Comparison of Nature and Synthetic Zeolite for Waste Battery Electrolyte Treatment in Fixed-Bed Adsorption Column

To support a sustainable energy development, CO2 reduction for carbon neutralization and water-splitting for hydrogen economy are two feasible technical routes, both of which require a significant input of renewable energies. To efficiently store renewable energies, secondary batteries will be applied in great quantity, so that a considerable amount of energy needs to be invested to eliminate the waste battery electrolyte pollution caused by heavy metals including Cu2+, Zn2+ and Pb2+. To reduce this energy consumption, the removal behaviors of these ions by using clinoptilolite and zeolite A under 5, 7 and 10 BV h−1 in a fixed-bed reactor were investigated. The used zeolites were then regenerated by a novel NH4Cl solution soaking, coupled with the ultrasonication method. Further characterizations were carried out using scanning electron microscopy, N2 adsorption and desorption test, and wide-angle X-ray diffraction. The adsorption breakthrough curves revealed that the leaching preference of clinoptilolite was Pb2+ > Cu2+ > Zn2+, while the removal sequence for zeolite A was Zn2+ > Cu2+ > Pb2+. The maximum removal percentage of Zn2+ ions for clinoptilolite under 5 BV h−1 was 21.55%, while it was 83.45% for zeolite A. The leaching ability difference was also discussed combining with the characterization results. The fact that unit cell stayed the same before and after the regeneration treatment approved the efficacy of the regeneration method, which detached most of the ions while doing little change to both morphology and crystallinity of the zeolites. By evaluating the pH and conductivity changes, the leaching mechanisms by adsorption and ion exchange were further studied.

Facile activation of lithium slag for the hydrothermal synthesis of zeolite A with commercial quality and high removal efficiency for the isotope of radioactive 90Sr

With the quick development of lithium industry, a large amount of solid waste of lithium slag are produced. Making high value-added products from lithium slag can not only alleviate the...

Controllable Preparation of Cubic Zeolite A and Application of Langmuir Model in Carbon Dioxide Adsorption

A large amount of remaining fly ash has been piled up or landfilled, which not only a waste of land resources but also results in a series of environmental problems. Therefore, using fly ash to produce high value-added products is a win-win development orientation between human beings and nature. In this study, zeolite A is successfully synthesized using a hydrothermal method using fly ash. Additionally, it is at 1.0 mol·L−1 of the alkali concentration that the crystallinity of zeolite A reaches the maximum value, about 96.6%. FTIR research shows that the main secondary structural unit D4R vibration band of zeolite A appears at 555 cm−1. The results of the SEM study indicate the structure of zeolite A is cubic. The TEM results show that the crystal structure of the zeolite A belongs to the body-centered cubic structure. Meanwhile, the positively charged sodium ions cooperate with the silicon oxygen tetrahedron and the aluminum oxygen tetrahedron to form the zeolite A skeleton. Carbon dioxide adsorption equilibrium study shows that the maximum adsorption capacity of zeolite A of 46.5 mL·g−1 is significantly higher than the maximum adsorption capacity of commercial-grade zeolite 4A of 39.3 mL·g−1. In addition, the application of the Langmuir model in the adsorption of carbon dioxide by commercial-grade zeolite 4A and zeolite A is studied, which not only extends the application of zeolite A, but can be further extended to other zeolite materials as well. Meanwhile, the adsorption process belongs to the Langmuir model, which is a single layer adsorption on an ideal surface.

Removal of aqueous organic pollutant by photo-Fenton process using low-cost Fe3O4/zeolite A

Degradation of methylene blue (MB) in textile water treatment was investigated by using the photo - Fenton method (mixture of Fe2+ and H2O2 with the UV irradiation) in the presence of nano-sized and low-cost catalyst Fe3O4/Zeolite A. This catalyst was synthesized by impregnation method; furthermore, its photo – catalytic performances and durability in heterogeneous Fenton system were evaluated. Both the structure and the physical chemistry properties of the photocatalyst was characterized by X-ray diffraction (XRD), scanning electron microscope (SEM). The study investigated the influences of different parameters of the MB decolorization efficiency such as initial concentration of peroxide attending the Fenton reaction, amounts of catalyst, pH of the dye solution and comparison of utilization of H2O2 in two cases with and without UV lamps. Under the optimum conditions which is the initial concentration of MB is 50 ppm and pH of dye solution is 3, high efficiencies of degradation were achieved – performance of 92.49%. These results suggest that the low-cost nanostructure catalyst Fe3O4/Zeolite A may be the considerable option because of the durability and the stability in the photo – Fenton reaction for organic wastewater treatment in textile industry.

Efficiency in Ofloxacin Antibiotic Water Remediation by Magnetic Zeolites Formed Combining Pure Sources and Wastes

In this work, red mud (RM) and spinel iron oxide nanoparticles (SPIONs) were added to pure silica/alumina sources (SAs) and fly ash (FA) with the aim of synthesizing and investigating the magnetic behavior of different zeolites. SAs were used to synthesize zeolite with LTA topology (zeolite A) with the addition of both red mud and spinel iron oxide nanoparticles. FA and RM were mixed to synthesize sodalite whereas only FA with the addition of SPIONs was used to form zeolite with FAU-topology (zeolite X). All the synthetic products showed magnetic properties. However, zeolites with spinel iron oxide nanoparticles (zeolites A and X) showed ferromagnetic-like behavior. Sodalite was characterized by a reduction in saturation magnetization, whereas zeolite A with red mud displayed antiferromagnetic behavior. For the first time, all the synthetic products were tested for polluted water remediation by a persistent emerging contaminant, ofloxacin (OFL) antibiotic. The four zeolite types showed good adsorption affinity towards OFL under actual conditions (tap water, natural pH). All materials were also tested for OFL removal in real waters spiked with OFL 10 µg L−1. Satisfactory recoveries (90–92% in tap water, 83–87% in river water) were obtained for the two zeolites synthesized from industrial waste materials.