Migration of Excitation Energy in Furocoumarins

The migration of excitation energy of a number of psoralen compounds has been studied. For this, the methods of induced absorption spectroscopy, stationary electron spectroscopy, fluorescence and phosphorescence, as well as quantum chemistry were used. A comparative photostability of psoralen was achieved by exposure to a XeCl excilamp irradiation (emission wavelength λem = 308 nm) with parameters Δλ = 5–10 nm, Wpeak = 18 mW/cm2, p = 8.1 J/cm3, f = 200 kHz, pulse duration 1 μs. It was found that the singlet-triplet transition played a major role in the migration of excitation energy into triplet states. Among all tested compounds, substances with an OCH3-group in the structure have the strongest effect on the spectral-luminescent characteristics.

A Mono-Copper Doped Undeca-Gold Cluster with Up-converted and Anti-Stokes Emissions of Fluorescence and Phosphorescence

We have synthesized single crystals of a highly stable Cu-doped undeca-gold cluster protected by both triphenylphosphine (PPh3) and 2-pyridinethiol (-SPy) ligands, formulated as [Au11Cu1(PPh3)7(SPy)3]+. This cluster (Au11Cu1 NCs for short)...

Simultaneous Fluorescence and Phosphorescence in Zn(II)-Zwitterionic Coordination Polymers with Tunable Colors

Three similar ionic-type ligands which can provide ligand-centred charge transfer (LCCT) have been employed to synthesize three isostructural complexes respectively. Since the coordination of the ligands to the metal centres,...