Metal-Organic Frameworks (MOFs) as Fuels for Advanced Applications: Evaluating and Modifying the Combustion Energy of Popular MOFs

Systematic investigation of combustion energies for popular metal-organic frameworks (MOFs) reveals energy content comparable to conventional energetic materials and can be further modified and dine-tuned by polymorphism and isostructural ligand replacement to yield materials with energy densities comparable to Diesel or kerosene.<br>

Metal-Organic Frameworks (MOFs) as Fuels for Advanced Applications: Evaluating and Modifying the Combustion Energy of Popular MOFs

Systematic investigation of combustion energies for popular metal-organic frameworks (MOFs) reveals energy content comparable to conventional energetic materials and can be further modified and dine-tuned by polymorphism and isostructural ligand replacement to yield materials with energy densities comparable to Diesel or kerosene.<br>

A luminescent edge-interlocked prismatic heteroleptic metallocage assembled through a ligand replacement reaction

A luminescent edge-interlocked heteroleptic metallocages based on Cu3(pyrazolate)3 was prepared through a ligand replacement reaction from a homoleptic metallocage and a new ligand.

Unequal coordination environment in complexes of the type [Au2Ag2(R)4(L)2]n. An immiscible solvent mixture as a key point in the control of ligand replacement

A new photoluminescent heterometallic polymer [Au6Ag6(C6Cl2F3)12(μ2-pym)2(NCMe)6]n (2) with three different coordination environments has been synthesised.

Host–guest driven ligand replacement on monodisperse inorganic nanoparticles

We demonstrate that crown ether-assisted ligand replacement on Fe3O4 NPs using halide salts leads to quantitative stripping of an existing stabilizer shell with unprecedented (complete) efficiency; this allows subsequent re-grafting of functional ligands at maximal surface density.