Effect of Aluminum Incorporation on the Reaction Process and Reaction Products of Hydrated Magnesium Silicate

In this study, we investigated the impact of aluminium ion (Al3+) incorporation on the microstructure and the phase transformation of the magnesium silicate hydrate system. The magnesium silicate hydrate system with aluminium was prepared by mixing magnesium oxide and silica fume with different aluminium ion contents (the Al/Si molar ratios of 0.01, 0.02, 0.05, 0.1, 0.2) at room temperature. The high degree of polymerization of the magnesium silicate hydrate phases resulted in the limited incorporation of aluminium in the structure of magnesium silicate hydrate. The silicon-oxygen tetrahedra sites of magnesium silicate hydrate layers, however, were unable to substitute for silicon sites through inverted silicon-oxygen linkages. The increase in aluminium ion content raised the degree of polymerization of the magnesium silicate hydrate phases from 0.84 to 0.92. A solid solution was formed from residual aluminum-amorphous phases such as hydroxyl-aluminum and magnesium silicate hydrate phases. X-ray diffraction (XRD), field emission scanning electron microscope (F-SEM), and 29Si and 27Al MAS NMR data showed that the addition of Al3+ promotes the hydration process of MgO and has an obvious effect on the appearance of M-S-H gel. The gel with low aluminum content is fluffy, while the gel with high aluminum content has irregular flakes. The amount of Al3+ that enters the M-S-H gel increased with the increase of Al3+ content, but there was a threshold: the highest Al/Si molar ratio of M-S-H gel can be maintained at about 0.006.

Environmental and Household-Based Spatial Risks for Tungiasis in an Endemic Area of Coastal Kenya

Tungiasis is a cutaneous parasitosis caused by an embedded female sand flea. The distribution of cases can be spatially heterogeneous even in areas with similar risk profiles. This study assesses household and remotely sensed environmental factors that contribute to the geographic distribution of tungiasis cases in a rural area along the Southern Kenyan Coast. Data on household tungiasis case status, demographic and socioeconomic information, and geographic locations were recorded during regular survey activities of the Health and Demographic Surveillance System, mainly during 2011. Data were joined with other spatial data sources using latitude/longitude coordinates. Generalized additive models were used to predict and visualize spatial risks for tungiasis. The household-level prevalence of tungiasis was 3.4% (272/7925). There was a 1.1% (461/41,135) prevalence of infection among all participants. A significant spatial variability was observed in the unadjusted model (p-value < 0.001). The number of children per household, earthen floor, organic roof, elevation, aluminum content in the soil, and distance to the nearest animal reserve attenuated the odds ratios and partially explained the spatial variation of tungiasis. Spatial heterogeneity in tungiasis risk remained even after a factor adjustment. This suggests that there are possible unmeasured factors associated with the complex ecology of sand fleas that may contribute to the disease’s uneven distribution.

Comparative Quality Analysis between Tap Water and Bottled Water

Recently, bottled water consumption has been increasing significantly, even when the quality of tap water is considered excellent, which contributes to plastic pollution. Besides, reducing the use of plastic generally is recommended world widely, as its consumption is in an alarming rate. Therefore, this study aims to compare the tap and bottled water and manifest the reasons behind choosing the bottled water, which is less comfortable and often more expensive over the tap water. In this study, samples have been taken from both bottled and tap water in Koya city from November 2020 to May 2021 to test their quality using PH, DO, EC, and TDS meter, hardness was determined by complexometric titration method at 21°C, and XRF spectrometers. According to the quality standards, most of the variables were in a permissible range, except for dissolved oxygen and Aluminum content in both types of water and TDS for two types of bottled water. However, the quality of tap water was much safer to be used, as compared with the bottled water.

Influence of the aluminum content on the luminescent and electronic properties of β-Ga2O3

In this work, we investigated bulk β-Ga2O3 samples grown by the Czochralski method on Al2O3 and β-Ga2O3 seeds. The elemental composition of the samples and its effect on the luminescent and electrophysical properties of the samples were determined. The Kelvin probe microscopy was used to study the processes of localization and dissipation of charges in the samples. It was shown that in a β-Ga2O3 sample grown on an Al2O3 seed, the characteristic charge dissipation time is 10 times longer.

STRUCTURE AND PHASE COMPOSITION OF COATING ON EP718 ALLOY AFTER HOT-DIP ALUMINIZING

The results of studies of the structure, chemical and phase composition of the aluminide coating formed on the surface of EP718 alloy after its hot-dip aluminizing are presented. It is shown that the inner layer of the coating consists of a continuous layer of a solid solution based on chromium aluminide CrAl with a monoclinic lattice, in which some of the Cr atoms are replaced by atoms of elements from the EP718 alloy, and the outer layer, which has a pronounced heterogeneous structure, is an aluminum matrix with inclusions of CrAl aluminide. with a lower aluminum content.

Microstructural Evolution as a Function of Increasing Aluminum Content in Novel Lightweight Cast Irons

In the context of the development of new lightweight materials, Al-alloyed cast irons have a great potential for reducing the weight of the different part of the vehicles in the transport industry. The correlation of the amount of Al and its effect in the microstructure of cast irons is not completely well established as it is affected by many factors such as chemical composition, cooling rate, etc. In this work, four novel lightweight cast irons were developed with different amounts of Al (from 0 wt. % to 15 wt. %). The alloys were manufactured by an easily scalable and affordable gravity casting process in an induction furnace, and casted in a resin-bonded sand mold. The microstructural evolution as a function of increasing Al content by different microstructural characterization techniques was studied. The hardness of the cast irons was measured by the Vickers indentation test and correlated with the previously characterized microstructures. In general, the microstructural evolution shows that the perlite content decrease with the increment of wt. % of Al. The opposite occurs with the ferrite content. In the case of graphite, a slight increment occurs with 2 wt. % of Al, but a great decrease occurs until 15 wt. % of Al. The addition of Al promotes the stabilization of ferrite in the studied alloys. The hardness obtained varied from 235 HV and 363 HV in function of the Al content. The addition of Al increases the hardness of the studied cast irons, but not gradually. The alloy with the highest hardness is the alloy containing 7 wt. % Al, which is correlated with the formation of kappa-carbides and finer perlite.

Potentialities and limitations of Planosols with distinct depths of diagnostic horizon

There is a variation in the depth of subsurface horizon of Planosols in semi-arid region, which may influence the agricultural potential and affect food production. The general aim of this study was to identify potentialities and limitations of two Planosols as a function of subsurface horizon depth. The adjacent profiles P1 and P2 were studied in Pentecoste (Ceará, Brazil). Morphological, physical, and chemical analyses were done aiming at soil characterization. Soil bulk density (BD), porosity, and penetration resistance (PR) were analyzed in a completely randomized split-plot design with four replicates to compare P1 and P2 and the horizons Ap and Btf. Btf was found at 62cm depth in P1 and at 18 cm depth in P2. Indicatives of water saturation were more evident in P2. The profile P1 showed lower hardness and higher friability, as well as higher acidity in subsurface (pHH2O from 4.4 to 4.7) and higher aluminum content (1.2cmolc kg-1). Both profiles were eutrophic and showed low contents of organic carbon (1.5 to 8.5g kg-1) and phosphorus (0.9 to 3.9mg kg-1). The sodium percentage in CEC was 9.1% in P1 and 5.5% in P2. Water retention increases in Btf compared with Ap was 7.3% in P2 and 2.7% in P1. Both profiles showed increase in BD in Btf, reaching 1.7g cm-3, while PR was higher in P2 (1.5 MPa). There are potentialities and limitations common to both soil profiles, but P1 has more physical potentialities and more chemical limitations than P2.