A compilation and characterisation of lithics in kimberlite and common maar-diatremes and tephra ring deposits

Maar-diatreme volcanoes are the second-most common type on land, occurring in volcanic fields within all major tectonic environments. Their deposits typically contain an abundance of lithic fragments quarried from the substrate, and many contain large, deep-sourced lithic fragments that were erupted to the surface. Primary volcaniclastic deposits fill the diatreme structure formed during eruption. There is negligible inelastic deformation of diatreme-adjacent country rock, indicating that country rock is removed to create the diatreme structures, either by being shifting downward below observable levels, ejected upward to contribute to surficial deposits, or dissolved and hidden in magma erupted or intruded at depth. No previous study has systematically reviewed and analysed the reported lithic fragments of maar-diatreme systems. We present a comprehensive compilation from published work of lithic characteristics in maar ejecta rings and in diatreme deposits of both common and kimberlite maar-diatremes. For maar-diatremes and their tephra ring deposits, we find no correlations among lithic clast sizes, shapes, depositional sites, and excavation depths. This is difficult to reconcile with models involving systematic diatreme deepening coupled with tephra-ring growth, but consistent with those involving chaotic explosions and mixing. Larger amounts of data are needed to further examine how these types of volcanoes operate.

Characterization of an Unstable Slope Using Geophysical, UAV, and Geological Techniques: Karakoram Himalaya, Northern Pakistan

Given active tectonism, rough terrain, and climate, the mountainous ranges in northern Pakistan are prone to geohazards, including earthquakes, unstable slopes, and landslides. The frequent landsliding in the region poses a risk to communities, economic activities, and transportation networks. In this context, the unstable slope above Mayun village calls for a multi-method approach for better assessment of the slope for planning interventions aimed at hazard mitigation. We conducted an integrated study including uncrewed aerial vehicle (UAV) and ground-penetrating radar (GPR) in coordination with geomorphic field observations to image the possible slip surfaces for a comprehensive understanding of a potential future rockslide with significant socioeconomic consequences. UAV-derived results helped delineate the overall extent of the unstable slope and its downslope area in a quick, remote, and safe way. GPR profiles have enabled the reconstruction of the bedrock’s morphology and its internal structure and the depth distribution of cracks running through the overburden and bedrock. The results provided insight into the stable and unstable compartments of the slope due to the thin cover of surficial deposits, high impedance contrast at the overburden-bedrock interface, lateral heterogeneities, and presence of open cracks, and almost detached blocks, respectively. These data on the dynamic properties of a landslide-prone slope could be used for the correct planning of civil infrastructure to minimize the potential risk of building damage in the seismically active Hunza valley.

A Compilation and Characterisation of Lithic Populations in Common and Kimberlite Maar-Diatremes and their Tephra Ring Deposits

Maar-diatreme volcanoes are the second-most common type on land, occurring in volcanic fields within all major tectonic environments. Their deposits typically contain an abundance of lithic fragments quarried from the substrate, and many contain large, deep-sourced lithic fragments that were erupted to the surface. Primary volcaniclastic deposits fill the diatreme structure formed during eruption. There is negligible inelastic deformation of diatreme-adjacent country rock, indicating that country rock is removed to create the diatreme structures, either by being shifting downward below observable levels, ejected upward to contribute to surficial deposits, or dissolved and hidden in magma erupted or intruded at depth. No previous study has systematically reviewed and analysed the reported lithic fragments of maar-diatreme systems. We present a comprehensive compilation from published work of lithic characteristics in maar ejecta rims and in diatreme deposits of both common and kimberlite maar-diatremes. For maar-diatremes and their tephra ring deposits, we find no correlations among lithic clast sizes, shapes, depositional sites, and excavation depths. This is difficult to reconcile with models involving systematic diatreme deepening coupled with tephra-ring growth, but consistent with those involving chaotic explosions and mixing. Larger amounts of data are needed to further examine how these types of volcanoes operate.

The role of calcium diffusion on high temperature SO2 uptake by volcanic glasses

<p>Glass-SO₂ reactions occurring at high temperatures in (terrestrial and extraterrestrial) volcanic environments have received increasing attention in the past years (e.g., Renggli and King 2018; Casas et al. 2019; Renggli et al. 2019), based on both natural and experimental observations. Laboratory studies carried out at high temperatures (>200 °C) demonstrate that volcanic glass in the presence of SO₂ reacts to form surficial sulfate-bearing minerals (e.g., Ayris et al. 2013; Delmelle et al. 2018), mostly calcium sulfate salts (CaSO₄). Thus, high temperature glass-SO₂ interaction acts as a sink for the magmatic S released during explosive volcanic activity, potentially impacting the S budget of large explosive eruptions. Here, we present the results of new experiments aimed at assessing the influence of the glass Ca content on SO<sub>2</sub> uptake in the temperature range of 600-800 °C. We exposed haplogranitic glasses to SO₂ for diverse time exposures (5-30 minutes). Rhyolitic composition was chosen due to the ubiquity of Si-rich magmas in large explosive eruptions (Cioni et al. 2000).</p><p>The experimental glasses were synthesized with an initial HPG8 composition (see Holtz et al. 1992), doped with 1 and 2 wt.% CaO. Furthermore, the role of Fe was tested by doping the glasses with 0, 0.1, 1, 1.5, 2 and 2.5 wt.% FeO and equilibrating them at 1500 °C. Leachates of post-treated glasses were analyzed by ion chromatography in order to determine SO<sub>2</sub>-uptake and the nature of the sulfate-bearing minerals formed by solid-gas reactions. The bulk redox state of iron (Fe³⁺/Fe<sub>total</sub>), was obtained by the K₂Cr₂O₇ potentiometric titration method. Our results show a strong correlation between the amount of Ca in the glasses and the formation of CaSO₄ surficial deposits (i.e. SO₂ uptake), i.e. the HPG8 + 2 wt.% CaO treated samples produced up to 40 % more CaSO₄ than the samples containing 1 wt.% CaO. Higher Fe content in the glass also enhanced formation of CaSO₄. In contrast, the absence of Fe oxide resulted in preferential formation of Na₂SO₄ and K₂SO₄, when compared to the Fe-bearing specimens. Our experiments confirm that high temperature SO₂ uptake by glass is strongly dependent on the Ca content and temperature, with the optimal reaction temperatures being ≥600 °C. Increasing the amount of FeO in the glasses seems to enhance SO<sub>2</sub> uptake, although this effect appears to be different for Ca than for Na or K, pointing out a more complex influence of redox dynamics on cation diffusion.</p><p> </p>

The Pilato Lake (Sibillini Mts., Central Italy): first results of a study on the supposed variations of its hydrogeological conditions induced by the seismic sequence 2016-2017

The Pilato Lake has glacial origin, is located in the Sibillini Mountains, Central Italy, and is characterized by the endemism of the small crustaceous Chirocephalus marchesonii. In the context of a research agreement with the Monti Sibillini National Park, the ISPRA Geological Survey of Italy is carrying on some studies aimed to evaluate the supposed effects of the 2016–2017 Central Italy earthquakes on the hydrogeological conditions controlling the lake’s evolution. The study, started in July 2018, aims primarily at the reconstruction of the geological and hydrogeological subsoil setting, beneath the valley hosting the lake. In order to define the conceptual model of groundwater circulation and, thus, to evaluate the emptying and recharge seasonal cycle of the lake, hydrogeological surveys and geophysical investigations were performed. The research program is still in progress and only preliminary results may be proposed. The hydrogeological surveys demonstrate the absence of geomorphological evidence of seismic-induced surface fractures generated by the seismic sequence 2016-2017. Consequently, the complete drying of the lake, occurred in summer 2017, was probably due to meteoclimatic reasons and/ or to not yet verified variations in the permeability characteristics of the surficial deposits and/or bedrock affecting the infiltration towards the subsoil, caused by the severe seismic shaking. The low electrical conductivity values of the lake’s waters are in accordance with the prevailing origin of the lake’s recharge by snow melting and direct rainfall. As concerns the first geophysical surveys in the Pilato Lake area, seismic surveys by surface wave method assessed that the maximum thickness of debris here estimated is about 12.5-14 m. As a whole, the factors responsible for the progressive lowering of the lake level are: i) the water overflow through the Fonte del Lago spring, ii) the evaporation from the lake surface and iii) the drainage through the scarcely permeable glacial deposits towards the Basal Calcareous Aquifer, hosted within the limestone at lower altitude.

A re-evaluation of the Hart Ash, an important stratigraphic marker: Wright Valley, Antarctica

Reliably dated surficial deposits for reconstructing palaeoclimate are rare in the McMurdo Dry Valleys of Antarctica. While many tephra have been found and dated, none is well characterized. In the Wright Valley, the Hart Ash is poorly dated and described. This paper reports profiles through tephra, the chemical signature of the glass shards and new high-precision multi-crystal laser fusion of 40Ar/39Ar ages. Major and trace element analyses of glass shards indicate the tephra are phonolitic and most probably sourced from Mount Discovery in the Erebus volcanic province. Two chemically distinct and stratigraphically separate tephra layers within the Hart Ash were found in three closely spaced soil profiles. The complex stratigraphy between these profiles could not be delineated without the geochemistry of the tephra. Importantly, our data suggest that only one tephra may be an in situ fall-out deposit, which gave a robust age of 2.97 ± 0.02 Ma. This new age for the Hart Ash tephra, which is 10 cm thick and is preserved at the current surface, provides a maximum age for surface deposits in the lower Wright Valley. This study highlights that well-characterized tephra enhance stratigraphic correlations in the Dry Valleys and improve the accuracy of palaeoenvironmental interpretations.