Variability of Physical and Biogeochemical Parameters in the Exclusive Economic Zone of Qatar

The oceanographic data collected along a transect in the Exclusive Economic Zone (EEZ) of Qatar during late summer (September 2014) and winter (January 2015) have been analyzed to investigate the spatial and temporal variability of hydrography and biogeochemistry. The study reveals that stratification is dominant in the deep-water regions during September, with a vertical variation of around 9 °C from surface to bottom. However, the water column remains in homogeneity during January due to strong wind mixing and surface cooling. The dissolved oxygen (DO) in the upper layer of the EEZ is on a reasonable range in both the seasons, while they gradually decrease with respect to depth in the mid and bottom layers during January. This leads to hypoxic conditions in summer. Chlorophyll-a (Chl-a ) is relatively high during summer in the offshore region, while that in the nearshore regions is very low. The variability in the physical and biogeochemical parameters has shown significant effects in primary productivity in the EEZ of Qatar.

The impact of sediment, fresh and marine water on the concentration of chemical elements in water of the ice-covered lagoon

The common use of chemical elements by man has been contributing to their extraction for centuries. As a consequence, they have been directly or indirectly introduced into the biogeochemical cycle. In the framework of many conventions, mining and processing of elements are currently subject to many restrictions. However, their large load that has already been deposited in the soil and bottom sediments can be remobilised and enter the food chain. The identification of factors favouring this process is very important, especially during the period of adopting new legal regulations on limiting the emission of pollutants. It became possible in February 2018 during the persistence of ice cover on the lagoon’s surface. This allowed observation of processes, the effect of which in the absence of ice is blurred by wind mixing water. Therefore, an investigation of sources of 25 elements in a lagoon of the southern Baltic has been undertaken, based on the example of the Vistula Lagoon. The results point to the remobilisation of chemical elements (including the toxic ones) from land and bottom sediments, where they have been deposited for decades. These processes led to the accumulation of metals in certain areas of the lagoon. It may result in their uptake and accumulation in the benthic organisms inhabiting the lagoon and further transfer in the food chain. It is of major importance as the lagoons in the southern Baltic fulfil many essential functions in the scope of tourism, economy, and fishery. Thanks to restrictions on the quality of wastewater and the emission of pollutants, it has been noticed a substantial “purifying” effect of rivers, too.

Enhanced internal tidal mixing in the Philippine Sea mesoscale environment

Turbulent mixing in the ocean interior is mainly attributed to internal wave breaking; however, the mixing properties and the modulation effects of mesoscale environmental factors are not well known. Here, the spatially inhomogeneous and seasonally variable diapycnal diffusivities in the upper Philippine Sea were estimated from Argo float data using a strain-based, fine-scale parameterization. Based on a coordinated analysis of multi-source data, we found that the driving processes for diapycnal diffusivities mainly included the near-inertial waves and internal tides. Mesoscale features were important in intensifying the mixing and modulating of its spatial pattern. An interesting finding was that, besides near-inertial waves, internal tides also contributed significant diapycnal mixing in the upper Philippine Sea. The seasonal cycles of diapycnal diffusivities and their contributors differed zonally. In the midlatitudes, wind mixing dominated and was strongest in winter and weakest in summer. In contrast, tidal mixing was more predominant in the lower latitudes and had no apparent seasonal variability. Furthermore, we provide evidence that the mesoscale environment in the Philippine Sea played a significant role in regulating the intensity and shaping the spatial inhomogeneity of the internal tidal mixing. The magnitudes of internal tidal mixing were greatly elevated in regions of energetic mesoscale processes. Anticyclonic mesoscale features were found to enhance diapycnal mixing more significantly than cyclonic ones.

Near-field wind mixing and implications on parameterization from float observations

A part of near-inertial wind energies dissipates locally below the surface mixed layer. Here, their role in the climate system is studied by adopting near-inertial near-field wind-mixing parameterization to a coarse-forward ocean general circulation model. After confirming a problem of the parameterization in the equatorial region, we investigate effects of near-field wind mixing due to storm track activities in the North Pacific. We found that, in the center of the Pacific Decadal Oscillation (PDO) around 170°W in the mid latitude, near-field wind mixing transfers the PDO signal into deeper layers. Since the results suggest that near-field wind mixing is important in the climate system, we also compared the parameterization with velocity observations by a float in the North Pacific. The float observed abrupt and local propagation of near-inertial internal waves and shear instabilities in the main thermocline along the Kuroshio Extension for 460 km. Vertical diffusivities inferred from the parameterization do not reproduce the enhanced diffusivities in the deeper layer inferred from the float. Wave-ray tracing indicates that wave trapping near the Kuroshio front is responsible for the elevated diffusivities. Therefore, enhanced mixing due to trapping should be included in the parameterization.

Hydrochemical state of the Uglovoy Bight (Amur Bay) in different seasons

Hydrological and chemical surveys were conducted in the Uglovoy Bight in October, 2019, February, May and June, 2020 (in total 120 stations) and chemical analyses of water from 13 small rivers running into the bight were done on October 21-22, 2020. Extremely high concentration of nutrients was detected in the Peschanka, Saperka and Gryaznukha Rivers that was obviously caused by waste waters discharge. These rivers were the main source of the bight eutrophication. Within the bight, the highest anomalies of chemical parameters, as low oxygen content, low pH, high concentrations of nutrients (N, P, Si), high turbidity, and high CO2 partial pressure were observed close to these rivers mouths, in particular under the ice in winter, when wind mixing was absent. The hypoxia disappeared in the warm period of year because of wind mixing. High concentrations of total nitrogen (10.0-40.0 μmol/L), total phosphorus (1.5-2.0 gmol/L), dissolved organic carbon (3-5 mgC/L), and chlorophyll a (0.5-2.0 μg/L) in all seasons were the results of active production-destruction processes, obviously with prevalence of organic matter destruction, since the water in the bight was undersaturated with oxygen and supersaturated with carbon dioxide — the bight accumulates and mineralizes organic matter from terrestrial and riverine discharge. Underwater photographs did not detect Zostera meadows at the bottom, which were observed in the northwestern Uglovoy bight in the past. Comparison of historical data on episodic studies in the bight with results of the surveys indicates degradation of its ecosystem, with such signs as disappearance of seagrass, hypoxia in winter, and CO2 flux into the atmosphere. Reduce in water exchange between the bight and the Amur Bay caused by construction of the underwater pipeline in 1982 and the bridge in 2012 is suggested as a reason of the degradation.

Enhanced internal tidal mixing in the Philippine Sea mesoscale environment

<p>Turbulent mixing in the ocean interior is mainly contributed by internal wave breaking; however, the mixing properties and the modulation effects of mesoscale environmental factors are not well-known. Here, the spatially inhomogeneous and seasonally variable diapycnal diffusivities in the upper Philippine Sea were estimated from ARGO float data using a strain-based finescale parameterization. Based on a coordinated analysis of multi-source data, we found that the driving processes for diapycnal diffusivities mainly included the near-inertial waves and internal tides. Mesoscale features were important in intensifying the mixing and modulating its spatial pattern. One interesting finding was that, besides near-inertial waves, internal tides also contributed significant diapycnal mixing for the upper Philippine Sea. The seasonal cycles of diapycnal diffusivities and their contributors differed zonally. In the mid-latitudes, wind-mixing dominated and was strongest in winter and weakest in summer. In contrast, tidal-mixing was more predominant in the lower-latitudes and had no apparent seasonal variability. Furthermore, we provide evidence that the mesoscale environment in the Philippine Sea played a significant role in regulating the intensity and shaping the spatial inhomogeneity of the internal tidal mixing. The magnitudes of internal tidal mixing was greatly elevated in regions of energetic mesoscale processes. The anticyclonic mesoscale features were found to enhance diapycnal mixing more significantly than did cyclonic ones.</p>

Enhanced internal tidal mixing in the Philippine Sea mesoscale environment

Turbulent mixing in the ocean interior is mainly contributed by internal wave breaking; however, the mixing properties and the modulation effects of mesoscale environmental factors are not well-known. Here, the spatially inhomogeneous and seasonally variable diapycnal diffusivities in the upper Philippine Sea were estimated from ARGO float data using a strain-based finescale parameterization. Based on a coordinated analysis of multi-source data, we found that the driving processes for diapycnal diffusivities mainly included the near-inertial waves and internal tides. Mesoscale features were important in intensifying the mixing and modulating its spatial pattern. One interesting finding was that, besides near-inertial waves, internal tides also contributed significant diapycnal mixing for the upper Philippine Sea. The seasonal cycles of diapycnal diffusivities and their contributors differed zonally. In the mid-latitudes, wind-mixing dominated and was strongest in winter and weakest in summer. In contrast, tidal-mixing was more predominant in the lower-latitudes and had no apparent seasonal variability. Furthermore, we provide evidence that the mesoscale environment in the Philippine Sea played a significant role in regulating the intensity and shaping the spatial inhomogeneity of the internal tidal mixing. The magnitudes of internal tidal mixing was greatly elevated in regions of energetic mesoscale processes. The anticyclonic mesoscale features were found to enhance diapycnal mixing more significantly than did cyclonic ones.

Encountering shoaling internal waves on the dispersal pathway of the pearl river plume in summer

Fundamentally, river plume dynamics are controlled by the buoyancy due to river effluent and mixing induced by local forcing such as winds and tides. Rarely the influence of far-field internal waves on the river plume dynamics is documented. Our 5-day fix-point measurements and underway acoustic profiling identified hydrodynamic processes on the dispersal pathway of the Pearl River plume. The river plume dispersal was driven by the SW monsoon winds that induced the intrusion of cold water near the bottom. The river effluent occupied the surface water, creating strong stratification and showing on-offshore variability due to tidal fluctuations. However, intermittent disruptions weakened stratification due to wind mixing and perturbations by nonlinear internal waves (NIWs) from the northern South China Sea (NSCS). During events of NIW encounter, significant drawdowns of the river plume up to 20 m occurred. The EOF deciphers and ranks the contributions of abovementioned processes: (1) the stratification/mixing coupled by wind-driven plume water and NIWs disruptions (81.7%); (2) the variation caused by tidal modulation (6.9%); and (3) the cold water intrusion induced by summer monsoon winds (5.1%). Our findings further improve the understanding of the Pearl River plume dynamics influenced by the NIWs from the NSCS.

Spatio-Temporal Study of Criteria Pollutants in Nigerian City

Aims: An investigation of characteristic long term air pollutants known for temporal and spatial behaviors was conducted due to increased pollution scenarios in Nigerian cities as a result of deprived environmental enforcement of statutory obligations. Study Design: One of the worlds’ most polluted cities (Onitsha lower basin) in Nigeria was selected for spatio-temporal study of three criteria pollutants combined with GIS and MATLAB alongside associated meteorological conditions during harmattan. Methodology: 72-hourly analyses of the nine different locations having 4 sampling sites and 500 meters apart were done from December to February which generated over 19, 440 experimental data per quarter of each annual study. Results: Upper Iweka/Nitel area recorded the highest concentration of SO2 pollutant at (94.2 µg/m3) due to longer residence times and low wind mixing height. Borromeo hospital showed the least active NO2 region but converges at points 1 due to North-east wind dissimilar to sampling points 1 having the lowest PM10 distribution. Measured temperature parameter correlates inversely with relative humidity and precipitation. The GIS spatial representation corresponded to temporal variability of gaseous and particulate pollutants. Conclusion: All sampled areas had AQI above 50; hence the study identified SO2, NO2, and PM10 as Primary pollutants of Onitsha lower basin.

Spatial Differentiation and Multiannual Dynamics of Water Conductivity in Lakes of the Suwałki Landscape Park

Water conductivity in 23 lakes of the Suwałki Landscape Park (SLP) was tested in the years 2012–2014. Conductivity profiles were made at the deepest place every two months between spring and autumn water mixing. The collected measurement data, supplemented with historical data, were used to identify factors that shape the spatial variability of water conductivity and to reconstruct its multiannual changes. The range of variability of the mean conductivity of surface water of the SLP lakes ranged from 178 to 522 µS cm−1. The strong negative relationship between conductivity and lake elevation (R = 0.816, p < 0.000) suggests that in the territorially compact complex of the SLP lakes, conductivity is a consequence of the location of the lake in the catchment, which, in turn, affects the structure of its water supply. However, the physical and environmental parameters of the catchment and morphometric parameters of lake basins are of secondary importance. In dimictic lakes and in those showing signs of “spring meromixis”, the magnitude of conductivity differences in the water column is determined by the lakes’ susceptibility to wind mixing expressed by the exposure index value. The developed climate models have also shown that conductivity, an indicator of water quality, is very sensitive to climate change. The analysis of the reconstructed chronological conductivity sequences shows that the deterioration of the quality of the waters of the SLP lakes first occurred at the beginning of the 21st century and a clear increasing trend has been maintained over the last decade.