Effect of Deep Cryogenic Treatment on Corrosion Behavior of AISI H13 Die Steel

AISI H13 die steel specimens were subjected to heating at 1020 °C followed by oil quenching and double tempering at 520 °C. Subsequently, these specimens were subjected to deep cryogenic treatment at −185 °C in liquid nitrogen environment for 16 h and then subjected to soft tempering at 100 °C once the specimens attained room temperature. Thereafter, the specimens were subjected to scanning electron microscopy (SEM) analysis and electron backscatter diffraction (EBSD) analysis. The electrochemical corrosion activity was investigated in 3.5% NaCl at 23 ± 0.5 °C by evaluating the evolution of open circuit potential over time and potentiodynamic curves, and electrochemical impedance spectroscopy study was also carried out. The heat-treated specimens exhibited better resistance to corrosion through more electropositive values of open circuit potential. This could be attributed to lower grain boundary area in heat-treated specimens as compared to 16 h cryogenically treated specimen as higher grain boundary areas behave as an anode in an electrochemical cell, thereby enhancing the rate of corrosion. According to electrochemical tests, the cryogenically treated surface is more resistant to corrosion, followed by heated alloy. However, both surface modification treatments improved the corrosion behavior of the untreated alloy.

Impact of cutting fluid on hybrid manufacturing of AISI H13 tool steel

Purpose This paper aims to analyse the effects derived from the presence of residual coolant from machining operations on the Directed Energy Deposition of AISI H13 tool steel and the quality of the resulting part. Design/methodology/approach In the present paper, the effectiveness of various cleaning techniques, including laser vaporising and air blasting, applied to different water/oil concentrations are studied. For this purpose, single-layer and multi-layer depositions are performed. Besides, the influence of the powder adhered to the coolant residues remaining on the surface of the workpiece is analysed. In all cases, cross-sections are studied in-depth, including metallographic, microhardness, scanning electron microscopy and crack mechanism analyses. Findings The results show that, although no significant differences were found for low oil concentrations when remarkably high oil concentrations were used the deposited material cracked, regardless of the cleaning technique applied. The crack initiation and propagation mechanisms have been analysed, concluding that the presence of oil leads to hydrogen induced cracking. Originality/value High oil concentration residues from previous machining operations in hybrid manufacturing led to hydrogen induced cracking when working with AISI H13 tool steel. The results obtained will help in defining future hybrid manufacturing processes that combine additive and subtractive operations.

Experimental evaluation and modelling of the boronizing kinetics of AISI H13 hot work tool steel

In the study for this contribution, the AISI H13 hot work steel was pack-boronized between 2 and 6 h of exposure time within the temperature range of 800 – 1000 °C. The boriding agent was composed of a powder mixture containing (in weight percent): 90 % of boron carbide (B4C) and 10 % of sodium tetrafluoroborate (NaBF4). The SEM observations showed a less pronounced jagged interface between the boronized layer and the transient zone. A double phase boride layer (FeB and Fe2B) was identified over the surface of AISI H13 steel with the presence of metallic borides inside this compound layer. The mean diffusion coefficient (MDC) method was applied to analyze the growth of iron borides (FeB and Fe2B) as compact layers over the surfaces of AISI H13 steel. The boron activation energies in the two iron borides were also assessed from the present kinetic approach by assuming the Arrhenius relationships. Afterwards, the kinetic model was checked experimentally by considering two extra boriding conditions (925 °C for 1 and 3 h). Finally, the predicted layer thicknesses are in accordance with experimental measurements.

Design and Testing of a WAAM Retrofit Kit for Repairing Operations on a Milling Machine

Repairing, remanufacturing, and refurbishing high value metal components are crucial to move towards a more sustainable economy. Nowadays, repairing operations on high value parts, such as dies, are generally performed using time-consuming manual approaches that rely on the operator’s expertise. The research idea of this paper is to develop a retrofit kit to provide additive capabilities to an existing milling machine, allowing automatic repairing of components thanks to a fast switch between additive and machining operations without a relevant economic investment such the acquisition of a brand-new machine: the final cost of the solution is lower than 10% with respect to the mean cost of a 5-axis milling machine. The additive technology used in this work is Wire Arc Additive Manufacturing (WAAM) that is characterized by a higher deposition rate and a simpler and cost-effective equipment with respect to other techniques (e.g., laser cladding). The design of the system is illustrated in the paper together with the analysis of the results achieved repairing a test case: a die casting mold made of AISI H13 tool steel.