace element characteristics of the Xiwanggou fertile mafic-ultramafic rocks shows the enrichments in Sr, Rb, Th, Ba and light rare earth elements, and depletions in Nb and Ta, which are associated with the slab derived fluid input and dehydration melting of amphiboles. Meanwhile, Sr–Nd and Hf isotopic compositions of the gabbro [εNd(t) = 0.66–1.18; εHf(t) = 5.2–12] and olivine-pyroxenite [εNd(t) = −1.09 – −0.43; εHf(t) = 5.4–17.7] show that the magma was mainly derived from the metasomatized portions of subcontinental lithospheric mantle (SCLM) source in the mantle wedge. The magma primarily experienced dehydration melting processes of amphiboles and subsequently underwent hydrated melting in the overlying mantle wedge and relatively reduced background. The cool subduction process of the Anemaqen oceanic lithosphere maybe trigger large melting in the mantle wedge resulting in a relative low-Ni content in the melt. The transpressional windows formed by the right-lateral strike-slip shearing action of the Wenquan and South Kunlun faults in the South Kunlun forearc belt created a significant conduit for the magma ascending. The thermometer of Fe and Ni exchange between coexisting olivine and sulfide melt indicates the magma were yielded in a temperature range of ca. 1200–1300°C and an oxygen fugacity range of ca. –10.57 to –8.98 (log unit), which suggested that the parental magma of the Xiwanggou complex derived from a relatively reduced source favoring Ni relative to Fe in the melt. The intermediate sulfide segregation from the melt resulted in a medium tenor potential for the Xiwanggou complex.

The role of lithospheric thickness in the formation of ocean islands and seamounts: contrasts between the Louisville and Emperor-Hawaiian hotspot trails

The Hawaii-Emperor and Louisville seamounts form the two most prominent time-progressive hotspot trails on Earth. Both formed over a similar time interval on lithosphere with a similar range of ages and thickness. The Hawaii-Emperor seamounts are large and magma productivity appears to be increasing at present. The Louisville seamounts, by contrast, are smaller and the trail appears to be waning. We present new major- and trace element data from five of the older (74–50 Ma) Louisville seamounts drilled during International Ocean Drilling Program (IODP) Expedition 330 and compare these to published data from the Emperor seamounts of the same age. Despite drilling deep into the shield-forming volcanic rocks at three of the Louisville seamounts, our data confirm the results of earlier studies based on dredge samples that the Louisville seamounts are composed of remarkably uniform alkali basalt. The basalt composition can be modelled by ∼1.5–3% partial melting of a dominantly garnet lherzolite mantle with a composition similar to that of the Ontong Java Plateau mantle source. Rock samples recovered by dredging and drilling on the Emperor Seamounts range in composition from tholeiitic to alkali basalt and require larger degrees of melting (2–10%) and spinel- to garnet lherzolite mantle sources. We use a simple decompression melting model to show that melting of mantle with a potential temperature of 1500ºC under lithosphere of varying thickness can account for the composition of the shield-forming tholeiitic basalts from the Emperor seamounts, while post-shield alkali basalt requires a lower temperature (1300–1400ºC). This is consistent with the derivation of Hawaii-Emperor shield-forming magmas from the hotter axis of a mantle plume and the post-shield magmas from the cooler plume sheath as the seamount drifts away from the plume axis. The composition of basalt from the Louisville seamounts shows no significant variation with lithosphere thickness at the time of seamount formation, contrary to the predictions of our decompression melting model. This lack of influence of lithospheric thickness is characteristic of basalt from most ocean islands. The problem can be resolved if the Louisville seamounts were formed by dehydration melting of mantle containing a small amount of water in a cooler plume. Hydrous melting in a relatively cool mantle plume (Tp = 1350–1400 °C) could produce a small amount of melt and then be inhibited by increasing viscosity from reaching the dry mantle solidus and melting further. The failure of the plume to reach the dry mantle solidus or the base of the lithosphere means that the resulting magmas would have the same composition irrespective of lithosphere thickness. A hotter mantle plume (Tp ≈ 1500 °C) beneath the Emperor seamounts and the Hawaiian Islands would have lower viscosity before the onset of melting, melt to a larger extent, and decompress to the base of the lithosphere. Thus our decompression melting model could potentially explain the composition of both the Emperor and Louisville seamounts. The absence of a significant lithospheric control on the composition of basalt from nearly all ocean islands suggests that dehydration melting is the rule and the Hawaiian islands the exception. Alternatively, many ocean islands may not be the product of mantle plumes but instead be formed by decompression melting of heterogeneous mantle sources composed of peridotite containing discrete bodies of carbonated and silica-oversaturated eclogite within the general upper mantle convective flow.

Dating crustal anatexis in UHT granulites with Lu-Hf

<p>Ultra-high temperature (UHT) metamorphism is a thermal regime that can be attained by the lower continental crust in exceptional contexts and that is usually accompanied by fluid-absent dehydration melting. Such conditions are observed in the Gruf Complex, a 12 x 10 km migmatitic body located in the Central Alps, which is characterized by the presence of UHT granulitic schlieren and enclaves within migmatitic orthogneisses and charnockites. Two types of granulites, both with a massive and melanocratic texture, were investigated. The first granulite contains sapphirine, garnet, orthopyroxene, K-feldspar and biotite in the peak mineral assemblage, whereas the second type displays garnet, orthopyroxene, sillimanite and biotite. In both granulites, garnets are porphyroblastic and can reach up to 2 cm in size. These garnets are almost pure almandine-pyrope solid solutions and are zoned, showing pyrope-richer rims (Alm<sub>43-54</sub>Prp<sub>43-55</sub>Sps<sub>0-2</sub>Grs<sub>1-6</sub>) compared to cores (Alm<sub>47-62</sub>Prp<sub>32-48</sub>Sps<sub>0-3</sub>Grs<sub>2-9</sub>). A clear zoning is also observed in the rare earth elements (REE), with garnet cores showing the highest REE concentrations. Moreover, the porphyroblastic garnets are characterized by the presence of numerous melt inclusions (MI), which can be noticed both in garnet cores and rims. The MI occur as polycrystalline (nanogranitoids) and glassy inclusions, and dominantly display a peraluminous, rhyolitic composition, suggesting that they were originated, along with the host garnet, by incongruent, fluid-absent melting reactions during crustal anatexis. Lu-Hf ages obtained for the MI-bearing garnet cores of both granulites indicate that they formed at about 41 ± 4 Ma, which therefore can be interpreted as the time that crustal anatexis generated the UHT granulites. Considering the granulites in the context of the alpine framework, it is also inferred that UHT conditions in the lower crust were achieved as a consequence of asthenospheric upwelling, probably related to slab steepening or slab breakoff.</p>