In traditional wireless sensor networks, information transmission usually uses data encryption methods to prevent information from being stolen illegally. However, once the encryption methods are leaked, eavesdropping nodes can easily obtain information. LT codes are rateless codes; if it is attacked by random channel noise, the decoding process will change and the decoding overhead will also randomly change. When it is used for physical layer communication of wireless sensor networks, it ensures that the destination node recovers all the information without adding the key, while the eavesdropping node can only obtain part of the information to achieve wireless information security transmission. To reduce the intercept efficiency of eavesdropping nodes, a physical layer security (PLS) method of LT codes with double encoding matrix reorder (DEMR-LT codes) is proposed. This method performs two consecutive LT code concatenated encoding on the source symbol, and part of the encoding matrix is reordered according to the degree value of each column from large to small, which reduces the probability of eavesdropping nodes recovering the source information. Experimental results show that compared with other LT code PLS schemes, DEMR-LT codes only increase the decoding overhead by a small amount. However, it can effectively reduce the intercept efficiency of eavesdropping nodes and improve information transmission security.