Development of Liquid Diene Rubber Based Highly Deformable Interactive Fiber-Elastomer Composites

The preparation of intelligent structures for multiple smart applications such as soft-robotics, artificial limbs, etc., is a rapidly evolving research topic. In the present work, the preparation of a functional fabric, and its integration into a soft elastomeric matrix to develop an adaptive fiber-elastomer composite structure, is presented. Functional fabric, with the implementation of the shape memory effect, was combined with liquid polybutadiene rubber by means of a low-temperature vulcanization process. A detailed investigation on the crosslinking behavior of liquid polybutadiene rubber was performed to develop a rubber formulation that is capable of crosslinking liquid rubber at 75 °C, a temperature that is much lower than the phase transformation temperature of SMA wires (90–110 °C). By utilizing the unique low-temperature crosslinking protocol for liquid polybutadiene rubber, soft intelligent structures containing functional fabric were developed. The adaptive structures were successfully activated by Joule heating. The deformation behavior of the smart structures was experimentally demonstrated by reaching a 120 mm bending distance at an activation voltage of 8 V without an additional load, whereas 90 mm, 70 mm, 65 mm, 57 mm bending distances were achieved with attached weights of 5 g, 10 g, 20 g, 30 g, respectively.

Experimental Analysis of Viscoelastic Properties of Room Temperature Vulcanized Silicone based Magnetorheological Elastomer

Magnetorheological Elastomers (MRE) endure a change in mechanical properties with the application of an externally applied magnetic field. It consists of an elastomeric matrix reinforced with ferromagnetic powdered particles. This paper focuses on the investigation of viscoelastic properties of Room Temperature Vulcanized (RTV) silicone based isotropic MRE in sandwich beam configuration by varying the volume percentage of Carbonyl Iron Powdered (CIP) reinforcement. Viscoelastic properties of the MRE core material were calculated by following the ASTM E756-05 standard. The magnetic field was applied by employing a Halbach array which was numerically analyzed using Finite Element Method Magnetics (FEMM). The magnetic field was varied up to 0.15 T. Loss factor and shear modulus were found to be strongly influenced by the percentage content of CIP. The loss factor and shear modulus of 30% MRE at 0.15 T were higher than other tested samples. The variation of natural frequency with respect to the addition of CIP was validated numerically using Modal analysis conducted in Hyperworks.

Influence of the curing system on the physical-mechanical, dynamic properties, and aging resistance of ethylene–propylene–diene monomer formulations for applications at high temperatures

The effects of three curing systems on rheometric, morphological, physical-mechanical, thermal, and dynamic properties of ethylene–propylene–diene monomer (EPDM) composites was investigated. The influence of thermo-oxidative aging on crosslink density and physical-mechanical properties was studied. Based on a standard composition for application at high temperatures, EPDM formulations with semi-efficient vulcanization systems (ES), efficient vulcanization systems (ED), and peroxide curing systems (EP) were prepared. Experimental results indicated that EPDM compounds cured with efficient vulcanization systems exhibit the highest scorch time with an intermediate maximum torque value at 150°C. The filler dispersion in the elastomeric matrix was greater than 94%; however, the ED formulation showed a more pronounced decrease, with the increase in deformation indicating a greater filler–filler interaction. In comparison with those cured with peroxide and semi-efficient systems, EPDM formulations cured with an efficient system presented better thermal resistance and the crosslink density was sufficient to maintain the mechanical integrity, leading to an intermediate hardness value, tensile strength, modulus, and greater elongation at breaking. In summary, the results indicated that the efficient curing system was the most appropriate to be used in the envelope’s manufacture, due to the better performance of the mechanical properties associated with the better resistance to thermal aging.

Monolithic Stacked Dielectric Elastomer Actuators

Dielectric elastomer actuators (DEAs) are a promising actuator technology for soft robotics. As a configuration of this technology, stacked DEAs afford a muscle-like contraction that is useful to build soft robotic systems. In stacked DEAs, dielectric and electrode layers are alternately stacked. Thus, often a dedicated setup with complicated processes or sometimes laborious manual stacking of the layers is required to fabricate stacked actuators. In this study, we propose a method to monolithically fabricate stacked DEAs without alternately stacking the dielectric and electrode layers. In this method, the actuators are fabricated mainly through two steps: 1) molding of an elastomeric matrix containing free-form microfluidic channels and 2) injection of a liquid conductive material that acts as an electrode. The feasibility of our method is investigated via the fabrication and characterization of simple monolithic DEAs with multiple electrodes (2, 4, and 10). The fabricated actuators are characterized in terms of actuation stroke, output force, and frequency response. In the actuators, polydimethylsiloxane (PDMS) and eutectic gallium–indium (EGaIn) are used for the elastomeric matrix and electrode material, respectively. Microfluidic channels are realized by dissolving a three-dimensional printed part suspended in the elastomeric structure. The experimental results show the successful implementation of the proposed method and the good agreement between the measured data and theoretical predication, validating the feasibility of the proposed method.

Study of new elastomeric composite systems containing wood ash based alternative filler

The presented paper deals with the preparation of the new types of elastomeric composite systems containing an alternative filler based on wood ash or fly ash. Wood ash (fly ash) is generated as the waste from the process of wood pellets burning in the pellet boilers. The results of the EDX analysis confirmed that CaO and SiO2 are the most represented components of wood ash, which contains commonly used white fillers, such as kaolin or silica. Therefore, wood ash was used as an alternative ecological filler in a function of a partial replacement for the commonly used carbon black filler in the elastomer systems. Rheological properties and cure characteristics of prepared elastomer composite systems and tensile properties of resulting vulcanizates have been studied. The prepared elastomeric systems were also subjected to a Payne effect study. The obtained results showed the degree of filler - filler interactions as well as the degree of mutual interactions between alternative filler particles and elastomeric matrix.

Supramolecular Self-Healing Sensor Fiber Composites for Damage Detection in Piezoresistive Electronic Skin for Soft Robots

Self-healing materials can prolong the lifetime of structures and products by enabling the repairing of damage. However, detecting the damage and the progress of the healing process remains an important issue. In this study, self-healing, piezoresistive strain sensor fibers (ShSFs) are used for detecting strain deformation and damage in a self-healing elastomeric matrix. The ShSFs were embedded in the self-healing matrix for the development of self-healing sensor fiber composites (ShSFC) with elongation at break values of up to 100%. A quadruple hydrogen-bonded supramolecular elastomer was used as a matrix material. The ShSFCs exhibited a reproducible and monotonic response. The ShSFCs were investigated for use as sensorized electronic skin on 3D-printed soft robotic modules, such as bending actuators. Depending on the bending actuator module, the electronic skin was loaded under either compression (pneumatic-based module) or tension (tendon-based module). In both configurations, the ShSFs could be successfully used as deformation sensors, and in addition, detect the presence of damage based on the sensor signal drift. The sensor under tension showed better recovery of the signal after healing, and smaller signal relaxation. Even with the complete severing of the fiber, the piezoresistive properties returned after the healing, but in that case, thermal heat treatment was required. With their resilient response and self-healing properties, the supramolecular fiber composites can be used for the next generation of soft robotic modules.

PDMS Sponges with Embedded Carbon Nanotubes as Piezoresistive Sensors for Human Motion Detection

Porous piezoresistive sensors offer promising flexible sensing functionality, such as human joint motion detection and gesture identification. Herein, a facile fabrication method is developed using a microwave-based rapid porogen removal technique for the manufacturing of porous nanocomposite sponges consisting of polydimethylsiloxane (PDMS) and well-dispersed carbon nanotubes (CNTs). The porogen amounts and CNT loadings are varied to tailor the porosity and electrical properties of the porous sensors. The sponges are characterized by a scanning electron microscope (SEM) to compare their microstructures, validate the high-quality CNT dispersion, and confirm the successful nanofiller embedding within the elastomeric matrix. Sponges with a 3 wt% CNT loading demonstrate the highest piezoresistive sensitivity. Experimental characterization shows that the sponges with low porosity have long durability and minimal strain rate dependence. Additionally, the developed sponges with 3 wt% CNTs are employed for the human motion detection using piezoresistive method. One experiment includes fingertip compression measurements on a prosthetic hand. Moreover, the sensors are attached to the chest, elbow, and knee of a user to detect breathing, running, walking, joint bending, and throwing motions.

Application of 4,4'-dihydroxydiphenylsulfone and its polymethylol derivative as additives in elastomeric materials

One of the ways to improve the quality of elastomeric materials is the modification of the elastomeric matrix as well as the use of multifunctional ingredients that can function as stabilizers, vulcanizing group components and compatibilizers (i.e. substances that increase compatibility in polymer heterogeneous systems). Compounds that can be used as binders in composite materials of different composition and ensure the environmental friendliness of their production and application are considered to be promising. Among such compounds, the reaction products of 4,4'-dioxydiphenylsulfone with formaldehyde attract a particular interest since they have a lower degree of toxicity than the phenol-formaldehyde resins. This work revealed the effect of 1, 2, and 4 parts by weight of 4,4'-dihydroxydiphenylsulfone and its polymethylol derivative on technological and physical-mechanical properties of elastomeric compositions. We showed the stabilizing activity of the investigated additives in rubbers based on carbochain unsaturated rubbers. The surface of the crushed vulcanizate was modified. It was determined that the addition of modified crushed vulcanizate to the composition of rubber mixtures improves the quality of rubbers. We showed the possibility of replacing traditional anti-aging agents without deterioration of the properties of finished products.

The structure of carbon nanotubes in a polymer matrix

We carried out an analytical structural analysis of interfacial effects and differences in the reinforcing ability of carbon nanotubes for polydicyclopentadiene/carbon nanotube nanocomposites with elastomeric and glassy matrices. In general, it showed that the reinforcing (strengthening) element of the structure of polymer nanocomposites is a combination of the nanofiller and interfacial regions. In the polymer matrix of the nanocomposite, carbon nanotubes form ring-like structures. Their radius depends heavily on the volume content of the nanofiller. Therefore, the structural reinforcing element of polymer/carbon nanotube nanocomposites can be considered as ring-like formations of carbon nanotubes coated with an interfacial layer. Their structure and properties differ from the characteristics of the bulk polymer matrix.According to this definition, the effective radius of the ring-like formations increases by the thickness of the interfacial layer. In turn, the level of interfacial adhesion between the polymer matrix and the nanofiller is uniquely determined by the radius of the specified carbon nanotube formations. For the considered nanocomposites, the elastomeric matrix has a higher degree of reinforcement compared to the glassy matrix, due to the thicker interfacial layer. It was shown that the ring-like nanotube formations could be successfully modelled as a structural analogue of macromolecular coils of branched polymers. This makes it possible to assess the effective (true) level of anisotropy of this nanofiller in the polymer matrixof the nanocomposite. When the nanofiller content is constant, this level, characterised by the aspect ratio of the nanotubes, uniquely determines the degree of reinforcement of the nanocomposites