The size effect of magnetic nanoparticles provides a various magnetic characteristic as a change of domain size. We report, synthesis of core-shell iron oxide and magnetic properties. Iron oxide particles were synthesized by co-precipitation method of iron (III) FeCl3.6H2O, iron (II) FeCl2.4H2O, in the mixture of with or without TEOS to investigated the physical properties. From XRD measurement, it was observed that all iron oxide particles with or without mixture of SiO2 has a hematite phase of a-Fe2O3. From M-H loop measurement, it was observed that the iron oxide without SiO2 has a ferromagnetic characteristic, while the iron oxide with SiO2 showed a medium state as a contribution of superparamagnetic and ferromagnetic properties.