Recent Advances of Polymeric Membranes in Tackling Plasticization and Aging for Practical Industrial CO2/CH4 Applications—A Review

Membranes are a promising technology for bulk CO2 separation from natural gas mixtures due to their numerous advantages. Despite the numerous fundamental studies on creating better quality membrane efficiency, scaling up the research work for field testing requires huge efforts. The challenge is to ensure the stability of the membrane throughout the operation while maintaining its high performance. This review addresses the key challenges in the application of polymeric technology for CO2 separation, focusing on plasticization and aging. A brief introduction to the properties and limitations of the current commercial polymeric membrane is first deliberated. The effect of each plasticizer component in natural gas towards membrane performance and the relationship between operating conditions and the membrane efficiency are discussed in this review. The recent technological advancements and techniques to overcome the plasticization and aging issues covering polymer modification, high free-volume polymers, polymer blending and facilitated transport membranes (FTMs) have been highlighted. We also give our perspectives on a few main features of research related to polymeric membranes and the way forwards. Upcoming research must emphasize mixed gas with CO2 including minor condensable contaminants as per real natural gas, to determine the competitive sorption effect on CO2 permeability and membrane selectivity. The effects of pore blocking, plasticization and aging should be given particular attention to cater for large-scale applications.

Field Performance Evaluation of High Polymer-Modified Asphalt Concrete Overlays

The objective of this paper was to assess the viability of using high polymer (HP) modified asphalt concrete (AC) mixtures in Virginia as a reflective crack mitigation technique or when deemed appropriate as a tool for increased crack resistance on higher volume facilities. This was achieved by compiling and evaluating routine distress survey data against pre-paving distress survey data for relevant in-service HP pavements constructed between 2015 and 2018 and comparing them with several control in-service conventional polymer-modified asphalt (PMA) pavements. This is the first effort in North America to provide a detailed field performance of HP AC mixtures. In general, none of the evaluated mixtures (HP or PMA) was able to prevent reflective cracking completely. The HP sections showed the most promising performance 5 years after construction regardless of traffic level and the pre-existing pavement conditions. The pavement management system data for the reviewed sections indicated a potential controlling effect of the joint condition of the underlying jointed concrete pavement layer regardless of the asphalt mixture type employed (PMA or HP). Moreover, performance evaluations using the network-level pavement management data were conducted to estimate the life expectancy of HP AC overlays. Two different approaches and three levels of analysis were undertaken. Overall, PMA and HP AC overlays had an average predicted service life of 6.2 and 8.3 years, respectively, indicating a 34% extension of performance life of the AC overlays with high polymer modification.

Characteristics of PEO Incorporated with CaTiO3 Nanoparticles: Structural and Optical Properties

In this research, direct band gap polymer composites with amorphous phase, which are imperative for optoelectronic devices applications were synthesized. The solution cast technique was used to produce polyethylene oxide (PEO)/calcium titanate (CaTiO3) nanocomposite (NC) films. The X-ray diffraction (XRD) confirms the growth of amorphous nature within PEO with CaTiO3 addition. The optical band gaps of pure PEO and PEO/CaTiO3 NC films were calculated using analysis of ultraviolet–visible (UV-Vis) spectra. The change in absorption edge toward lower photon energy is evidence of polymer modification. The dispersion behavior of the refractive index of PEO was manipulated to a higher wavelength upon doping with CaTiO3. Upon adding CaTiO3 to the pure PEO polymer, the dielectric constant and refractive index were considerably modified. The band gap shifts from 4.90 eV to 4.19 eV for the PEO incorporated with an optimum portion of 8 wt. % of CaTiO3. The types of the electronic transition in composite samples were specified, based on the Taucs model and the optical dielectric loss. The alteration of UV/Vis absorption spectra of the NC film was considered a suitable candidate to be applied in nanotechnology-based devices. The spherulites ascribed to the crystalline phase were distinguished through the optical microscopy (OM) study.

Sustainable Polymers from Recycled Waste Plastics and Their Virgin Counterparts as Bitumen Modifiers: A Comprehensive Review

The failure of bituminous pavements takes place due to heavy traffic loads and weather-related conditions, such as moisture, temperature, and UV radiation. To overcome or minimize such failures, a great effort has been put in recent years to enhance the material properties of bitumen, ultimately improving field performance and increasing the pavement service life. Polymer modification is considered one of the most suitable and by far the most popular approach. Elastomers, chemically functionalised thermoplastics and plastomers * (* Note: notwithstanding the fact that in Polymer Science the word ‘plastomer’ indicates a polymer with the simultaneous behaviour of an elastomer and plastics (thermoplastics), this paper uses the term ‘plastomer’ to indicate a thermoplastic polymer as it is more commonly found in Civil and Pavement Engineering.) are the most commonly used polymers for bitumen modification. Plastomers provide several advantages and are commonly acknowledged to improve high-temperature stiffness, although some of them are more prone to phase separation and consequent storage instability. Nowadays, due to the recent push for recycling, many road authorities are looking at the use of recycled plastics in roads. Hence, some of the available plastomers—in pellet, flakes, or powder form—are coming from materials recycling facilities rather than chemical companies. This review article describes the details of using plastomers as bitumen modifiers—with a specific focus on recycled plastics—and how these can potentially be used to enhance bitumen performance and the road durability. Chemical modifiers for improving the compatibility between plastomers and bitumen are also addressed in this review. Plastomers, either individual or in combination of two or three polymers, are found to offer great stiffness at high temperature. Different polymers including HDPE, LDPE, LLDPE, MDPE, PP, PS, PET, EMA, and EVA have been successfully employed for bitumen modification. However, each of them has its own merit and demerit as thoroughly discussed in the paper. The recent push in using recycled materials in roads has brought new light to the use of virgin and recycled plastomers for bitumen modification as a low-cost and somehow environmental beneficial solution for roads and pavements.

Microwave Induction Heating of Polymer-Modified Asphalt Materials for Self-Healing and Deicing

This study evaluates the influence of polymer-modification on the induction heating capability of asphalt mastic in a microwave field, and investigates how effectively this approach can be utilized for ice melting and self-healing purposes. To this end, different asphalt mastic mixtures with different polymer-modification and mixing procedures were tested under microwave field exposure for induction heating capability, ice-melting ability, and self-healing capacity. The mixtures were made through warm-mix and hot-mix procedures with four bituminous binders, including virgin (unmodified) asphalt and the same binder modified with three types of polymers. The results showed the effectiveness of microwave induction heating of asphalt mastic for both crack-healing and deicing purposes. The binder type was found to influence the ice melting and crack healing rates, such that using a warm-mix asphalt binder resulted in a more efficient heat generation and conduction than using a virgin asphalt binder. While polymer-modification undermined induction-heating, ice-melting, and self-healing performances, SBS-modified asphalt binders exhibited better performance than the other polymer-modified binders.

Effect of Position and Structure of the Terminal Moieties in the Side Group on the Liquid Crystal Alignment Behavior of Polystyrene Derivatives

We synthesized a series of polystyrene derivatives containing various side groups, such as the 4-(tert-butyl)-phenoxymethyl, 3-(tert-butyl)-phenoxymethyl, 2-(tert-butyl)-phenoxymethyl, 4-cumyl-phenoxymethyl, and 4-trityl-phenoxymethyl groups, through a polymer modification reaction to examine the liquid crystal (LC) alignment of these derivatives. In general, the vertical LC alignment on polymer films can be affected by the position and structure of the terminal moiety of the polymer side group. For example, the LC cells fabricated with 4-(tert-butyl)-phenoxymethyl-substituted polystyrene having a tert-butyl moiety as a para-type attachment to the phenoxy groups of the polystyrene derivatives exhibited vertical LC alignment, whereas the LC cells prepared from 3-(tert-butyl)- and 2-(tert-butyl)-phenoxymethyl-substituted polystyrene films exhibited planar LC alignment. In addition, the LC cells fabricated from 4-cumyl- and 4-trityl-phenoxymethyl-substituted polystyrene films with additional phenyl rings in the side groups exhibited planar LC alignment, in contrast to the LC alignment of the (tert-butyl)-phenoxymethyl-substituted polystyrene series. The vertical LC orientation was well correlated with the surface energy of these polymer films. For example, vertical LC orientation, which mainly originates due to the nonpolar tertiary carbon moiety having bulky groups, was observed when the surface energy of the polymer was lower than 36.6 mJ/m2.

Evaluation and Comparison of Mechanical Properties of Polymer-Modified Asphalt Mixtures

Polymer modification is extensively used in the Kingdom of Saudi Arabia (KSA) because the available asphalt cement does not satisfy the high-temperature requirements. It was widely used in KSA for more than two decades, and there is little information regarding the differences in the performance of different polymers approved for binder modification. Pavement engineers require performance comparisons among various polymers to select the best polymer for modification rather than make their selection based on satisfying binder specifications. Furthermore, the mechanical properties can help select polymer type, producing mixes of better resistance to specific pavement distresses. The study objective was to compare the mechanical properties of the various polymer-modified asphalt (PMA) mixtures that are widely used in the Riyadh region. Control mix and five other mixes with different polymers (Lucolast 7010, Anglomak 2144, Pavflex140, SBS KTR 401, and EE-2) were prepared. PMA mixtures were evaluated through different mechanical tests, including dynamic modulus, flow number, Hamburg wheel tracking, and indirect tensile strength. The results show an improvement in mechanical properties for all PMA mixtures relative to the control mixture. Based on the overall comparison, the asphalt mixture with polymer Anglomk2144 was ranked the best performing mixture, followed by Paveflex140 and EE-2.