Supplemental Material: Apatite fingerprints on the magmatic-hydrothermal evolution of the Daheishan giant porphyry Mo deposit, NE China

Figure S1: Harker diagrams illustrating major elemental variations of the porphyry and wall rock. QGP—Qiancuoluo granodioritic porphyry; QBG—Qiancuoluo biotite granodiorite; Figure S2: (a) Chondrite-normalized REE patterns and (b) primitive mantle (PM)-normalized spider diagrams of the porphyry and wall rock. Normalizing values are taken from S. Sun and McDonough (1989); Table S1: Whole-rock major and trace element compositions of the Qiancuoluo granodioritic porphyry (QGP) and Qiancuoluo biotite granodiorite (QBG) granites; Table S2: Whole-rock Sr-Nd compositions of the Qiancuoluo granodioritic porphyry (QGP) and Qiancuoluo biotite granodiorite (QBG); Table S3: Apatite major and trace elements (ppm) of the Qiancuoluo granodioritic porphyry (QGP) and Qiancuoluo biotite granodiorite (QBG); Table S4: Apatite Sr and Nd isotope data of the Qiancuoluo granodioritic porphyry (QGP) and Qiancuoluo biotite granodiorite (QBG); Table S5: Apatite U-Pb isotope data of the Qiancuoluo granodioritic porphyry (QGP) and Qiancuoluo biotite granodiorite (QBG).

Supplemental Material: Apatite fingerprints on the magmatic-hydrothermal evolution of the Daheishan giant porphyry Mo deposit, NE China

Figure S1: Harker diagrams illustrating major elemental variations of the porphyry and wall rock. QGP—Qiancuoluo granodioritic porphyry; QBG—Qiancuoluo biotite granodiorite; Figure S2: (a) Chondrite-normalized REE patterns and (b) primitive mantle (PM)-normalized spider diagrams of the porphyry and wall rock. Normalizing values are taken from S. Sun and McDonough (1989); Table S1: Whole-rock major and trace element compositions of the Qiancuoluo granodioritic porphyry (QGP) and Qiancuoluo biotite granodiorite (QBG) granites; Table S2: Whole-rock Sr-Nd compositions of the Qiancuoluo granodioritic porphyry (QGP) and Qiancuoluo biotite granodiorite (QBG); Table S3: Apatite major and trace elements (ppm) of the Qiancuoluo granodioritic porphyry (QGP) and Qiancuoluo biotite granodiorite (QBG); Table S4: Apatite Sr and Nd isotope data of the Qiancuoluo granodioritic porphyry (QGP) and Qiancuoluo biotite granodiorite (QBG); Table S5: Apatite U-Pb isotope data of the Qiancuoluo granodioritic porphyry (QGP) and Qiancuoluo biotite granodiorite (QBG).

Eocene Arc-related Magmatism within the Neotethys Subduction System in NW Iran; Geochemistry and SHRIMP zircon U-Pb Dating on Magmatic Phases in the Shahjahan Batholith

Granitoids of the composite Shahjahan batholith in the northernmost part of the Urmia-Dokhtar magmatic arc of Iran, and southernmost of the Lesser Caucasus (South Armenia) show SHRIMP zircon ages of 37.1±1.2 to 47.1±4.5 Ma. Dioritic rocks of the pluton with an age of 46.6 ± 4.6 to 47.1 ± 4.5 Ma are calk-alkaline to high-K calc-alkaline, metaluminous and I-type. They show arc-related affinities, characterized by LREE and LILE enrichment and HREE and HFSE depletion, especially negative Ti, Nb and Ta anomalies (TNT effect) in the normalized spider diagrams. low Ce/Pb, Nb/La and high Ba/Nb, U/Th and Hf/Zr ratios along with positive Pb, K, Th and Sr anomalies in the normalized spider diagrams for the studied samples are compatible with magma contamination with crustal materials during ascend to the lower crustal levels. Felsic dikes with granodiorite and syenite compositions and 37.1 ± 1.2 to 38.57 ± 0.41 Ma old, are characterized by high-K calc-alkaline to shoshonitic, metaluminous, and A2- type affinities which show post-collision tectonic setting geochemical features. The REE patterns for all studied samples and the composition of the trace element ratios indicate a geochemically enriched spinel-lherzolite lithospheric mantle source for the magmas, which underwent a low degree of partial melting. Dating arc-related dioritic samples and post collision felsic dikes put constrain on timing of Neotethys Ocean closure in NW Iran. Based on the present study, Middle to Upper Eocene is suggested as closure time of the Neotethys Ocean, Arabia and Central Iran plates’ collision and crustal thickening in Northwest Iran.

¿Son las universidades socialmente responsables?

The importance of university social responsibility (USR) is given by the commitment assumed by the university towards its stakeholders. This study aims at providing new insights on this topic, by analyzing the level of performance in USR that universities communicate. To this end, a structured procedure in five phases is proposed, analyzing elements of the strategic direction and considering the use of USR indicators which are grouped in the four main areas of impact (organizational, educational, cognitive and social). To do this, a qualitative approach has been followed, supported by the use of text analysis software as well as by frequency and spider diagrams. To illustrate its use and the type of analysis it allows, the procedure is applied to the case of the Catalan higher education system, presenting the results at different levels. The study ends with the discussion of the implications, a list of recommendations and suggestion for future works.

The role of shallow open system processes in the evolution of South Tepeldag Pluton (NW Turkey): insights and constraints from thermodynamic modelling

<p>Eocene granitoids in NW Anatolia occurred following the continental collision between Sakarya Continent and Tauride-Anatolide Platform and mark the onset of post-collisional magmatism in the region. One of the representative members of the Eocene granitoids, the Tepeldağ pluton crops out as two isolated granitic bodies and is intruded into the Cretaceous blueschist assemblages (Kocasu formation) and ophiolitic rocks within the Izmir-Ankara-Erzincan suture zone (IAESZ). South Tepeldağ pluton (STP) is composed mainly of granodiorite with subordinate quartz diorite, which show transitional contacts. Aplitic dykes crosscut the pluton as well as the country rocks. STP includes a number of mafic microgranular enclaves (MME) of gabbro/diorite composition.</p><p>Geochemically, STP shows distinct I-type affinity with a metaluminous to slightly peraluminous (ASI ≤1.02) nature. The samples are medium-K to high-K calc-alkaline in character. They exhibit depletion in HFSE (Ti, Hf, Zr, Nb and Ta) compared to large ion lithophile elements (Rb, Ba, Th, U, K) and presents negative Nb, P, Ti anomalies. STP displays slight negative Eu anomalies (Eu/Eu* = 0.7–1.2), enrichment in LREE and flat HREE patterns in chondrite-normalized spider diagrams. MELTS modeling (with initial parameters of 1–3 kbar pressure, 2–3% water and QFM-NNO oxygen fugacity buffers) indicate that compositional variations in STP samples can be interpreted as a result of open system processes (assimilation fractional crystallization) rather than a reflection of fractional crystallization in the upper crustal magma chamber. All thermodynamic simulations dictate a crustal assimilation, especially in the late stages of the magmatic process, with a MgO, Na<sub>2</sub>O and Al<sub>2</sub>O<sub>3</sub>-rich assimilant similar to the suture zone (IAESZ) rocks.</p>

Ophiolitic peridotites in Xigaze (Tibet): Constraints on modes of melt transport in the mantle

<p>The Xigaze ophiolite (Tibet), which occurs in the central segment of the Yarlung Zangbo Suture Zone, exposes a complete portion of a mantle sequence that consists essentially of fresh as well as serpentinized peridotites. We studied a sequence beneath the crustal section that exposes fresh, Cpx-bearing harzburgites and dunites that are underlain by serpentinized Cpx-bearing harzburgites and dunites. The rocks at the bottom are crosscut by dykes that have undergone different degrees of rodingitization. The modal compositions of peridotite from both fresh and serpentinized sections plot in abyssal upper mantle fields, with clinopyroxene modes less than 5 vol. %. Although harzburgites and dunites indicate that melt has been lost relative to primitive mantle compositions, the trace element patterns carry signatures of enrichment in incompatible elements, such as (i) “bowl-shaped” patterns of trace elements in silicate-Earth normalized spider diagrams, (ii) positive anomalies in highly incompatible trace elements such as Rb, Th, U, Ta, and (iii) enrichment of LREE in the clinopyroxenes from dunites and harzburgites. These features are indicative of complex melt transfer processes and cannot be produced by simple melt extraction. Petrographic studies reveal that harzburgite and dunite contain interstitial polyphase aggregates of olivine + Cpx + spinel + Opx and olivine + Cpx + Spinel, respectively. Experimental studies (e.g. Morgan and Liang, 2003) suggest that these aggregates represent frozen melt-rich components, indicating that fertile melt was percolating through the depleted harzburgite – dunite matrix. Presence of such “melt pods” would explain the trace element enrichment patterns of the bulk rock, as well as features such as reverse zoning (core: Cr, Fe<sup>2+</sup> rich, rim: Al, Mg rich) of spinels in polyphase aggregates in fresh dunites. These results show that melt extraction from the mantle is not a single stage process, and that evidence of multiple melt pulses that propagated through a rock are preserved in the petrographic features as well as in the form of chemical signatures that indicate refertilization of initially depleted rocks.</p>

Lamprophyres of Kayla pipe and their mantle xenocrysts, SE Yakutia

<p>The bulk rock and geochemistry of the Kayla and Khatastyr lamproites is similar to other Aldan lamproites and lamprophyres.  The ultramafic varieties are close to cratonic Ol- lamproites and alkaline Al, Si-rich varieties are closer to orogenic type.</p><p>Trace element bulk rock trace element (TRE) spider diagrams show inclined patterns with the LILE, Sr, Pb, U, peaks and Ta, Nb minima suggesting melting of originally depleted metasomatized Phl peridotites and mixed ancient (EMII, Nd, Sr isotopes) source (low crust)  and later olivine and clinopyroxene fractionation. They are dated 132-134 Ma (Late Cretaceous plume) similar to Chompolo lamprophyres and many alkaline complexes.</p><p>Thermobarometry for the deep-seated xenocrysts gives the low temperature and Sp-Gar and Gar facies for Cr- diopsides and chromites. Low - Cr- clinopyroxenes derived from lamproites give hot 90 mw/m<sup>2</sup> advective branches. </p><p>The REE patterns for Cr-diopsides are more inclined for deeper varieties and reveal Ba, Th, U, Sr peaks and minima Ta, Nd and smaller in Zr-Hf. The `low Cr diopsides show flatter REE and HFSE minima TRE patterns of parental melts are lamproitic. Salites reveal hot crust conditions.</p><p>Lamproites melted from Phl peridotite eclogites mixture in the lithosphere base and interacted with mantle beneath Moho.</p><p>The work was supported by the Ministry of Science and Higher Education of the Russian Federation RBRF grants 19-05-00788a, 18-05-00073a;  Government tasks for Institute of Geochemistry SB RAS and Institute of Geology and Mineralogy SB RAS and the governmental assignment in terms of Project IX. 129.1.4</p><p><img src="https://contentmanager.copernicus.org/fileStorageProxy.php?f=gnp.4ea3446a7a0068249921161/sdaolpUECMynit/12UGE&app=m&a=0&c=101ace07d05786aa80749a09f997276d&ct=x&pn=gnp.elif&d=1" alt=""></p><p><img src="https://contentmanager.copernicus.org/fileStorageProxy.php?f=gnp.7be3a47a7a0064449921161/sdaolpUECMynit/12UGE&app=m&a=0&c=58a37dd97ea8acf0b318506645b8f918&ct=x&pn=gnp.elif&d=1" alt=""></p><p><img src="https://contentmanager.copernicus.org/fileStorageProxy.php?f=gnp.911e478a7a0063649921161/sdaolpUECMynit/12UGE&app=m&a=0&c=ec045b1e85e57506c9df6f4987365dc2&ct=x&pn=gnp.elif&d=1" alt=""></p><p><img src="https://contentmanager.copernicus.org/fileStorageProxy.php?f=gnp.6b2d469a7a0068749921161/sdaolpUECMynit/12UGE&app=m&a=0&c=db2505c5dc47a12bf5bbe2da42dc4538&ct=x&pn=gnp.elif&d=1" alt=""></p>

Petrogenesis and tectonic implication of the lower Silurian high-Sr/Y subvolcanic rocks from the South Qilian suture zone in the Qilian Orogen, NW China

As the remnant of the South Qilian Ocean, the South Qilian suture zone recorded abundant information on the Cambrian–Ordovician subduction history of the southern branch of the Proto-Tethyan Ocean. However, the closure timing of the South Qilian Ocean and subsequent collision are poorly constrained. In this study, we report early Silurian (433–435 Ma) U–Pb ages of felsic subvolcanic rocks from Lianhuashan, Ayishan and Shihuiyao of the Lajishan district within the South Qilian suture zone. They intruded the Late Ordovician – Silurian sedimentary or Late Ordovician volcanic rocks and have high SiO2 (61.43–73.06 wt%), Sr/Y ratios with significant different rare earth elements (REEs) and trace-element spider diagrams, and Sr–Nd isotopic compositions, probably implying that they were formed through distinctly different generation mechanisms. Geochemistry of the Lianhuashan dacites reveals compositions typical of adakitic rocks derived from partial melting of lower crust in a thickened setting. The Ayishan dacites were derived from partial melting of crustal materials with the involvement of minor peridotite mantle, and the Shihuiyao rhyolites were derived from partial melting of felsic crust. The similar geochemical characteristics of coeval post-collisional igneous rocks in the Central Qilian and South Qilian blocks indicates that the lower Silurian subvolcanic rocks were generated in a thickened crust of post-collisional setting. Considering their intrusive contacts with Late Ordovician – Silurian retro-foreland basin and Late Ordovician collisional volcanic rocks, we propose that the South Qilian suture zone was at a transitional stage from collisional to post-collisional during the early Silurian Period.

Supplemental Material: Mesozoic crustal melting and metamorphism in the U.S. Cordilleran hinterland: Insights from the Sawtooth metamorphic complex, central Idaho

Geologic map of the Sawtooth metamorphic complex (Fig. S1), sample outcrop photos (Fig. S2), whole-rock spider diagrams (Fig. S3), plots of igneous zircon trace element versus zircon age (Fig. S4), rare earth element patterns of igneous zircons (Fig. S5), details of analytical methods, sample information (Table S1), whole-rock elemental data (Table S2), zircon U-Pb data (Table S3), titanite U-Pb and trace element data (Table S4), zircon trace element data (Table S5), and zircon Lu-Hf data (Table S6).

Supplemental Material: Mesozoic crustal melting and metamorphism in the U.S. Cordilleran hinterland: Insights from the Sawtooth metamorphic complex, central Idaho

Geologic map of the Sawtooth metamorphic complex (Fig. S1), sample outcrop photos (Fig. S2), whole-rock spider diagrams (Fig. S3), plots of igneous zircon trace element versus zircon age (Fig. S4), rare earth element patterns of igneous zircons (Fig. S5), details of analytical methods, sample information (Table S1), whole-rock elemental data (Table S2), zircon U-Pb data (Table S3), titanite U-Pb and trace element data (Table S4), zircon trace element data (Table S5), and zircon Lu-Hf data (Table S6).