Torrefaction of Palm Kernel Shell and Petcoke Blends for Various Mixing Ratios and Temperatures

In the present study, torrefaction of palm kernel shell (PKS) and petcoke blends was performed for the production of solid biofuels with high energy density. The torrefaction process was performed for mixtures with various mixing ratios (by weight) from 90:10 to 60:40 (PKS:petcoke). For torrefaction under various temperatures of 250℃ to 300℃, the mixing ratio of 60:40 was used. Meanwhile, residence time and nitrogen flow rate were fixed at 30 minutes and 1 l/min, respectively. In general, the fixed carbon and ash contents increased, while the moisture and volatile matter contents decreased after torrefaction. It has been elucidated that mass yield is a dominant factor that affects the energy yield of torrefied mixtures rather than the higher heating value (HHV) ratio. Based on the energy yield and ultimate analysis, it was found that a higher amount of petcoke and higher temperature give better performance, thus causing the torrefied mixture to become very close to coals region in Van Krevelen diagram. In this case, the mixture with a mixing ratio of 60:40 torrefied under the temperature of 300℃ gives the best performance. It was also found that this mixture is thermally stable than the mixture torrefied at 250℃.

Use of Modified Palm Kernel Shell Particles Composite Blend with Cement or Clay as Alternative Material for Block Production

This study presents the potential of modified Palm Kernel Shell (MPKS) particles in the production of blocks as an alternative building material using cement or clay as binders. Several studies on Palm Kernel Shell (PKS) as a blend with other natural fibres/fillers found that due to its hydrophilic nature, it has low physical and mechanical capabilities in comparison to MPKS, making it less compatible with any polymeric matrix. Experimental tests were conducted to determine the physicomechanical attributes of MPKS/Cement and MPKS/Clay blocks, including characterization of the cement and clay using Atomic Absorption Spectroscopy (AAS), as well as moisture content, water absorption, hardness, apparent porosity, bulk density, compressive strength, and flake. The morphology of the samples was determined using Scanning Electron Microscope (SEM). Results show that MPKS/Cement block samples exhibit superior physicomechanical and morphological properties compared to MPKS/Clay. The MPKS/Cement block sample moisture content ranged between 4.76 – 9.94%. The 80/20 MPKS/Cement sample recorded the most water absorption at 49.5%, and a microhardness value of 82.3 Hv for the 20/80 sample. The MPKS/Clay samples showed higher values of apparent porosity but recorded the least bulk density in the 80/20 samples. The 20/80 MPKS/Cement and MPKS/Clay samples showed the best compressive strength at 63.72 and 50.3 N/mm2 respectively, while 80/20 for both cement and clay displayed very weak compressive strengths. The ratio 20/80 of MPKS/Cement is observed to be the optimum ratio where better properties of the composites were obtained. For the structure industry's long-term viability, MPKS' superior mechanical properties as an aggregate in block manufacturing make it an asset material as an alternative for some high-cost construction resources such as sand.

Development of iron ores sintering machine for blast furnace process

There must be proper means to sinter and, agglomerated iron ore concentrate before it can be further processed in the blast furnace. A Sintering machine of 5kg capacity of agglomerated ore was designed and fabricated using mild steel material, which was locally sourced. The machine was fabricated with a combustion chamber of 30 by 30 cm and with 15cm depth. It was also lined with refractory material to reduce the chamber to the volume of 3375 cm3. However, the sintering chamber was designed to have a truncated square pyramid shape to the volume of 2150 cm3 after lining with refractory material. The design was made to utilize coke and palm kernel shell char as fuel which will be ignited to produce heat into the sintered material by suction of the heat into the agglomerated sintered ore. Tests such as tumbler index, abrasion, and porosity test were carried out on the sintered products in agreement with ASTM E276 and E389 standards. The results from the test gave a tumbler index of 70.2% and 65.7% for coke and palm kernel shells respectively. Also, abrasion index of 5.1% and 4.6% for coke and palm kernel char, and porosity of 6.8% and 6.5% for coke and palm kernel char respectively. The results from the experimental test were in agreement with other research work. Therefore, the developed iron ore sintering machine has a better efficiency of producing sinter for blast furnace operation.

PHYSICO-TRIBOLOGICAL ANND WEAR MECHANISM CHARACTERISTICS OF HYBRID REINFFORCED Al6063 MATRIX COMPOSITES

The development of engineering materials is continuously attracting attention from scientists and engineers for numerous engineering applications. The physical properties and wear mechanism of aluminium (Al 6063) matrix reinforced with silicon carbide (SiC) and palm kernel shell ash (PKSA) particulates at different weight ratios ranging from 0 to 10 wt.% with 2 wt.% intervals were investigated. The liquid route of double stir casting was employed in synthesizing the composites. The wear experiment was conducted using the Taber-type wear abrasion machine. The worn surfaces were examined using scanning electron microscopy (SEM) with energy-dispersive x-ray spectroscopy (EDS), while the intermetallic phases were examined using the x-ray diffractometer (XRD). From the result, the increase in PKSA and SiC lowered and improved the density of the composites, respectively. The percentage porosity values (2 - 2.4%) obtained in this study were found to be within the acceptable limit of less than 4% for metal matrix composites castings. The mass loss and wear index increased owing to the rotating speed and applied load increase, resulting from the occurrence of mechanical mixing between the contacting surface of the sample disk and the machined disc. Adhesive and abrasive wear mechanisms were the major mechanisms observed in this study.