DELAMINATED CELLS FOR NANO-ENABLED INKJET PRINTABILITY

Nanometer scale cells delaminated from oil palm fruit bunch (EFB) microfiber cell walls were coated on commercial A4 and laboratory sheets prepared from virgin fibers. High-resolution transmission electron microscopy (HRTEM) revealed the cells as translucent laminae of fibrils (TRX) bound together in a 5 nm to 100 nm thick web with dendritic edges. Coating of TRX onto the commercial A4 paper improved inkjet printability by up to 80%. The nano-enabled printability occurred as a summed effect of TRX forming (1) a canopy on or “loose-masking” of the protruding inorganic fillers, (2) capillary bridging of micro-voids formed by TRX fibrillary ends, (3) partial bridging of micro-gaps, (4) masking of the fiber surface, and (5) nano-grip arising from dendritic ends slipping into the micro-voids. The TRX-coated virgin pulp network revealed improved nano-enabled coverage by significantly reducing the stray and by print uniformity. The results provided an insight into the possibility of interfacing TRX with the paper surface for an improved inkjet print and economy through high-precision printing, also providing a pleasurable reading experience.

Carbon dioxide snow cleaning of paper

The cleaning of particles from smooth and rough paper surfaces using a high-speed CO2 snow jet was investigated. The measurements included characterization of the jet properties, determination of the cleaning efficiency, and evaluation of any possible adverse effects. The method was compared with nitrogen jet cleaning and dry cleaning by commercial materials. The results showed that the CO2 snow jet is able to effectively remove particles from the paper surface and did not cause any observable degradation. The CO2 snow jet cleaning compared with the mechanical dry cleaning showed similar effectiveness without any adverse effects on the paper surface. It was proved that the CO2 snow technique is a suitable method for cleaning common types of paper materials.

Paper-Based Device for Sweat Chloride Testing Based on the Photochemical Response of Silver Halide Nanocrystals

A new method for the determination of chloride anions in sweat is described. The novelty of the method relies on the different photochemical response of silver ions and silver chloride crystals when exposed to UV light. Silver ions undergo an intense colorimetric transition from colorless to dark grey-brown due to the formation of nanosized Ag while AgCl exhibits a less intense color change from white to slightly grey. The analytical signal is obtained as mean grey value of color intensity on the paper surface and is expressed as the absolute difference between the signal of the blank (i.e., in absence of chloride) and the sample (i.e., in the presence of chloride). The method is simple to perform (addition of sample, incubation in the absence of light, irradiation, and offline measurement in a flatbed scanner), does not require any special signal processing steps (the color intensity is directly measured from a constant window on the paper surface without any imager processing) and is performed with minimum sample volume (2 μL). The method operates within a large chloride concentration range (10–140 mM) with good detection limits (2.7 mM chloride), satisfactory recoveries (95.2–108.7%), and reproducibility (<9%). Based on these data the method could serve as a potential tool for the diagnosis of cystic fibrosis through the determination of chloride in human sweat.

Paper trapping research after adding Mulberry tree branches bark cellulose pulp

The paper presents the study results of paper trapping during inkjet printing which contains cellulose pulp from the inner bark layer of mulberry branches. The connection between the print density and the paper surface structure, in particular, water absorption and raggedness, is established. The study of the stepwise gradation transition and color rendition, the graphic accuracy of reproduction of the slur element of the image is carried out. Densitometric and microscopic analysis of the impressions printed on an inkjet printer was performed. It was revealed that the pigments of water ink, depending on the microgeometry of the paper surface, penetrated deeper in different ways. It was found that the maximum thickness of the paint layer, expressed using the optical density values for the primary colors of the subtractive synthesis, and the best color reproduction were provided by the surface of the paper sample with 100 % addition of cellulose pulp from the inner layer of the bark of mulberry tree branches, which has the least roughness, according to the scanning probe microscope Solver HV. Recommendations are given for testing paper data on inkjet printers that use pigment inks and are less demanding on the surface properties of paper, or by printing methods that do not use low-viscosity printing inks.

Evaluation of Photosensitive Paper Coatings as Detectors for Instrumentation-Free UV Photometric Analysis Based on Photography-Based Photometry

Photography-based photometry is a technique developed to perform high throughput UV photometric analysis without instrumental detectors in resource-limited settings. Its principle relies on the illumination of a sample with UV irradiation and then capturing the transmitted irradiation on a photosensitive paper surface. Therefore, the photosensitive surface acts as a detector for the determination of the concentration of analytes in the sample. This work aims to investigate the optimum photosensitive paper coatings for capturing the transmitted UV irradiation. To this end, photosensitive coatings based on silver, iron, and dichromate salts were tested using three assays of pharmaceutical and biochemical interest. The results from both calibrations, using standard solutions and the application in real samples, show that photosensitive coatings based on iron salts provide the best results. Importantly, the detection limits and the linear range of the calibration curves were better than those obtained with standard photometry. Based on these findings, cyanotype green papers, are proposed as optimum detectors for photography-based photometry. This finding simplifies the operation of the technique enabling the fabrication of prototype readers for analytical assays performed in resource limited settings, point-of-need applications or in the field.

Printability of paper and paperboard surface treatment with gum rosin and derivatives

Purpose This study aims to provide control of liquids, especially against water-based ink on the paper and paperboard surface with natural substances, in also practical and greenway. Design/methodology/approach The paper surface was treated with natural rosin and its derivatives to obtain a hydrophobic effect and to improve printing properties. The oleoresin samples collected from Pinus nigra Arnold and Pinus pinaster Aiton trees in the controlled area and turpentine content removed was by hydrodistillation. The gum rosin (GR), fortified 10% with maleic anhydride (MGR) and esterified with 10% pentaerythritol (PMGR) samples solved in a simply alcohol and sprayed the base paper surface directly with a spray gun. Base paper samples were paperboard, bleached paper and test liner paper. Then, flexo printing was applied and printability properties were measured. Findings The treatment weights of these paper samples were 1.8 ± 0.5, 1.3 ± 0.5 and 0.7 ± 0.2 g/m2, respectively, compared to the base paper. Greater Cobb60 results were obtained from modified rosin samples than unmodified gum rosin-sized paperboards and the PMGR surface treatment reduces Cobb60 values by 20% and MGR treatment reduces 15% comparing to the base sheet. Then, the printing procedure was applied to the surface of the treated materials using a flexo printing system. As a result of the treatment better print density, chroma and print lightness value consumed a less hydrophobic agent and controlling water-based flexo ink on the base paper surface. Originality/value The unique aspect of this work was improving the hydrophobicity of the paper surfaces was achieved by spraying with natural rosin and derivatives.

Paper Doped with Polyacrylonitrile Fibres Modified with 10,12–Pentacosadiynoic Acid

This work reports a modification of a fibrous cellulose material (paper) by the addition of polyacrylonitrile (PAN) fibres doped with 10,12–pentacosadiynoic acid (PDA). The fibres are sensitive to ultraviolet (UV) light. When the paper containing PAN–PDA is irradiated with UV light it changes colour to blue as a consequence of interaction of the light with PDA. The colour intensity is related to the absorbed dose, content of PAN–PDA fibres in the paper and the wavelength of UV radiation. The features of the paper are summarised after reflectance spectrophotometry and scanning microscopy analyses. All the properties of the modified paper were tested in accordance with adequate ISO standards. Moreover, a unique method for assessing the unevenness of the paper surface and the quality of printing was proposed by using a Python script (RGBreader) for the analysis of RGB colour channels. The modification applied to the paper can serve as a paper security system. The modified paper can act also as a UV radiation indicator.

Fabrication of super-hydrophobic filter paper via mixed wax phase separation for efficient oil/water separation

Despite previous efforts, the fabrication of superhydrophobic substrate via an environment friendly and easy approach remains a great challenge. In this study, a low cost, simple, and green procedure was developed to prepare a superhydrophobic paper surface that is acceptable for the papermaking industry. First, a wax mixture (beeswax & carnauba wax) was emulsified and coated on the filter paper surface. Then, the coated paper was annealed at different temperatures. The further heat-treatment-rendered wax-coated paper hydrophobic or superhydrophobic because submicrometer or micrometer wax structures were present on the paper surface. The water contact angle of the annealed filter paper sample reached 151.5° at 60 °C, and the sliding angle was under 10°. Further, the relationship between surface composition and the hydrophobic properties of the coated paper samples was discussed. The obtained paper samples showed great potential in water/oil separation, as they had an efficiency over 99%. This work proposed a new simple and mild approach to fabricate superhydrophobic filter papers and explored the hydrophobicity and water/oil separation properties.