A new torsional vibration coupling model for transmission system in diesel generator

The coupling between the crankshaft and the camshaft is neglected before in fault diagnosis which may lead to incomplete fault information. In this paper, a new torsional coupling model of a diesel generator transmission system is proposed for fault diagnosis. The natural frequency and forced torsional vibration response of the model are obtained by the system matrix method and Newmark-β method. For the system without considering the lumped mass of camshafts, some key natural frequencies are lost. The vibration dynamics are compared for the transmission system with and without the new coupling model. And important frequency responses are missed in the spectrums of the forced torsional vibration without the new coupling model. Finally, the new coupling model is implemented in fault diagnosis and the cause of an unusual vibration fault is deduced in the simulation, which confirms the feasibility of the proposed model in fault diagnosis.

Small reorganization energy acceptors enable low energy losses in non-fullerene organic solar cells

Minimizing the energy loss is of critical importance in the pursuit of attaining high-performance organic solar cells (OSCs). Interestingly, electron-vibration coupling (namely reorganization energy) plays a crucial role in the photo-electric conversion processes. However, a molecular understanding of the relationship between the reorganization energy and the energy loss has rarely been studied. Here, two new acceptors Qx-1 and Qx-2 with quinoxaline (Qx)-containing fused core were designed and synthesized. The results indicate that the reorganization energies of these two acceptors during the photoelectric conversion processes are substantially smaller than the conventional Y6 acceptor, which is beneficial for improving the exciton lifetime and diffusion length, promoting charge transport and reducing the energy loss originating from exciton dissociation and non-radiative recombination. As a result, an outstanding power conversion efficiency (PCE) of 18.2% with high Voc above 0.93 V in the PM6:Qx-2 blend, accompanying a significantly reduced energy loss of 0.48 eV. To the best of our knowledge, the obtained energy loss is the smallest for the binary OSCs with PCEs over 16% reported to date. This work underlines the importance of the reorganization energy in achieving small energy loss in organic active materials and paves a new way to obtain high-performance OSCs.

Influence Mechanism of Electromechanical Parameters on Transient Dynamics of FWD-EVs: Part I: Co-Modeling of IWM and Vehicle System

In-wheel motor (IWM), as an ideal power source of independent four-wheel drive electric vehicles, has been paid more and more attention due to its high-power density, low starting current, wide speed adjustment range, simple control system and robustness. However, the electromechanical issue is enlarged in both longitudinal and vertical because of in-wheel driven scheme. In this paper, the electromagnetic multi-field characteristic of IWM is investigated based on Fourier series method. The negative vibration coupling on vehicle dynamics is discussed by proposing a conjoint electromechanical FWD-EV model. Results shows that the motor incentive coupled with the vehicle system in multi-degree of freedom, caused the body and wheel resonance in the low speed, meanwhile deteriorated the anti-rollover capability of the IWM-EV in the high speed.

Normal & reversed spin mobility in a diradical by electron-vibration coupling

Abstractπ−conjugated radicals have great promise for use in organic spintronics, however, the mechanisms of spin relaxation and mobility related to radical structural flexibility remain unexplored. Here, we describe a dumbbell shape azobenzene diradical and correlate its solid-state flexibility with spin relaxation and mobility. We employ a combination of X-ray diffraction and Raman spectroscopy to determine the molecular changes with temperature. Heating leads to: i) a modulation of the spin distribution; and ii) a “normal” quinoidal → aromatic transformation at low temperatures driven by the intramolecular rotational vibrations of the azobenzene core and a “reversed” aromatic → quinoidal change at high temperatures activated by an azobenzene bicycle pedal motion amplified by anisotropic intermolecular interactions. Thermal excitation of these vibrational states modulates the diradical electronic and spin structures featuring vibronic coupling mechanisms that might be relevant for future design of high spin organic molecules with tunable magnetic properties for solid state spintronics.

Coupled Lateral and Torsional Vibration of Rub-Impact Rotor during Hovering Flight

When aircraft make a maneuvering during flight, additional loads acting on the engine rotor system are generated, which may induce rub-impact faults between the rotor and stator. To study the rub-impact response characteristics of the rotor system during hovering flight, the dynamic model of a rub-impact rotor system is established with lateral-torsional vibration coupling effect under arbitrary maneuvering flight conditions using the finite element method and Lagrange equation. An implicit numerical integral method combining the Newmark-β and Newton–Raphson methods is used to solve the vibration response. The results indicate that the dynamic characteristics of the rotor system will change during maneuvering flight, and the subharmonic vibrations are amplified in both lateral and torsional vibrations due to maneuvering overload. The form of the rub-impact is different during level and hovering flight conditions: the rub-impact may occur at an arbitrary phase of the whole cycle under the condition of level flight, while only local rub-impact occurs during hovering flight. Under the both flight conditions, the rub-impact has a large effect on the spectral characteristics, periodicity, and stability of the rotor system.