Структурный переход в пленках триацетата целлюлозы

Electron microscopy data are used to comparative analysis of the topological structure of the surface of two samples of cellulose triacetate (СTA) films. The samples were obtained from CTA solutions without use (sample №1) and with the use of a small sodium fluoride additive that lowers the viscosity of the solution (sample №2). It is shown that in sample №1, the nodes of the physical network of macromolecules are periodically alternating regions of local orientation order - microdomains of average size d~18 nm. In sample №2, due to repackaging of microdomains on the scale R >d, a uniformly disordered fractal cluster of the mesophase CTA is formed. The fractalization of the surface and the growth of structural anisotropy are consistent with the decrease in the viscosity of the solution and explain the change in the deformation properties of sample №2 compared to №1.

Student perceptions of the classroom environment, student characteristics, and motivation for music lessons at secondary school

The literature suggests that there is often no alignment between student preferences and what and how it is taught in the music classroom. A total of 749 Cypriot secondary school students, aged 12 to 14 years, responded to a survey addressing enjoyment of music, motivation for school music lessons, and perceptions of the music classroom environment. The survey included a questionnaire with six subscales: Involvement, Affiliation, Teacher Support, Task Orientation, Order and Organization, and Rule Clarity. High ratings for Affiliation, Teacher Support, and Rule Clarity suggest that, overall, students’ perceptions of the classroom environment were positive. They were not uniform, but varied on the basis of student characteristics. Girls rated Rule Clarity higher than boys. Younger students tended to rate Task Orientation, Order and Organization, and Rule Clarity higher than older students. Higher-achieving students tended to rate Affiliation and Teacher Support higher. Older boys rated Involvement lower than younger boys, whereas older girls rated Involvement higher than younger girls. It can be inferred that boys experienced a gradual increase in perceived Affiliation as their achievement improved, although the pattern was less consistent for girls. Girls tended to report higher motivation for school music lessons than boys. Motivation was enhanced by classroom environments in which students experienced higher levels of enjoyment of music, engagement, and support from teachers. The findings show that the music classroom environment should be characterized by student engagement, clarity of rules, good organization, clear goals, teacher support, and affiliation between classmates.

Orientation order parameters and effective conductivity of a 2-D solid with partially disordered array of circular inhomogeneities

The paper focuses on the quantitative characterization of the microstructure of a two-dimensional heterogeneous solid with circular inhomogeneities that may vary from perfectly periodic arrangement to completely random one. This characterization is linked to the calculation of the effective conductivity of the material. The partially disordered system of disks is generated in the framework of the representative unit cell model using Metropolis algorithm. The orientation order metrics are taken as the structural parameters providing a quantitative measure of disorder, and their variation caused by the gradual disordering of the periodic system is assessed. The effective conductivity of the heterogeneous solid with partially disordered microstructure is evaluated by the multipole expansion method. It is shown that effective conductivity cannot be fully characterized by only one orientation order metric, and the required additional ones are identified.

Off the Grid... and Back Again? The Recent Evolution of American Street Network Planning and Design

This morphological study identifies and measures recent nationwide trends in American street network design. Historically, orthogonal street grids provided the interconnectivity and density that researchers identify as important factors for reducing vehicular travel and emissions and increasing road safety and physical activity. During the 20th century, griddedness declined in planning practice alongside declines in urban form compactness, density, and connectivity as urbanization sprawled around automobile dependence. But less is known about comprehensive empirical trends across US neighborhoods, especially in recent years. This study uses public and open data to examine tract-level street networks across the entire US. It develops theoretical and measurement frameworks for a quality of street networks defined here as griddedness. It measures how griddedness, orientation order, straightness, 4-way intersections, and intersection density declined from 1940 through the 1990s while dead-ends and block lengths increased. However, since 2000, these trends have rebounded, shifting back toward historical design patterns. Yet, despite this rebound, when controlling for topography and built environment factors all decades post-1939 are associated with lower griddedness than pre-1940. Higher griddedness is associated with less car ownership—which itself has a well-established relationship with vehicle kilometers traveled and greenhouse gas emissions—while controlling for density, home and household size, income, jobs proximity, street network grain, and local topography. Interconnected grid-like street networks offer practitioners an important tool for curbing car dependence and emissions. Once established, street patterns determine urban spatial structure for centuries, so proactive planning is essential.

Urban Spatial Order: Street Network Orientation, Configuration, and Entropy

Street networks may be planned according to clear organizing principles or they may evolve organically through accretion, but their configurations and orientations help define a city’s spatial logic and order. Measures of entropy reveal a city’s streets’ order and disorder. Past studies have explored individual cases of orientation and entropy, but little is known about broader patterns and trends worldwide. This study examines street network orientation, configuration, and entropy in 100 cities around the world using OpenStreetMap data and OSMnx. It measures the entropy of street bearings in weighted and unweighted network models, along with each city’s typical street segment length, average circuity, average node degree, and the network’s proportions of four-way intersections and dead-ends. It also develops a new indicator of orientation-order that quantifies how a city’s street network follows the geometric ordering logic of a single grid. A cluster analysis is performed to explore similarities and differences among these study sites in multiple dimensions. Significant statistical relationships exist between city orientation-order and other indicators of spatial order, including street circuity and measures of connectedness. On average, US/Canadian study sites are far more grid-like than those elsewhere, exhibiting less entropy and circuity. These indicators, taken in concert, help reveal the extent and nuance of the grid. These methods demonstrate automatic, scalable, reproducible tools to empirically measure and visualize city spatial order, illustrating complex urban transportation system patterns and configurations around the world.