Microstructure Refinement on Crevice Corrosion of High-Speed Rail Steel U75V Visualized by an In Situ Monitoring System

Rail foot covered by a fastener will suffer from crevice corrosion, leading to thinning and localized attack of crevice interior posing a risk of failure. This work investigated crevice corrosion behavior of a typical pearlitic high-speed rail steel U75V, focusing for the first time on the effect of pearlitic microstructure refinement achieved by heat treatment with different cooling rates 2, 5, and 10°C/s. Under anodic polarization, localized dissolved spots presented on the as-received sample, where crevice corrosion mostly initiated from. For cooling rates 2 and 5°C/s, localized dissolved spots were also observed but crevice corrosion was mostly presented as general corrosion instead of from local spots, ascribed to enhanced tendency of uniform dissolution due to microstructure refinement and homogenization. For cooling rate 10°C/s, crevice corrosion expanded flocculently, ascribed to preferential dissolution of pearlitic nodules with entangled cementite due to over refinement. Crevice corrosion was obviously accelerated by microstructure refinement. Cooling rates 5 and 10°C/s led to the fastest and slowest expansion of the corroded area, respectively, while the corrosion depth was just the opposite based on the same amount of metal loss. This work provides important information regarding the effect of pearlitic microstructure refinement on crevice corrosion and introduces a facile method for in situ monitoring of crevice corrosion.

The Importance of Local Chemistry and Potential in Localized Corrosion and Stress-Corrosion Cracking

The nature and rates of the chemical and electrochemical reactions that occur within the occluded regions of a given alloy are controlled by the local electrochemical potential and the local solution composition. The very small physical dimensions of these regions lead to challenges in both measurement and modeling. When performed in a coordinated and complementary way, measurements and modeling provide insights into the controlling processes of a range of localized corrosion phenomena, including crevice corrosion, pitting, intergranular corrosion, and stress-corrosion cracking. Examples of attempts to overcome the measurement challenges are described for a range of corrosion scenarios, including identification of the critical ionic species in stainless steel crevice corrosion and in the corrosion of aircraft lap joints, operando measurement of chemistry and potential simultaneously within stress-corrosion cracks, and monitoring of water layer thickness in salt spray testing. Examples of work addressing the challenges in modeling localized corrosion including intergranular corrosion of AA5XXX alloys, scaling laws in crevice corrosion, the extent to which the Laplace Equation can be used and applied to geometrically complex galvanic structures, and an approach to modeling localized corrosion for extraordinarily long service times. Finally, suggestions regarding future avenues of research are provided.

The Effect of Deposited Dust on SCC and Crevice Corrosion of AISI 304L Stainless Steel in Saline Environment

Crevice corrosion has become an important issue of the safety of AISI 304L austenitic stainless steel canister when exposed to the chloride environments located in coastal areas. Moreover, dust deposited on the canister surface may enhance the corrosion effect of 304L stainless steel. In this work, white emery was adopted to simulate the dust accumulated on the as-machined specimen surface. To investigate the effect of deposited white emery, chloride concentration, and relative humidity on the crevice corrosion behavior, an experiment was conducted on 304L stainless steel specimens at 45 °C with 45%, 55%, and 70% relative humidity (RH) for 7000 h. The surface features and crack morphology of the tested 304L stainless steel specimens were examined by SEM equipped with energy-dispersive spectrometry (EDS) and electron back scatter diffraction (EBSD). From the experimental results, a threshold RH for the stress corrosion cracking (SCC) initiation of AISI 304L austenitic stainless steel with different concentrations of chloride was proposed.