Effect of Cryogenic Treatment on Density, Resistivity and Conductivity of Manganese Used in Lithium-Ion Batteries

Refrigeration is one of the core branch in the field of thermal engineering. In other words, we can say that the refrigeration is the sister branch of the thermal engineering or thermal science. The main purpose of refrigeration is to maintain the low temperature than the atmospheric temperature or simply room temperature. In a few decades, the new trends in the field of the refrigeration and air condition has been changed drastically. The need for the development of new refrigeration processes is to achieve possible minimum temperature by the liquefaction techniques such as linde claude system. The new field known as cryogenics is developed in recent few years whose main aim is to achieve the lowest possible temperature in order of -100 to - 1500 C. the cryogenics has a wide veriety of the applications ranging from space research to the medical science which can be supposed as a science fiction in the real life. Our research work is based on the analysis of the cryogenic treatment to the lithium ion battery to improve the performance of the battery for the long period. Keywords: Cryogenics, lithium ion batteries, manganese, density, conductivity

Enhancement of sp3 C Fraction in Diamond-like Carbon Coatings by Cryogenic Treatment

Diamond-like carbon (DLC) coatings deposited onto high-speed-steel surfaces were subjected to deep cryogenic treatment (DCT) at temperatures of −120 to −196 °C to investigate the evolution of microstructure, bonding structure, and mechanical properties. The surface morphology and the bonding structure of the DLC coatings were studied using scanning electron microscopy, transmission electron microscopy, micro-Raman spectroscopy, and X-ray photoelectron spectroscopy. It is found that DCT affects the surface morphology, especially the size and the height of the aggregates. For those DLCs with more than 50% sp3 C fraction, the sp2 C → sp3 C transformation occurred in coatings treated at a temperature of −120 to −160 °C; and the maximum fraction of sp3 C was obtained after treatment at −140 °C. Almost keeping the wear resistance of DLCs, DCT can improve the adhesion strength, and surface hardness. The findings of this study indicate that DCT will be a potential post-treatment method to tune the microstructure and mechanical performance of DLC coatings.

Effect of Deep Cryogenic Treatment on Corrosion Behavior of AISI H13 Die Steel

AISI H13 die steel specimens were subjected to heating at 1020 °C followed by oil quenching and double tempering at 520 °C. Subsequently, these specimens were subjected to deep cryogenic treatment at −185 °C in liquid nitrogen environment for 16 h and then subjected to soft tempering at 100 °C once the specimens attained room temperature. Thereafter, the specimens were subjected to scanning electron microscopy (SEM) analysis and electron backscatter diffraction (EBSD) analysis. The electrochemical corrosion activity was investigated in 3.5% NaCl at 23 ± 0.5 °C by evaluating the evolution of open circuit potential over time and potentiodynamic curves, and electrochemical impedance spectroscopy study was also carried out. The heat-treated specimens exhibited better resistance to corrosion through more electropositive values of open circuit potential. This could be attributed to lower grain boundary area in heat-treated specimens as compared to 16 h cryogenically treated specimen as higher grain boundary areas behave as an anode in an electrochemical cell, thereby enhancing the rate of corrosion. According to electrochemical tests, the cryogenically treated surface is more resistant to corrosion, followed by heated alloy. However, both surface modification treatments improved the corrosion behavior of the untreated alloy.

THE EFFECT OF DEEP CRYOGENIC ON TENSILE STRENGTH AND IMPACT TOUGHNESS IN QUENCH TEMPERED STEEL PLATE AS A CANDIDATE FOR BALLISTIC RESISTANCE MATERIAL

Ballistic resistant materials are materials containing right combination of hardness, strength, and toughness. The quench process produces high hardness and tensile strength but decreases toughness. The hardening process has been performed using an induction machine and a tempering process on a medium carbon steel plate. This work aimed to determine and analyze the effect of deep cryogenic treatment (DCT) on steel plates that have been quenched tempered. This research utilized steel plates of 130 x 130 x 8 mm size which has been quenched and then immersed in liquid nitrogen at a temperature of -196°C for 1, 5, 10, and 20 days. The micro Vickers hardness test specimen, tensile test and charpy impact test were made to determine the effect of immersion time. The test results and analysis showed that DCT had the ability to change microstructure, improve the hardness, tensile strength, and impact toughness. Furthermore, the maximum hardness was obtained during the immersion treatment of 20 days, which was 449.45 VHN and 1107.53 MPa, respectively. However, the highest toughness was obtained during the immersion of 10 days, which was 1,001 J/mm2. In order to get the optimal combination of ballistic characters, further ballistic testing is needed, both in simulation using the finite element method and ballistic experiment test.

Effect of Deep Cryogenic Treatment on Wear and Galling Properties of High-Speed Steels

New approaches to improving wear resistance with an affordable and noncomplex technology, such as deep cryogenic treatment, (DCT0), are receiving attention. The aim of this study is to investigate the effect of DCT on the friction and wear performance of high-speed steels. AISI M2, AISI M3:2 and AISI M35 were heat-treated under different conditions, and then investigated under dry sliding conditions. Tribological testing involved different contact conditions, prevailing wear mechanisms and loading conditions. The DCT effect on sliding wear resistance depends on HSS steel grade, as well as contact conditions and wear mode, whereas it improves the dynamic impact of the wear and galling resistance.