Chromite-PGM Mineralization in the Lherzolite Mantle Tectonite of the Kraka Ophiolite Complex (Southern Urals, Russia)

The mantle tectonite of the Kraka ophiolite contains several chromite deposits. Two of them consisting of high-Cr podiform chromitite—the Bolshoi Bashart located within harzburgite of the upper mantle transition zone and Prospect 33 located in the deep lherzolitic mantle—have been investigated. Both deposits are enveloped in dunite, and were formed by reaction between the mantle protolith and high-Mg, anhydrous magma, enriched in Al2O3, TiO2, and Na2O compared with boninite. The PGE mineralization is very poor (<100 ppb) in both deposits. Laurite (RuS2) is the most common PGM inclusion in chromite, although it is accompanied by erlichmanite (OsS2) and (Ir,Ni) sulfides in Prospect 33. Precipitation of PGM occurred at sulfur fugacity and temperatures of logƒS2 = (−3.0), 1300–1100 °C in Bolshoi Bashart, and logƒS2 = (−3.0/+1.0), 1100–800 °C in Prospect 33, respectively. The paucity of chromite-PGM mineralization compared with giant chromite deposits in the mantle tectonite in supra-subduction zones (SSZ) of the Urals (Ray-Iz, Kempirsai) is ascribed to the peculiar petrologic nature (low depleted lherzolite) and geodynamic setting (rifted continental margin?) of the Kraka ophiolite, which did not enable drainage of the upper mantle with a large volume of mafic magma.

Geochronology, geochemistry, Sr–Nd–Hf isotope composition of the late Permian adakite in West Ujimqin, Inner Mongolia: petrogenesis and tectonic implications

We report herein on new zircon U–Pb ages, the major and trace elements of whole-rock, and the Sr–Nd–Hf isotope composition for adakitic intrusives collected from the West Ujimqin district in the Southeast region of the Central Asian Orogenic Belt (CAOB). These data provide important constraints on the petrogenetic evolution and geodynamic setting of late Permian magmatism in the Southeast CAOB. The U–Pb dating of zircon shows that the ages of Seerbeng pluton and Nuhetingshala pluton in West Ujimqin are 255.3 ± 0.71 and 254.4 ± 1.2 Ma, respectively, which signifies that these are products of magmatic activity in the late Permian. The adakitic intrusives are characterized by high levels of Sr (Sr ≥ 741 ppm), low Y, low Yb, high Sr:Y ratios, and strongly fractionated rare earth elements (10.3 < LaN/YbN < 22.5), which is similar to the features of the adakite. The magmatic zircons exhibit positive Hf values (+8.1 to +13.3), and young two-stage model ages vary from 430 to 760 Ma. The high εNd(t) and low (87Sr:86Sr)i indicate that the adakitic granite derived from the partial melting of subducted oceanic slab. The high level of Mg# [100 × Mg/(Mg + Fe) in atomic number] and abundant Cr–Ni indicate that magmatic melts interacted with olivine rocks in the mantle. Considering these results and the regional rock assemblies, we conclude that the Paleo-Asian Ocean had not yet completely closed in the late Permian, and northward subduction continued, with the subducted slab possibly breaking off.

Genesis of High-Mg Adakites in the Southeastern Margin of North China Craton: Geochemical and U-Pb Geochronological Perspectives

In the eastern North China Craton (NCC), Mesozoic tectonics was dominated by the Paleo-Pacific subduction rollback and the Tanlu crustal-scale fault movement. The regional transtension had generated extensive adakitic magmatism, some Cu-Au ore-forming but others not. To establish the geodynamic setting and any metallogenic link for the adakites from the southeastern NCC margin, we analyzed the ore-barren adakitic rocks from underground mines in the Huaibei-Linhuan coalfield (where surface igneous outcrops are scarce), and compared their ages and geochemistry with other mineralized and ore-barren adakites across Eastern China. Zircon U-Pb dating reveals two magmatic episodes in the Huaibei-Linhuan coalfield: 1) early-Early Cretaceous (ca. 130–129 Ma) (quartz-)diorite and granodiorite, and 2) late-Early Cretaceous (ca. 115.8 and 105.8 Ma) microgabbro and dolerite. Whole-rock geochemistry indicates that the (quartz-)diorite and granodiorite are high-Mg adakitic, featured by low K2O/Na2O (avg. 0.33), high Sr/La (avg. 44.3), and lack of correlation between SiO2 (fractionation index) and Sr/Y (avg. 56.55) and MREE/HREE (avg. 1.09), resembling typical adakites derived from oceanic-slab partial melting. Geochronological correlation with the regional tectonic events suggests that the slab-melting may have been caused by the Paleo-Pacific subduction rollback. Further extension and crustal thinning in the late-Early Cretaceous along the southern Tanlu fault may have formed the gabbro-dolerite in the coalfield. Geochemical comparison suggests that parental magma of the Huaibei-Linhuan adakites may have had similar water content [similar zircon 10,000*(Eu/Eu*)/Y and Eu/Eu* ratios] to typical porphyry Cu-Au ore-forming magmas, yet the former may have been considerably more reduced (lower zircon Ce/Nd and whole-rock V/Sc ratios). We considered that the assimilation of Carboniferous-Permian coal seams in the area may have further lowered the magma fO2 and thus its potential to form Cu-Au mineralization.

Formation of Ultramylonites in an Upper Mantle Shear Zone, Erro-Tobbio, Italy

Deformation in the upper mantle is localized in shear zones. In order to localize strain, weakening has to occur, which can be achieved by a reduction in grain size. In order for grains to remain small and preserve shear zones, phases have to mix. Phase mixing leads to dragging or pinning of grain boundaries which slows down or halts grain growth. Multiple phase mixing processes have been suggested to be important during shear zone evolution. The importance of a phase mixing process depends on the geodynamic setting. This study presents detailed microstructural analysis of spinel bearing shear zones from the Erro-Tobbio peridotite (Italy) that formed during pre-alpine rifting. The first stage of deformation occurred under melt-free conditions, during which clinopyroxene and olivine porphyroclasts dynamically recrystallized. With ongoing extension, silica-undersaturated melt percolated through the shear zones and reacted with the clinopyroxene neoblasts, forming olivine–clinopyroxene layers. Furthermore, the melt reacted with orthopyroxene porphyroclasts, forming fine-grained polymineralic layers (ultramylonites) adjacent to the porphyroclasts. Strain rates in these layers are estimated to be about an order of magnitude faster than within the olivine-rich matrix. This study demonstrates the importance of melt-rock reactions for grain size reduction, phase mixing and strain localization in these shear zones.

Geochemistry and Sr-Nd isotopic studies of Palaeoproterozoic (ca. 2.3 Ga) meta-lamprophyre from Rapuru area, Nellore Schist Belt, Southern India: Implication for back-arc basin magmatism and its relevance to the Columbia Supercontinent assembly

Present study reports two lamprophyre dykes from the Rapuru area along the margin of Eastern Dharwar Craton (EDC) and Nellore Schist Belt (NSB). The Rapuru lamprophyre (RL) dykes are situated along southern extension of the Prakassam Alkaline Province (PAP). The Rapuru lamprophyre (RL) dykes are deformed yet preserves the porphyritic-panidiomorphic texture with mica phenocrysts and amphibole and feldspars in the groundmass. The geochemically RL have low Mg# (0.28-0.37), Ni (30 ppm - 60 ppm) and Cr (119 ppm - 228 ppm) concentration indicates their evolved nature like other reported lamprophyre from PAP and EDC. Which is a further supported Sr-Nd isotopic ratios shows affinity towards MORB-OIB like signature and juvenile magmatic nature. The RL seems to have inherited by two major influences, namely, primary source region: which is geochemically juvenile similar to the compositional field of enriched-MORB, and the continental lithosphere. Such magmas are known to have formed in the back-arc-basin environment. The initial 87 Sr/ 86 Sr ratio (∼0.7012-0.7045) and initial εNd (3.13 to 7.93) ratios are in line with the Back-Arc Basin Basalts (BABB) recorded in other parts of the world. The field observation and bulk-rock Sr-Nd radiogenic isotope in the present study support Palaeoproterozoic nature of RL. This concurrence of juvenile radiogenic isotopes and fluid-related trace element compositions apparently suggest dehydration of a subducted slab triggered metasomatism of the overlying mantle wedge in subduction related geodynamic setting. Such intrusive lamprophyre rocks of the older ages are limited in India as well as other part of the world. The rocks of 2.1 and 1.8 Ga, are widely considered to be the ages of initial accretion and final breakup of an erstwhile Columbia Supercontinent assembly. We argue that the RLs were formed in Palaeoproterozoic period during the waxing stages of the Columbia Supercontinent Assembly in BAB environment; most probably due to low degree of partial melting of asthenosphere and lithospheric interaction by the introduction of influx of subduction component into arc-back arc basin system.Supplementary material at https://doi.org/10.6084/m9.figshare.c.5598266

A geochemical study of the Crown Formation and Bird Member lavas of the Mesoarchaean Witwatersrand Supergroup, South Africa

The ca. 2.97 to 2.80 Ga Witwatersrand Supergroup, South Africa, represents the oldest intracontinental sedimentary basin of the Kaapvaal craton. Two volcanic units occur in this supergroup: the widespread Crown Formation lavas in the marine shale-dominated West Rand Group and the more geographically restricted Bird Member lavas, intercalated with fluvial to fluvio-deltaic sandstone and conglomerate of the Central Rand Group. These units remain poorly studied as they are rarely exposed and generally deeply weathered when cropping out. We report whole-rock major and trace elements, Hf and Nd-isotope whole-rock analyses of the lavas from core samples drilled in the south of the Witwatersrand basin and underground samples from the Evander Goldfield in the northeast. In the studied areas, both the Crown Formation and Bird Member are composed of two units of lava separated by sandstone. Whereas all the Crown Formation samples show a similar geochemical composition, the upper and lower volcanic units of the Bird Member present clear differences. However, the primitive mantle-normalized incompatible trace element concentrations of all Crown Formation and Bird Member samples show variously enriched patterns and marked negative Nb and Ta anomalies relative to Th and La. Despite the convergent geodynamic setting of the Witwatersrand Supergroup suggested by the literature, the Crown Formation and Bird Member are probably not related to subduction-related magmatism but more to decompression melting. Overall, the combined trace element and Sm-Nd isotopic data indicate melts from slightly to moderately depleted sources that were variably contaminated with crustal material. Greater contamination, followed by differentiation in different magma chambers, can explain the difference between the two signatures of the Bird Member. Finally, despite previous proposals for stratigraphically correlating the Witwatersrand Supergroup to the Mozaan Group of the Pongola Supergroup, their volcanic units are overall geochemically distinct.