A Novel Machine-Assisted Technique for Extracting Multiscale Vugs and Fractures in Heterogeneous Carbonates Sequence

Predicting petrophysical properties in carbonate reservoirs is challenging due to the deposition and diagenetic history, which creates pore-scale features and heterogeneity at multiple-length scale. Non-fractured carbonate rocks with monomodal pore distribution often provide weak transportation properties compared to carbonates with multimodal pore system. The behaviour of such formations is subject to percolation effect where the connectivity of vug clusters control the poro-perm relationship which can be explained with high-resolution microresistivity images and nuclear magnetic resonance (NMR) data. A machine-assisted processing technique, defined as "thresholding," was applied to high-resolution microresistivity images, resolving vugs and fractures with similar resistivity. Other objects of interest are removed using object-oriented filters and thresholding, resulting in a "sculptured image" containing only vugs and fractures. The image is analysed to quantify formation porosity. A Laplacian of Gaussian filter is used to avoid highlighting features of no interest. Step two analyses T1 and T2 relaxations allowing portions of signal from a pore-size group to spill across the discrete boundaries. The pore-size takes on a fuzziness near the discrete relaxation time cut-offs corresponding to pore radii breakover points. High poro-perm layers of grainstone in overall thinly bedded sequences of packstone and wackestone were successfully identified and subsequently shed light upon the ambiguities observed in mobility values obtained from formation tester across the same lithocolumn. This novel technology helps in deciphering high-resolution integrated lithofacies. The histogram from the image porosity binning demonstrates a different response within vugular zones compared to fractured zones. Where the vugs sizes are variable, they exhibit a multi-pore system nature in NMR. For the fractured interval, the images and NMR exhibit weak distribution. The resistivity independent image pixel-based filtration technique helps to define interesting features on images which can be enhanced and measurable at various scales. Machine assisted technique in NMR complement the results in aiding to characterize the heterogeneous carbonate rocks.

Liability for robots II: an economic analysis

This is the second of two companion papers that discuss accidents caused by robots. In the first paper (Guerra et al., 2021), we presented the novel problems posed by robot accidents, and assessed the related legal approaches and institutional opportunities. In this paper, we build on the previous analysis to consider a novel liability regime, which we refer to as ‘manufacturer residual liability’ rule. This makes operators and victims liable for accidents due to their negligence – hence, incentivizing them to act diligently; and makes manufacturers residually liable for non-negligent accidents – hence, incentivizing them to make optimal investments in R&D for robots' safety. In turn, this rule will bring down the price of safer robots, driving unsafe technology out of the market. Thanks to the percolation effect of residual liability, operators will also be incentivized to adopt optimal activity levels in robots' usage.

Relaxation Phenomena in Chitosan-Au Nanoparticle Thin Films

Chitosan–gold nanoparticle (CS/AuNP) thin films were synthesized through the chemical reduction of HAuCl4 in sodium citrate/chitosan solutions. The dielectric and dynamic mechanical behaviors of CS/AuNP films have been investigated as a function of moisture and HAuCl4 content. Two relaxation processes in the nanocomposites have been observed. The α-relaxation process is related to a glass transition in wet CS/AuNP films. However, in dry composites (with 0.2 wt% of moisture content), the glass transition vanished. A second relaxation process was observed from 70 °C to the onset of thermal degradation (160 °C) in wet films and from 33 °C to the onset of degradation in dry films. This relaxation is identified as the σ-relaxation and may be related to the local diffusion process of ions between high potential barriers in disordered systems. The α- and σ-relaxation processes are affected by the HAuCl4 content of the solutions from which films were obtained because of the interaction between CS, sodium succinate, and gold nanoparticles. With about 0.6 mM of HAuCl4, the conductivity of both wet and dry films sharply increased by six orders, corresponding to the percolation effect, which may be related to the appearance of a conductivity pathway between AuNPs, HAuCl4, and NaCl.

Design, Development and Evaluation of Thermal Properties of Polysulphone–CNT/GNP Nanocomposites

Polysulphone (PSU) composites with carbon nanotubes (PSU-CNT) and graphene nanoplatelets (PSU-GNP) were developed through the solution casting process, using various weight load percentages of 1, 3, 5, and 10 wt% of CNT and GNP nanofillers. The microstructural and thermal properties of the PSU-based composites were compared. The microstructural characterisation of both composites (PSU-CNTs and PSU-GNPs) showed a strong matrix–filler interfacial interaction and uniform dispersion of CNTs and GNPs in the PSU matrix. The analysis demonstrated that both the thermal conductivity and effusivity improved with the increase in the weight percentage (wt%) of CNTs and GNPs because of the percolation effect. The polysulphone-based composite containing 10 wt% CNTs showed a remarkably high thermal conductivity value of 1.13 (W/m·K), which is 163% times higher than pure PSU. While the glass transition temperature (Tg) was shifted to a higher temperature, the thermal expansion was reduced in all the PSU-CNT and PSU-GNP composites. Interestingly, the CNTs allowed homogeneous distribution and a reasonably good interfacial network of interaction with the PSU matrix, leading to better microstructural characteristics and thermal properties than those of the PSU-GNP composites. The findings highlight the importance of controlling the nature, distribution, and content of fillers within the polymeric matrix.

Understanding the Percolation Effect in Triboelectric Nanogenerator with Conductive Intermediate Layer

Introducing the conductive intermediate layer into a triboelectric nanogenerator (TENG) has been proved as an efficient way to enhance the surface charge density that is attributed to the enhancement of the dielectric permittivity. However, far too little attention has been paid to the companion percolation, another key element to affect the output. Here, the TENG with MXene-embedded polyvinylidene fluoride (PVDF) composite film is fabricated, and the dependence of the output capability on the MXene loading is investigated experimentally and theoretically. Specifically, the surface charge density mainly depends on the dielectric permittivity at lower MXene loadings, and in contrast, the percolation becomes the degrading factor with the further increase of the conductive loadings. At the balance between the dielectric and percolation properties, the surface charge density of the MXene-modified TENG obtained 350% enhancement compared to that with the pure PVDF. This work shed new light on understanding the dielectric and percolation effect in TENG, which renders a universal strategy for the high-performance triboelectronics.

Analytical Estimates of the Water Drop Spreading Process with Percolation Effect

To solve the problems of active influence on thunderstorm clouds, the physical mechanism of artificial formation of water and ice germs in the cloud environment is theoretically studied. Based on the Gibbs-Vollmer theory of new phase formation, it follows that the defining parameters in the formation of embryos are the interphase energies at the vapor - water - reagent boundaries and the wetting edge angle. The active process of water spreading over a water-soluble flat horizontal substrate is studied using analytical methods. It is established that the process of interfacial interaction is metastable, in addition, the spreading process is characterized by the presence of direct contact zone between two phases in which the formation of a new compound is delayed. A theoretical evaluation of individual parameters of the system under gravitational spreading without the influence of other external fields is made. Two problems were solved: determining the dynamics of the free surface of the liquid phase and finding the boundaries of liquid propagation in the substrate. An analytical expression defining the contact angle is obtained. It is shown that the expressions defining the process main parameters of spreading a drop with simultaneous impregnation of the substrate, accompanied by a loss of mass of the liquid through the contact spot on the border of the two phases, are almost equivalent to the relations describing the process of mass loss when spreading an easily evaporating liquid.

Copper-Containing Films Obtained by the Simple Citrate Sol–Gel Route for NO2 Detection: Adsorption and Kinetic Study

The citrate sol–gel method was utilized for the fabrication of copper-containing films sensitive to NO2 gas. Effect of annealing temperature on the film phase composition, morphology, and sensor response was studied. X-ray diffraction reveals the formation of Cu2Cl(OH)3 phase at 250 °C and the CuO phase at 350 and 500 °C. It was found out that the films annealed at 250 °C and 350 °C showed the best sensor characteristics. The influence of thermal degradation on the probability of percolation effect in films and its connection to a decrease of gas sensitivity was studied. The kinetics of the NO2 gas adsorption on the film’s surface was described following the Elovich model. Activation energy estimated from the ln(S) vs. 1/T plots was 252 and 30 kJ/mol for the films annealed at 250 and 350 °C, respectively.

Understanding the Effect of Cementitious Grouting Pressure on Micro-Fracture Permeability for Rock Reinforcement Underground: A Lab Study

In grouting support projects, due to the small concealment of micro-fractures, the support effect often fails to meet design requirements. The percolation effect is a common factor that causes grouting failure, and the influence of grouting pressure on the percolation effect is very obvious. In this article, a design of a micro-fracture grouting experimental system is presented that can realize high-pressure grouting and then uses a variety of ultrafine cements to carry out high- and low-pressure grouting tests under different fracture opening conditions, thereby obtaining the grouting pressure and accumulated grouting weight during the grouting process. The results show that a combination of the grouting pressure curve and the cumulative grouting weight curve can determine whether the ultrafine cement will have a percolation effect. Increasing the grouting pressure can reduce the critical fracture opening value and also reduce the occurrence of the percolation effect. The research results provide a theoretical basis for the high-pressure grouting of micro-fracture rock masses and offer certain guiding significance for the design of high-pressure grouting support schemes.

Non-linear stability analysis of two-layered porous journal bearings with velocity slip and percolation effect of additives of coupled-stress lubricant

In this paper a non-linear stability analysis of the two-layered porous journal bearing under coupled-stress lubricant has been presented with velocity slip phenomenon and additive’s percolation effect. In this non-linear transient analysis, system stability is determined by tracing the locus of the journal center and various trajectories of journal center locus have been represented in graphical form for different operating conditions. Furthermore, stability characteristics in respect of critical mass parameter and whirl ratio have been studied under various parametric conditions and a comparison between the linear and non-linear stability analysis have been demonstrated. To acquire the non-dimensional pressure values, non-dimensional transient Reynolds equation has been solved and with these pressure values, bearing load carrying capacity are derived. Fourth order Runge-Kutta method is used to solve the second order equations of motion for journal bearing system to obtain the stability characteristics. Results of this analysis may be helpful for designing such bearings.