The problem of determining the main parameters of light nuclei from precision atomic spectroscopy is considered. Within the framework of the quasipotential method in quantum electrodynamics, the energy interval [Formula: see text] in muonic ions of lithium, beryllium and boron is calculated. Corrections of orders [Formula: see text], which are determined by relativistic effects, effects of vacuum polarization, nuclear structure and recoil, as well as combined corrections, including the above, are taken into account. Nuclear structure effects are expressed in terms of the nuclear charge radius in the case of one-photon interaction and the electromagnetic form factors of nuclei in the case of two-photon interaction. The obtained numerical values for the [Formula: see text] interval can be used for comparison with future experimental data and for a more accurate determination of the nucleus charge radii.