Generation of Hydrogen and Oxygen from Water by Solar Energy Conversion

Photosynthesis is considered to be one of the promising areas of cheap and environmentally friendly energy. Photosynthesis involves the process of water oxidation with the formation of molecular oxygen and hydrogen as byproducts. The aim of the present article is to review the energy (light) phase of photosynthesis based on the published X-ray studies of photosystems I and II (PS-I and PS-II). Using modern ideas about semiconductors and biological semiconductor structures, the mechanisms of H+, O2↑, e− generation from water are described. At the initial stage, PS II produces hydrogen peroxide from water as a result of the photoenzymatic reaction, which is oxidized in the active center of PS-II on the Mn4CaO5 cluster to form O2↑, H+, e−. Mn4+ is reduced to Mn2+ and then oxidized to Mn4+ with the transfer of reducing the equivalents of PS-I. The electrons formed are transported to PS-I (P 700), where the electrochemical reaction of water decomposition takes place in a two-electrode electrolysis system with the formation of gaseous oxygen and hydrogen. The proposed functioning mechanisms of PS-I and PS-II can be used in the development of environmentally friendly technologies for the production of molecular hydrogen.

The Relationship between Ozone and Human Blood in the Course of a Well-Controlled, Mild, and Transitory Oxidative Eustress

In the last twenty years there has been a proliferation of articles on the therapeutic use of ozone. As it is well-known, the term ozone therapy is very broad. It ranges from either systemic or loco-regional administration of unstable gaseous oxygen/ozone mixtures to the topical application of stable ozonated derivatives. Anyway, in relation to the absence of specific receptors and the extreme reactivity with the biological liquids with which it comes into contact, gaseous ozone cannot be classified as either a drug or a pro-drug. When the gaseous ozone impacts a biological matrix, both reactive oxygen species (ROS) and lipid oxidation products (LOPs) are formed. They represent the effector molecules responsible for modulating the therapeutic activity in the body. Apart from the merits of the action mechanisms resulting from the use of ozone, this article seeks to validate the practice of ozone therapy as an adjuvant treatment in full compliance with the physiology of the whole organism.

Mathematical modeling of a solid oxide fuel cell operating on biogas

Solid oxide fuel cells (SOFC) are the most efficient devices for directly converting the chemical energy of a fuel into electrical energy. This is one of the main reasons why these fuel cells have received a lot of attention from the scientific community and from several developers who have invested in the use of this technology in various applications. Biogas is one of the products of anaerobic decomposition (absence of gaseous oxygen) of organic matter, which occurs due to the action of certain types of bacteria. Biogas is mainly composed of methane (CH4) and carbon dioxide (CO2) and its use in solid oxide fuel cells has been investigated since Biogas is a renewable biofuel. The aim of this paper was to perform mathematical modeling of a solid oxide fuel cell operating on biogas. The results confirmed that the overall efficiency of the system is above 94% and the largest irreversibilities of the system are related to heat exchangers.

Oxygen Generation Using Catalytic Nano/Micromotors

Gaseous oxygen plays a vital role in driving the metabolism of living organisms and has multiple agricultural, medical, and technological applications. Different methods have been discovered to produce oxygen, including plants, oxygen concentrators and catalytic reactions. However, many such approaches are relatively expensive, involve challenges, complexities in post-production processes or generate undesired reaction products. Catalytic oxygen generation using hydrogen peroxide is one of the simplest and cleanest methods to produce oxygen in the required quantities. Chemically powered micro/nanomotors, capable of self-propulsion in liquid media, offer convenient and economic platforms for on-the-fly generation of gaseous oxygen on demand. Micromotors have opened up opportunities for controlled oxygen generation and transport under complex conditions, critical medical diagnostics and therapy. Mobile oxygen micro-carriers help better understand the energy transduction efficiencies of micro/nanoscopic active matter by careful selection of catalytic materials, fuel compositions and concentrations, catalyst surface curvatures and catalytic particle size, which opens avenues for controllable oxygen release on the level of a single catalytic microreactor. This review discusses various micro/nanomotor systems capable of functioning as mobile oxygen generators while highlighting their features, efficiencies and application potentials in different fields.

Continuous Monitoring of a Soil Aquifer Treatment System’s Physico-Chemical Conditions to Optimize Operational Performance

Soil aquifer treatment (SAT) is a tertiary process for wastewater treatment where the wastewater infiltrates through a thick vadose zone for purification and storage in the underneath aquifer. SAT infiltration basins are typically flooded intermittently, while maintaining a fixed ratio between the wetting and the drying stages. However, infiltration basins exhibit different physical and chemical properties, limiting the generalization of SAT operation to attain optimal efficiency. Since frequent sampling of the soil pore water to verify the SAT’s biodegradation efficiency can be arduous, continuous monitoring of the SAT vadose zone’s physico-chemical conditions is required. In this study, redox potential (Eh) was continuously monitored, together with other variables such as water content (θ), soil temperature, and gaseous oxygen (O2), at multiple depths of a SAT vadose zone throughout the year and while the system was constrained to different operational modes. Hydrological models were calibrated and validated to water content observations, and they illustrated the seasonal changes in water infiltration. Furthermore, it was shown that under long wetting stages during winter, there was a reduction in the SAT’s drainage capabilities. The Eh observations, under long wetting stages, demonstrated larger variability and very negative values as ambient temperature increased. Assembling the daily Eh observations illustrated that a wetting stage should cease after about 30 hours, once suboxic conditions are established. A drying stage’s optimal duration should be 36 hours, according to the Eh and O2 observations during summer and winter. Ultimately, the study shows that the length of wetting and drying stages should be defined separately, rather than by adhering to the wetting/drying ratio.

Persufflation—Current State of Play

With the ever-increasing disparity between the number of patients waiting for organ transplants and the number organs available, some patients are unable to receive life-saving transplantation in time. The present, widely-used form of preservation is proving to be incapable of maintaining organ quality during long periods of preservation and meeting the needs of an ever-changing legislative and transplantation landscape. This has led to the need for improved preservation techniques. One such technique that has been extensively researched is gaseous oxygen perfusion or Persufflation (PSF). This method discovered in the early 20th century has shown promise in providing both longer term preservation and organ reconditioning capabilities for multiple organs including the liver, kidneys, and pancreas. PSF utilises the organs own vascular network to provide oxygen to the organ tissue and maintain metabolism during preservation to avoid hypoxic damage. This review delves into the history of this technique, its multiple different approaches and uses, as well as in-depth discussion of work published in the past 15 years. Finally, we discuss exciting commercial developments which may help unlock the potential for this technique to be applied at scale.

Valorization of secondary feedstocks from the agroindustry by selective catalytic oxidation to formic and acetic acid using the OxFA process

The selective oxidative conversion of seven representative fully characterized biomasses recovered as secondary feedstocks from the agroindustry is reported. The reaction system, known as the “OxFA process,” involves a homogeneous polyoxometalate catalyst (H8PV5Mo7O40), gaseous oxygen, p-toluene sulfonic acid, and water as solvent. It took place at 20 bar and 90 °C and transformed agro-industrial wastes, such as coffee husks, cocoa husks, palm rachis, fiber and nuts, sugarcane bagasse, and rice husks into biogenic formic acid, acetic acid, and CO2 as sole products. Even though all samples were transformed; remarkably, the reaction obtains up to 64, and 55% combined yield of formic and acetic acid for coffee and cocoa husks as raw material within 24 h, respectively. In addition to the role of the catalysts and additive for promoting the reaction, the influence of biomass components (hemicellulose, cellulose and lignin) into biogenic formic acid formation has been also demonstrated. Thus, these results are of major interest for the application of novel oxidation techniques under real recovered biomass for producing value-added products. Graphical abstract

IGNITION BEHAVIOR OF SUPERCRITICAL LIQUID FUEL IN COMBUSTION SYSTEM

In systems that involve super-critical liquid fuel combustion, the temperature of the propellants is in the sub-critical state when they are injected into the combustion chamber. However, during the process of combustion, the system experiences a shift in its state of thermodynamics from subcritical to supercritical. The present study predicts the ignition behavior for super-critical liquid fuel combustion through the techniques of computational fluid dynamics (CFD). Simulations are carried out for a single shear coaxial injector’s test case of the combustion chamber. For super-critical combustion, the present research uses kerosene as a fuel and gaseous oxygen as the oxidizer. Simulations are carried out at a steady state for various values of rich flammability limit (RFL). The real gas model, Soave-Redlich-Kwong (SRK) is used for performing simulations in the present study. On the other hand, for the various values of rich flammability limit (RFL), transient simulations are carried out for ideal gas. It has been observed that the simulations performed for steady-state closely approximate the experimental data in comparison to transient simulations. It is also observed that the inherent stability issues involved in transient simulations emphasize the use of an ideal gas model for its computation.

Regression rate performance of paraffin wax and bees wax –Gox with varied grain configuration in a hybrid rocket motor

Purpose This paper aims to determine the regression rate using wax fuels for three different grain configurations and find a suitable grain port design for hybrid rocket application. Design/methodology/approach The design methodology of this work includes different grain port designs and subsequent selection of solid fuels for a suitable hybrid rocket application. A square, a cylindrical and a five-point star grained were designed and prepared using paraffin and beeswax fuels. They were tested in a laboratory-scale rocket with gaseous oxygen to study the effectiveness of solid fuels on these grain structures. The regression rate by static fire testing of these wax fuels was analyzed. Findings Beeswax performance is better than that of paraffin wax fuel for all three designs, and the five-slotted star fuel port grain attained the best performance. Beeswax fuel attained an average regression rate ≈of 1.35 mm/s as a function of oxidizer mass flux Gox ≈ 111.8 kg/m2 s and for paraffin wax 1.199 mm/s at Gox ≈ 121 kg/m2 s with gaseous oxygen. The local regression rates of fuels increased in the range of 0.93–1.194 mm/s at oxidizer mass flux range of 98–131 kg/m2 s for cylindrical grain, 0.99–1.21 mm/s at oxidizer mass flux range of 96–129 kg/m2s for square grain and 1.12–1.35 mm/s at oxidizer mass flux range of 91–126 kg/m2 s for a star grain. A complete set of the regression rate formulas is obtained for all three-grain designs as a function of oxidizer flux rate. Research limitations/implications The experiment has been performed for a lower chamber pressure up to 10 bar. Originality/value Different grain configurations were designed according to the required dimension of the combustion chamber, injector and exhaust nozzle of the design of a lab-scale hybrid rocket, and input parameters were selected and analyzed.