Investigation of per- and polyfluoroalkyl substances (PFAS) in soils and sewage sludges by fluorine K-edge XANES spectroscopy and combustion ion chromatography

For the first time, fluorine K-edge X-ray absorption near-edge structure (XANES) spectroscopy was applied to detect per- and polyfluoroalkyl substances (PFAS) in various soil and sewage sludge samples. The method can be used to determine the speciation of inorganic and organic fluorides, without pre-treatment of solid samples. Therefore, XANES spectra of several inorganic fluorides as well as selected fluorinated organic compounds were recorded. While inorganic fluorides partially exhibit a variety of sharp spectral features in the XANES spectrum, almost all inspected organofluorine compounds show two distinct broad features at 688.5 and 692.0 eV. Moreover, the peak intensity ratio 688.5 eV/692.0 eV in the PFAS XANES spectrum can be inversely correlated to the chain length of the perfluoro sulfonic acid group. The detection of targeted PFAS by bulk-XANES spectroscopy in combination with linear combination fitting in soils and sewage sludges was not applicable due to the low organic fluorine to total fluorine ratio of the samples (0.01–1.84%). Nonetheless, direct analysis of pure PFAS revealed that analysis of organofluorine species might be achieved in higher concentrated samples. Furthermore, quantitative measurements by combustion ion chromatography (CIC) evaluated as sum parameters extractable organically bound fluorine (EOF) and total fluorine (TF) emphasize that besides soils, sewage sludges are a significant source of organic fluorine in agriculture (154–7209 µg/kg).

Complete Genome Sequence of Cupriavidus sp. Strain EM10, Isolated from Sewage Sludge

Cupriavidus species have been known as versatile microorganisms in the field of industrial biotechnology. Cupriavidus sp. strain EM10 was isolated from sewage sludges. Here, we report the complete genome sequence of this bacterium, which contains 6,658,510 bp (GC content, 65.12%) and 6,248 genes.

Scenario Analysis for Selecting Sewage Sludge-to-Energy/Matter Recovery Processes

The sewage sludges are the byproducts of the wastewater treatment. The new perspective of the wastewater value chain points to a sustainable circular economy approach, where the residual solid material produced by sewage sludge treatments is a resource rather than a waste. A sewage sludge treatment system consists of five main phases; each of them can be performed by different alternative processes. Each process is characterized by its capability to recover energy and/or matter. In this paper, a state of the art of the sludge-to-energy and sludge-to-matter treatments is provided. Then, a scenario analysis is developed to identify suitable sewage sludge treatments plants that best fit the quality and flowrate of sewage sludge to be processed while meeting technological and economic constraints. Based on the scientific literature findings and experts’ opinions, the authors identify a set of reference initial scenarios and the corresponding best treatments’ selection for configuring sewage sludge treatment plants. The scenario analysis reveals a useful reference technical framework when circular economy goals are pursued. The results achieved in all scenarios ensure the potential recovery of matter and/or energy from sewage sludges processes.