Production of coke from scrap tire vacuum pyrolysis oil

1996 ◽  
Vol 46 (3) ◽  
pp. 227-239 ◽  
Author(s):  
A. Chaala ◽  
C. Roy
2001 ◽  
Vol 24 (1-2) ◽  
pp. 155-165 ◽  
Author(s):  
Jean Népo Murwanashyaka ◽  
Hooshang Pakdel ◽  
Christian Roy

2008 ◽  
Vol 12 (1) ◽  
pp. 157-167 ◽  
Author(s):  
Sivalingam Murugan ◽  
Chandrasekaran Ramaswamy ◽  
Govindan Nagarajan

Conversion of waste to energy is one of the recent trends in minimizing not only the waste disposal but also could be used as an alternate fuel for internal combustion engines. Fuels like wood pyrolysis oil, rubber pyrolysis oil are also derived through waste to energy conversion method. Early investigations report that tyre pyrolysis oil derived from vacuum pyrolysis method seemed to possess properties similar to diesel fuel. In the present work, the crude tyre pyrolisis oil was desulphurised and distilled to improve the properties and studied the use of it. Experimental studies were conducted on a single cylinder four-stroke air cooled engine fuelled with two different blends, 30% tyre pyrolysis oil and 70% diesel fuel (TPO 30) and 30% distilled tyre pyrolysis oil and 70% diesel fuel (DTPO 30). The results of the performance, emission and combustion characteristics of the engine indicated that NOx is reduced by about 8% compared to tire pyrolysis oil and by about 10% compared to diesel fuel. Hydrocarbon emission is reduced by about 2% compared to TPO 30 operation. Smoke increased for DTPO 30 compared to TPO 30 and diesel fuel.


2020 ◽  
Vol 224 ◽  
pp. 113327 ◽  
Author(s):  
Elena Rodríguez ◽  
Sepideh Izaddoust ◽  
José Valecillos ◽  
Javier Bilbao ◽  
José M. Arandes ◽  
...  

Author(s):  
José Ignacio Alvira ◽  
Idoia Hita ◽  
Elena Rodriguez ◽  
Jose M Arandes ◽  
Pedro Castaño

Associating the most influential parameters with the product distribution is of uttermost importance in complex catalytic processes such as fluid catalytic cracking (FCC). These correlations can lead to the information-driven catalyst screening, kinetic modeling and reactor design. In this work, a dataset of 104 uncorrelated experiments, with 64 variables, has been obtained in an FCC simulator using 6 types of feedstock (vacuum gasoil, polyethylene pyrolysis waxes, scrap tire pyrolysis oil, dissolved polyethylene and blends of the previous), 36 possible sets of conditions (varying contact time, temperature and catalyst/oil ratio) and 3 industrial catalysts. Principal component analysis (PCA) has been applied over the dataset, showing that the main components are associated with feed composition (27.41% variance); operational conditions (19.09%) and catalyst properties (12.72%). The variables of each component have been correlated with the indexes and yields of the products: conversion, octane number, aromatics, olefins (propylene) or coke, among others.


Holzforschung ◽  
2002 ◽  
Vol 56 (2) ◽  
pp. 167-175 ◽  
Author(s):  
Carlos Amen-Chen ◽  
Bernard Riedl ◽  
Xiang-Ming Wang ◽  
Christian Roy

Summary Bark residues generated by the pulp and paper and wood industries represent a threat to the environment due to leaching of chemicals such as phenolics and resin acids which are being currently regulated by governments. Vacuum pyrolysis of resinous bark produces phenolic-rich oils which represent a potential raw material to replace petroleum-based phenol presently used in the formulation of wood adhesive resols. Resols with different levels of phenol replacement by phenolic pyrolysis oils, formaldehyde to phenolics molar ratios and sodium hydroxide to phenolics molar ratios were synthesized. Strandboards werepreparedandtheirmechanicalandphysicalpropertiessuchasmodulusofrupture(MOR),modulus of elasticity (MOE), dry and 2-hour boil internal bond (IB) and thickness swelling (TS) were evaluated. Homogeneous panels bonded with resins having 25 and 50% by wt of pyrolysis oils replacing phenol exhibited comparable mechanical properties to those of panels made with a commercial surface resin under the same pressing conditions. Three-layer panels made with resins having 50 % by wt phenol replacement in the surface and 25% by wt phenol replacement in the core had mechanical properties above the requirements specified by the Canadian Standards CSAO437.0-93 for OSB products.


Processes ◽  
2018 ◽  
Vol 6 (12) ◽  
pp. 243 ◽  
Author(s):  
José Alvira ◽  
Idoia Hita ◽  
Elena Rodríguez ◽  
José Arandes ◽  
Pedro Castaño

Establishing a reaction network is of uttermost importance in complex catalytic processes such as fluid catalytic cracking (FCC). This step is the seed for a faithful reactor modeling and the subsequent catalyst re-design, process optimization or prediction. In this work, a dataset of 104 uncorrelated experiments, with 64 variables, was obtained in an FCC simulator using six types of feedstock (vacuum gasoil, polyethylene pyrolysis waxes, scrap tire pyrolysis oil, dissolved polyethylene and blends of the previous), 36 possible sets of conditions (varying contact time, temperature and catalyst/oil ratio) and three industrial catalysts. Principal component analysis (PCA) was applied over the dataset, showing that the main components are associated with feed composition (27.41% variance), operational conditions (19.09%) and catalyst properties (12.72%). The variables of each component were correlated with the indexes and yields of the products: conversion, octane number, aromatics, olefins (propylene) or coke, among others. Then, a data-driven reaction network was proposed for the cracking of waste feeds based on the previously obtained correlations.


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