Increase of Productivity and Neutralization of Pathological Processes in Plants of Grain and Fruit Crops with the Help of Aqueous Solutions Activated by Plasma of High-Frequency Glow Discharge

In this work, we, for the first time, manufactured a plasma-chemical reactor operating at a frequency of 0.11 MHz. The reactor allows for the activation of large volumes of liquids in a short time. The physicochemical properties of activated liquids (concentration of hydrogen peroxide, nitrate anions, redox potential, electrical conductivity, pH, concentration of dissolved gases) are characterized in detail. Antifungal activity of aqueous solutions activated by a glow discharge has been investigated. It was shown that aqueous solutions activated by a glow discharge significantly reduce the degree of presence of phytopathogens and their effect on the germination of such seeds. Seeds of cereals (sorghum and barley) and fruit (strawberries) crops were studied. The greatest positive effect was found in the treatment of sorghum seeds. Moreover, laboratory tests have shown a significant increase in sorghum drought tolerance. The effectiveness of the use of glow-discharge-activated aqueous solutions was shown during a field experiment, which was set up in the saline semi-desert of the Northern Caspian region. Thus, the technology developed by us makes it possible to carry out the activation of aqueous solutions on an industrial scale. Water activated by a glow discharge exhibits antifungicidal activity and significantly accelerates the development of the grain and fruit crops we studied. In the case of sorghum culture, glow-discharge-activated water significantly increases drought resistance.

Reactivity induced transient analysis when the occurrence of leakage in the dry irradiation channels of the Dalat Nuclear Research Reactor

The leakage from the reactor pool back into the dry irradiation channels due to corrosion or mechanics based reason is a postulated event that could occur under operating conditions of the Dalat nuclear research reactor (DNRR), especially the channel 7-1 which has been installed more than 30 years. When it occurs, the air space in these channels will be occupied by the water, subsequently a water column will appear in fuel region. The appearance of water column considerably enhances medium of neutron moderation for its surrounding fuel assemblies. As a result, a positive reactivity is inserted in the core and this event is classified as an insertion of excess reactivity. This event needs to be addressed by analysis and assessment from safety point of view and the results of analysis are also important for updating the reactor operating procedures. This paper presents assumptions, computer models and the results of analysis for such event in the DNRR by using MCNP5 code (code for neutronics analysis) and EUREKA-2/RR code (code for transient analysis). The calculation results include value of reactivity insertion, change in power of reactor, as well as surface temperature of the hottest fuel assembly. This research contributes to updating the reactor operating procedure.

An Electrohydraulic Direct Current Discharge for Inactivation of Escherichia coli in High-Bacterial Density Wastewaters

The United Nations, through its Sustainable Development Goals, have identified access to clean water as one of the challenges facing society. With reported global deaths exceeding 1 million annually linked to untreated water consumption, which is usually contaminated by pathogenic micro-organisms, further research continues in water disinfection. The direct generation of non-thermal plasma in water is a promising method for the inactivation of disease-causing bacteria present in the wastewater. This study explored the efficacy of plasma in the inactivation of different bacterial densities (4.0×104, 1.5×105, and 2.5×107 CFU/mL) using a 500 mL plasma batch reactor operating at atmospheric pressure. The plasma discharge was generated in water by a Technix-SR-10R-5000 high voltage direct current power supply in negative polarity with a set current of 0.45 A and a maximum pre-set ignition voltage of 9 kV. The electrodes used in the discharge was a copper material. A bacterial culture of Escherichia coli ATCC® 25922TM (E.coli) was used as a model for the direct plasma discharge. The study further investigated the contribution of copper ions (0.4 and 0.7 mg/L) released into the water during treatment by having two control reactors that were not exposed to plasma. The results show a complete inactivation at 180 seconds for the bacterial densities from 4.0×104 to 2.5×107 CFU/mL. The results from this study indicated the potential of a direct electric discharge in handling water source with high-bacteria densities.

Experimental evaluation of natural convection in the IPR-R1 Triga research reactor at 264 kW and 105 kW

In order to study the safety aspects connected with the permanent increase of the maximum steady state power of the IPR-R1 Triga Reactor of the Nuclear Technology Development Center (CDTN), experimental measurements were done with the reactor operating at power levels of 265 kW and 105 kW, with the pool forced cooling system turned off. A number of parameters were measured in real-time such as fuel and water temperatures, radiation levels, reactivity, and influence of cooling system. Information on all aspects of reactor operation was displayed on the Data Acquisition System (DAS) shown the IPR-R1 online performance. The DAS was developed to monitor and record all operational parameters. Information displayed on the monitor was recorded on hard disk in a historical database. This paper summarizes the behavior of some operational parameters, and in particular, the evolution of the temperature in the fuel element centerline positioned in the core hottest location. The natural circulation test was performed to confirm the cooling capability of the natural convection in the IPR-R1 reactor. It was confirmed that the IPR-R1 has capability of long-term core cooling by natural circulation operating at 265 kW. The measured maximum fuel temperature of about 300 oC was lower than the operating limit of 550 oC. It has been proven that without cooling in the primary the gamma dose rate above reactor pool at high power levels was rather high.

Thermodynamic Evaluation of Equilibrium Oxygen Composition of UO2-Mo Nuclear Fuel Pellet Under High Temperature Steam

Micro-plate or microcell UO2–Mo is considered a promising accident tolerant fuel candidate for water-cooled power reactors. In this work, we evaluated the anticipated oxidation behavior of a UO2–Mo system under high-temperature steam to understand the impact of Mo oxidation on the fuel degradation mechanism in the event of steam ingress through cracks in the cladding. The equilibrium oxygen compositions of UO2 and Mo in various steam atmospheres relevant to reactor operating conditions were predicted using thermodynamic calculations and then compared with previous results. The oxidation behavior of UO2–Mo pellets was discussed through thermodynamic calculations and in terms of kinetic parameters such as oxygen diffusion, fuel temperature profile, and pellet microstructure. Mo oxidation was found to have an insignificant effect on pellet integrity in a cladding leakage scenario under normal reactor operating conditions.

Enhancing CO2 Conversion to CO over Plasma-Deposited Composites Based on Mixed Co and Fe Oxides

The hydrogenation of CO2 to produce CO and H2O, known as reverse-water-gas shift reaction (RWGS) is considered to be an important CO2 valorization pathway. This work is aimed at proposing the thin-film catalysts based on iron and cobalt oxides for this purpose. A series of Fe–Co nanocomposites were prepared by the plasma-enhanced chemical vapor deposition (PECVD) from organic cobalt and iron precursors on a wire-mesh support. The catalysts were characterized by SEM/EDX, XPS, XRD, and Raman spectroscopy and studied for hydrogenation of CO2 in a tubular reactor operating in the temperature range of 250–400 °C and atmospheric pressure. The Co-based catalyst, containing crystalline CoO phase, exhibited high activity toward CH4, while the Fe-based catalyst, containing crystalline Fe2O3/Fe3O4 phases, was less active and converted CO2 mainly into CO. Regarding the Fe–Co nanocomposites (incl. Fe2O3/Fe3O4 and CoO), even a small fraction of iron dramatically inhibited the production of methane. With increasing the atomic fraction of iron in the Fe–Co systems, the efficiency of the RWGS reaction at 400 °C increased up to 95% selectivity to CO and 30% conversion of CO2, which significantly exceeded the conversion for pure iron–based films (approx. 9%). The superior performance of the Fe–Co nanocomposites compared to “pure” Co and Fe–based films was proposed to be explained by assuming changes in the electronic structure of the catalyst resulting from the formation of p–n junctions between nanoparticles of cobalt and iron oxides.

Patchy nuclear chain reactions

Stochastic fluctuations of the neutron population within a nuclear reactor are typically prevented by operating the core at a sufficient power, since a deterministic (i.e., exactly predictable) behavior of the neutron population is required by automatic safety systems to detect unwanted power excursions. In order to characterize the reactor operating conditions at which the fluctuations vanish, an experiment was designed and took place in 2017 at the Rensselaer Polytechnic Institute Reactor Critical Facility. This experiment however revealed persisting fluctuations and striking patchy spatial patterns in neutron spatial distributions. Here we report these experimental findings, interpret them by a stochastic modeling based on branching random walks, and extend them using a “numerical twin” of the reactor core. Consequences on nuclear safety will be discussed.