In this paper, we generate some new classes of entangled states of a bimodal Bose–Einstein condensate (BEC), a pair of tunnel-coupled BEC, in the presence of two- and three-body elastic as well as mode-exchange collisions. The Hamiltonian of the considered system is very complicated, moreover, it can be fortunately transformed into a simple form using a two-mode displacement operator. After introducing the general form of the time evolved state, various classes of entangled states are generated. Indeed, the influence of different orders of tunneling strengths on the generated entangled states has been studied. Depending on the tunneling strength constants, two-, three- and four-partite entangled states are generated, all of which are superposition states of macroscopic number of BEC atoms. Considering three-particle collision dramatically changes the generated entangled states. Moreover, in particular cases, the resulted states are non-entangled. Also, we show that tunneling and collisional interactions can be manipulated to generate a pair of atomic entangled coherent states (quasi-Bell states). In addition, it is observed that the degree of entanglement for two-partite entangled states can be tuned via the number of BEC atoms, i.e. the corresponding concurrences tend to their maximum value by increasing the atoms in both modes of system.