Investigation of Electrochemical Performance and Gas Swelling Behavior on Li4Ti5O12/Activated Carbon Lithium-Ion Capacitor with Acetonitrile-Based and Ester-Based Electrolytes

Lithium-ion capacitors (LICs) have gained significant attention due to the combination on the advantages of electric double-layer capacitors (EDLCs) and lithium-ion batteries (LIBs). Herein, the LIC pouch cell was fabricated by an activated carbon (AC) cathode and a Li4Ti5O12 (LTO) anode. Two organic electrolytes (1 mol L−1 LiBF4/acetonitrile (AN) and 1 mol L−1 LiPF6/ ethylene carbonate (EC) + ethyl methyl carbonate (EMC) + dimethyl carbonate (DMC)) were chosen and the gas swelling behavior was studied. Compared with the ester-based LIC, the AN-based LIC displays higher energy density of 13.31 Wh kg−1 at 11.4 W kg−1 and even provides a value of 9.1 Wh kg−1 at 1075 W kg−1. Because of the lower DC Resistance of 0.761 mΩ, the maximum power density of the AN-based LIC reaches 12.5 kW kg−1. The AN-based LIC delivers good stability with an energy retention of 88.3% after 900 cycles. It is discovered that the swelling behavior of AN-based LICs is more serious and the major component is H2. The difference of swelling behavior among the LICs, lithium nickel cobalt manganese oxide (NCM)/LTO LIB and AC/AC EDLC is proposed to be caused by the AC electrode and the interfacial reaction of LTO.

Sorting for secreted molecule production using a biosensor-in-microdroplet approach

Sorting large libraries of cells for improved small molecule secretion is throughput limited. Here, we combine producer/secretor cell libraries with whole-cell biosensors using a microfluidic-based screening workflow. This approach enables a mix-and-match capability using off-the-shelf biosensors through either coencapsulation or pico-injection. We demonstrate the cell type and library agnostic nature of this workflow by utilizing single-guide RNA, transposon, and ethyl-methyl sulfonate mutagenesis libraries across three distinct microbes (Escherichia coli, Saccharomyces cerevisiae, and Yarrowia lipolytica), biosensors from two organisms (E. coli and S. cerevisiae), and three products (triacetic acid lactone, naringenin, and L-DOPA) to identify targets improving production/secretion.

Influences of Chemical Functionalities on Crystal Structures and Electrochemical Properties of Dihydro-benzoxazine Dimer Derivatives

Dihydro-1,3,2H-benzoxazine dimer derivatives or dihydro-benzoxazine dimers are a class of compounds typically prepared by ring-opening reactions between dihydro-benzoxazines and phenols. Dihydro-benzoxazine dimers act as chelating agents for several transition and rare-earth cations. To better understand the chelating properties, it is necessary to examine their structural features and electrochemical characteristics thoroughly. However, the electrochemical properties of dihydro-benzoxazine dimers have not been tremendously examined. Herein, eight derivatives of dihydro-benzoxazine dimers possessing different substituents on the benzene ring and the tertiary-amine nitrogen were synthesized as model compounds to investigate their influences on crystal structures and electrochemical properties. The crystal structure of the dihydro-benzoxazine dimer, namely 2,2’-(cyclohexylazanediyl)bis(methylene)bis(4-methoxyphenol) (7), is identified for the first time and further used to compare with the crystal structures of other derivatives reported previously. For all the derivatives, intermolecular O–H···O hydrogen bonds are the significant interactions to hold the crystal packing of (7) and also the other derivatives. Hirshfeld surface analyses confirm the presence of intermolecular O–H···O hydrogen bonds. Redox behavior of the eight dihydro-benzoxazine dimers was studied by cyclic voltammetry. An oxidation peak observed at 0.25–0.47 V corresponds to the oxidation of the phenolic –OH group to the phenoxonium intermediate. The shift in the electrochemical peak positions is due to the different abilities of the substituents to stabilize the phenoxonium cation intermediate. The stabilizing power is ranged in the following order: methoxy > dimethyl > ethyl ≈ methyl, and N-cyclohexyl > N-methyl. Thus, the derivative (7), which contains both the methoxy and N-cyclohexyl groups, has the lowest oxidation potential. Our work elucidates the effect of the substituents on the crystal structures and electrochemical properties of the dihydro-benzoxazine dimers.

Strategy and choice criteria’s of initial disturbances of brain circulation in family physician’s practice

In the present paper a modern sights to manifestations of initial stages of brain ischemia and its role in damage of CNS in cerebrovascular pathology have been looked. Based on this point of view, the requirements to choice of optimal pharmacological strategy concerning correction of brain pathological changes during ischemia, and particularly neurometabolic pharmacotherapy’ advantages have been analyzed. A basic goals of clinical use of neuroprotection’s strategy in generally, and particularly neurometabolic pharmacotherapy have been looked. A main attention paid to mechanisms of action and peculiarities of clinical use of drug Dinar (ethyl-methyl-hydroxypiridine succinat) and its possibilities in plane to realization of pathogenetically grounding neurometabolic pharmacotherapy of initial stages of cerebrovascular pathology. A clinical efficacy of Dinar and its safety characteristics have been looked in detail.

Candidate Gene, SmCPR1, Encoding CPR1 Related to Plant Height of the Eggplant Dwarf Mutant dwf

Eggplant is a vegetable crop with high economic value that is cultivated worldwide. The dwarf mutant is an important germplasm material that has been extensively used in crop breeding. However, no eggplant dwarf mutants have been reported, and little is known regarding the genes responsible for dwarfism in eggplant. In this study, we isolated an eggplant dwarf mutant (dwf) from an ethyl methyl sulfonate (EMS)-induced mutant library. Genetic analysis revealed that dwf was caused by a single recessive gene. A candidate gene SmCPR1, encoding cytochrome P450 reductases (CPR1), was identified by bulked segregant analysis (BSA). Mutation from G to A at 8216 bp of SmCPR1 resulted in mutation of the amino acid from valine to isoleucine. The results of KASP and Sanger sequencing further support the conclusion that SmCPR1 is a candidate gene responsible for the dwarfism of dwf. Moreover, the activity of SmCPR1 was significantly increased in dwf, which might be a response to dwarfism in dwf.

Coffee berry borer (Hypothenemus hampei Ferrari) trapping in coffee (Coffea arabica L.) with artisan traps at el Paraíso, Guerrero, Mexico

Objective: To evaluate three proportions of alcohol in traps with one and three windows and two different colors to capture Hypothenemus hampei Ferrari in Coffea arabica L. plants. Design/methodology/approach: The experiment followed a completely randomized design with a complete factorial arrangement and four replications. From March to July 2007, three mixtures of ethyl: methyl alcohol were evaluated in different proportions (1: 0, 0: 1 and 1: 1). In addition, green and transparent traps were used, designed with a single or three windows. The number of captured coffee berry borers, water loss, attractant evaporation and damaged fruits percentage was evaluated. The data were analyzed through an analysis of variance and a test of means differences (Tukey, p ? 0.05). Results: The mixture of ethyl: methyl alcohol 1: 1 was the best, with an average catch of 980 trapped - insects week-1. The single window of transparent color traps was the most efficient to avoid water loss, with an average loss of 1,129.79 mL and 905 mL respectively. Limitations on study/implications: The design and color of the traps did not influence the capture efficiency and the evaporation of the attractant during the evaluated months. Therefore, it should be further evaluated during other important phenological stages for the crop. Findings/conclusions: Transparent color traps with a window and 1: 1 ethyl: methyl alcohol were efficient for capturing H. hampei and lowering their population.