metal metal bonds
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Anti-Electrostatic Main Group Metal–Metal Bonds That Activate CO2

2021 ◽  
pp. 7545-7552
Author(s):  
Chuan-Kai Tang ◽  
Ya-Zhou Li ◽  
Fang Ma ◽  
Zexing Cao ◽  
Yirong Mo
Keyword(s):  
Main Group ◽  
Group Metal ◽  
Main Group Metal ◽  
Metal Metal ◽  
Metal Metal Bonds ◽  
Metal Bonds

Lantern‐Type Divanadium Complexes with Bridging Ligands: Short Metal‐Metal Bonds with High Multiple Bond Orders

ChemPhysChem ◽  
2021 ◽  
Author(s):  
Derek R. Langstieh ◽  
Richard Hmingliana Duncan Lyngdoh ◽  
R. Bruce King ◽  
Henry F. Schaefer
Keyword(s):  
Multiple Bond ◽  
Bond Orders ◽  
Bridging Ligands ◽  
Metal Metal ◽  
Metal Metal Bonds ◽  
Metal Bonds

Metal−Metal Bonds in Polyoxometalate Chemistry

Nanoscale ◽  
2021 ◽  
Author(s):  
Aleksandar Kondinski
Keyword(s):  
Metal Bonding ◽  
Metal Metal ◽  
Metal Metal Bonds ◽  
Metal Bonds

Half a century ago, F. Albert Cotton emphasized the relevance of metal-metal bonding in the constitution of cluster materials. Based on his description, nanoscale polyoxometalates (POMs) normally would not be...

Dysprosium complexes bearing unsupported DyIII–GeII/SnIImetal–metal bonds as single-ion magnets

2019 ◽  
Vol 55 (57) ◽  
pp. 8250-8253 ◽  
Author(s):  
Shi-Ming Chen ◽  
Jin Xiong ◽  
Yi-Quan Zhang ◽  
Fang Ma ◽  
Hao-Ling Sun ◽  
...  
Keyword(s):  
Slow Relaxation ◽  
Blocking Temperature ◽  
Zero Field ◽  
Energy Barriers ◽  
Metal Metal ◽  
Metal Metal Bonds ◽  
Metal Bonds

We report here two dysprosium complexes bearing unsupported Dy–Ge/Sn metal–metal bonds which contain relatively large covalency. Both complexes can exhibit slow relaxation of magnetization at zero field with energy barriers of 485 and 620 K, respectively, and the blocking temperature of 6 K.

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