Correction: Thiostannate coordination transformation-induced self-crosslinking chalcogenide aerogel with local coordination control and effective Cs+ remediation functionality

Correction for ‘Thiostannate coordination transformation-induced self-crosslinking chalcogenide aerogel with local coordination control and effective Cs+ remediation functionality’ by Yeo Kyung Kang et al., J. Mater. Chem. A, 2020, 8, 3468–3480, DOI: 10.1039/C9TA11282K.

Visualizing translation dynamics at atomic detail inside a bacterial cell

Translation is the fundamental process of protein synthesis and is catalysed by the ribosome in all living cells. Here, we use cryo-electron tomography and sub-tomogram analysis to visualize the dynamics of translation inside the prokaryote Mycoplasma pneumoniae. We first obtain an in-cell atomic model for the M. pneumoniae ribosome that reveals distinct extensions of ribosomal proteins. Classification then resolves thirteen ribosome states that differ in conformation and composition and reflect intermediates during translation. Based on these states, we animate translation elongation and demonstrate how antibiotics reshape the translation landscape inside cells. During translation elongation, ribosomes often arrange in a defined manner to form polysomes. By mapping the intracellular three-dimensional organization of translating ribosomes, we show that their association into polysomes exerts a local coordination mechanism that is mediated by the ribosomal protein L9. Our work demonstrates the feasibility of visualizing molecular processes at atomic detail inside cells.

Synchronising institutions and value systems: A model of opinion dynamics mediated by proportional representation

Individuals increasingly participate in online platforms where they copy, share and form they opinions. Social interactions in these platforms are mediated by digital institutions, which dictate algorithms that in turn affect how users form and evolve their opinions. In this work, we examine the conditions under which convergence on shared opinions can be obtained in a social network where connected agents repeatedly update their normalised cardinal preferences (i.e. value systems) under the influence of a non-constant reflexive signal (i.e. institution) that aggregates populations’ information using a proportional representation rule. We analyse the impact of institutions that aggregate (i) expressed opinions (i.e. opinion-aggregation institutions), and (ii) cardinal preferences (i.e. value-aggregation institutions). We find that, in certain regions of the parameter space, moderate institutional influence can lead to moderate consensus and strong institutional influence can lead to polarisation. In our randomised network, local coordination alone in the total absence of institutions does not lead to convergence on shared opinions, but very low levels of institutional influence are sufficient to generate a feedback loop that favours global conventions. We also show that opinion-aggregation may act as a catalyst for value change and convergence. When applied to digital institutions, we show that the best mechanism to avoid extremism is to increase the initial diversity of the value systems in the population.

Switching the Local Symmetry from D5h to D4h for Single-Molecule Magnets by Non-Coordinating Solvents

A solvent effect towards the performance of two single-molecule magnets (SMMs) was observed. The tetrahydrofuran and toluene solvents can switch the equatorial coordinated 4-Phenylpyridine (4-PhPy) molecules from five to four, respectively, in [Dy(OtBu)2(4-PhPy)5]BPh41 and Na{[Dy(OtBu)2(4-PhPy)4][BPh4]2}∙2thf∙hex 2. This alternation significantly changes the local coordination symmetry of the Dy(III) center from D5h to D4h for 1 and 2, seperately. Magnetic studies show that the magnetic anisotropy energy barrier of 2 is higher than that of 1, while the relation of blocking temperature is just on the contrary due to the symmetry effect. The calculations of the electrostatic potential successfully explained the driving force of solvents for the molecular structure change, confirming the feasibility of adjusting the performance of SMMs via diverse solvents.