Critical reviews of electro-reactivity of screen-printed nanocomposite electrode to safeguard the environment from trace metals

Author(s):  
Chyh Shyang Ong ◽  
Qi Hwa Ng ◽  
Siew Chun Low
1993 ◽  
Vol 361 (1-2) ◽  
pp. 77-83 ◽  
Author(s):  
Joseph Wang ◽  
Jianmin Lu ◽  
Baomin Tian ◽  
Chaim Yarnitzky
Keyword(s):  

2006 ◽  
Vol 573-574 ◽  
pp. 14-19 ◽  
Author(s):  
Corinne Parat ◽  
Stéphanie Betelu ◽  
Laurent Authier ◽  
Martine Potin-Gautier

Molecules ◽  
2021 ◽  
Vol 26 (18) ◽  
pp. 5502
Author(s):  
Laetitia Hackel ◽  
Elise Rotureau ◽  
Aoife Morrin ◽  
José Paulo Pinheiro

Electrochemical stripping techniques are interesting candidates for carrying out onsite speciation of environmentally relevant trace metals due to the existing low-cost portable instrumentation available and the low detection limits that can be achieved. In this work, we describe the initial analytical technique method development by quantifying the total metal concentrations using Stripping Chronopotentiometry (SCP). Carbon paste screen-printed electrodes were modified with thin films of mercury and used to quantify sub-nanomolar concentrations of lead and cadmium and sub-micromolar concentrations of zinc in river water. Low detection limits of 0.06 nM for Pb(II) and 0.04 nM for Cd(II) were obtained by the standard addition method using a SCP deposition time of 180 s. The SCP results obtained for Pb(II) and Cd(II) agreed with those of inductively coupled plasma mass spectrometry (ICP-MS). The coupling of SCP with screen-printed electrodes opens up excellent potential for the development of onsite speciation of trace metals. Due to the low analysis throughput obtained for the standard addition method, we also propose a new, more rapid screening Cd(II) internal standard methodology to significantly increase the number of samples that can be analyzed per day.


Author(s):  
B. J. Panessa ◽  
H. W. Kraner ◽  
J. B. Warren ◽  
K. W. Jones

During photoexcitation the retina requires specific electrolytes and trace metals for optimal function (Na, Mg, Cl, K, Ca, S, P, Cu and Zn). According to Hagins (1981), photoexcitation and generation of a nerve impulse involves the movement of Ca from the rhodopsin-ladened membranes of the rod outer segment (ROS) to the plasmalemma, which in turn decreases the in-flow of Na into the photoreceptor, resulting in hyperpolarization. In toad isolated retinas, the presence of Ba has been found to increase the amplitude and prolong the delay of the light response (Brown and Flaming, 1978). Trace metals such as Cu, Zn and Se are essential for the activity of the metalloenzymes of the retina and retina pigment epithelium (RPE) (i.e. carbonic anhydrase, retinol dehydrogenase, tyrosinase, glutathione peroxidase, superoxide dismutase...). Therefore the content and fluctuations of these elements in the retina and choroid are of fundamental importance for the maintenance of vision. This paper presents elemental data from light and dark adapted frog ocular tissues examined by electron beam induced x-ray microanalysis, x-ray fluorescence spectrometry (XRF) and proton induced x-ray emission spectrometry (PIXE).


Author(s):  
James S. Webber

INTRODUCTION“Acid rain” and “acid deposition” are terms no longer confined to the lexicon of atmospheric scientists and 1imnologists. Public awareness of and concern over this phenomenon, particularly as it affects acid-sensitive regions of North America, have increased dramatically in the last five years. Temperate ecosystems are suffering from decreased pH caused by acid deposition. Human health may be directly affected by respirable sulfates and by the increased solubility of toxic trace metals in acidified waters. Even man's monuments are deteriorating as airborne acids etch metal and stone features.Sulfates account for about two thirds of airborne acids with wet and dry deposition contributing equally to acids reaching surface waters or ground. The industrial Midwest is widely assumed to be the source of most sulfates reaching the acid-sensitive Northeast since S02 emitted as a byproduct of coal combustion in the Midwest dwarfs S02 emitted from all sources in the Northeast.


2003 ◽  
Vol 104 ◽  
pp. 435-438 ◽  
Author(s):  
B. S. Twining ◽  
S. B. Baines ◽  
N. S. Fisher ◽  
C. Jacobsen ◽  
J. Maser
Keyword(s):  

2003 ◽  
Vol 104 ◽  
pp. 321-324 ◽  
Author(s):  
T. Pinheiro ◽  
L. C. Alves ◽  
A. Barreiros ◽  
F. Araujo ◽  
S. Bohic ◽  
...  

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