One of the earliest uses of soils in archaeological research, in addition to stratigraphic markers, was as paleoenvironmental indicators. Similar to soil stratigraphy, the use of soils as environmental indicators in archaeological research probably has its roots in Quaternary geology (e.g., Leighton, 1937; Bryan, 1941a, 1948; Bryan and Albritton, 1943; Movius, 1944; Ruhe, 1965; Haynes, 1968; Valentine and Dalrymple, 1976). Quaternary geologists and geomorphologists working with archaeologists were quick to use soils as clues to past environments (e.g., Leighton, 1936; Antevs, 1941; Bryan, 1941a; Hopkins and Giddings, 1953; Haynes, 1968). Likewise, the nature of prehistoric environments has long been a fundamental question in archaeology. Recognition of the relationship of soil development and morphology to environmental conditions goes back to the beginning of modern pedology, in the later 19th century in Russia and in the early 20th century in the United States (Thorp, 1941, 1949; Tandarich and Sprecher, 1994; Johnson and Hole, 1994). Climate and vegetation in particular were understood as important soil-forming factors long before Jenny produced his landmark volume on Factors of Soil Formation (1941). What Jenny (1941, 1980) brought to the discussion was a theoretical means, using the state factor approach, of assessing the effect of vegetation and climate on soils. By understanding these relationships via biosequences or climosequences, we are theoretically able to pick out the morphological and chemical characteristics of soils that are linked to climate or to vegetation. Climate most directly influences pedogenesis through precipitation and temperature and influences pedogenesis indirectly through vegetation. The most direct effects of biota probably come from the addition of a wide range of chemical compounds, from bioturbation, and from rooting. This chapter is a discussion of those characteristics of soils that have some utility for environmental reconstructions, including climate and vegetation estimates. The chapter also includes some discussion of the potential pitfalls in using soils as paleoenvironmental indicators. Longer and more in-depth discussions of soil–environment relationships in the context of soil geomorphology or environmental reconstruction are presented by Birkeland (1999, pp. 268–306) and chapters in Wilding et al. (1983b) and Martini and Chesworth (1992, pp. 155–306).