This paper focuses on Piano Key Weirs (PKWs) as an effective solution for improving the discharge capacity of spillway systems. The flow behavior in inlet and outlet keys is experimentally studied to analyze the discharge capacity of PKWs with different plan shapes (i.e., rectangular, trapezoidal, and triangular). The results show that in outlet keys, the flow aeration regimes extend to higher values of headwater ratios (Ho/P) by increasing the length magnification ratio (B/w) and apex width ratio (A/w). In addition, the local submergence length is a decreasing function of A/w, especially in high flow heads. While the total interference length enlarges by reducing A/w in lower Ho/P values (Ho/P < 0.5), a reverse trend is observed in higher headwater ratios. PKW performance may also be impacted by the flow contraction and recirculation zone in inlet keys, which intensify in higher values of Ho/P, B/w, and A/w. According to the obtained results, while the discharge coefficient is a decreasing function of A/w in Ho/P > 0.4, it may have a reverse trend in lower head conditions. In addition, a trapezoidal PKW has the highest discharge efficiency in a wide range of the studied domain (Ho/P > 0.25 and B/w ≥ 2). It can improve the discharge efficiency by around 5%, while its body volume is almost 7% smaller than the traditional rectangular PKW. However, for low-length and high-head conditions (B/w = 1 and Ho/P > 0.5), the efficiency a rectangular PKW exceeds that of the other shapes.