Synthesis, characterization, DFT and antimicrobial studies of transition metal ion complexes of a new schiff base ligand, 5-methylpyrazole-3yl-N-(2́-hydroxyphenylamine)methyleneimine, (MPzOAP)

2019 ◽  
Vol 1178 ◽  
pp. 100-111 ◽  
Author(s):  
Susmita Mandal ◽  
Mousumi Das ◽  
Piu Das ◽  
Amalesh Samanta ◽  
Ray J. Butcher ◽  
...  
Keyword(s):  
Schiff Base ◽  
Transition Metal ◽  
Schiff Base Ligand ◽  
Metal Ion ◽  
Metal Ion Complexes ◽  
Transition Metal Ion ◽  
Antimicrobial Studies

scholarly journals Synthesis, Characterization and Magnetic Susceptibility of Novel Transition Metal Ion Complexes with (E)-2-((7H-Purin-6-ylimino)methyl)phenol and Its Antibacterial Efficiency

2021 ◽  
Vol 7 (4) ◽  
pp. 748-750
Author(s):  
S. Tihile Mangesh ◽  
N. Chaudhari Gajanan
Keyword(s):  
Magnetic Susceptibility ◽  
Schiff Base ◽  
Transition Metal ◽  
Metal Ion ◽  
Spectroscopic Techniques ◽  
The Novel ◽  
Metal Ion Complexes ◽  
Transition Metal Ion ◽  
Ft Ir

The novel transition metal ion complexes were synthesized by refluxing the ethanolic solutions of metal acetates with Schiff base in 1:2 ratios. The structure and characterization of synthesized complexes of Mn (II), Co (II), Ni (II), Cu (II) and Zn (II) with Schiff base (E)-2-((7H-purin-6-ylimino)methyl)phenol were elucidated by using 1H NMR, FT-IR and UV-Visible spectroscopic techniques. The synthesized compounds were also been screened against gram positive and gram-negative bacteria. The novel compounds were further carried out for the study of magnetic susceptibility.

scholarly journals Synthesis and Spectral Analysis of Some Metal Ions Complexes with Mixed Ligands of Schiff Base and 1, 10-Phenanthroline

2017 ◽  
Vol 14 (1) ◽  
pp. 135-147
Author(s):  
Baghdad Science Journal
Keyword(s):  
Schiff Base ◽  
Metal Ions ◽  
Metal Complexes ◽  
Mass Spectrometer ◽  
Schiff Base Ligand ◽  
Metal Ion ◽  
Molecular Structures ◽  
Spectroscopic Techniques ◽  
Metal Ion Complexes ◽  
Free Schiff Base

The free Schiff base ligand (HL1) is prepared by being mixed with the co-ligand 1, 10-phenanthroline (L2). The product then is reacted with metal ions: (Cr+3, Fe+3, Co+2, Ni+2, Cu+2 and Cd+2) to get new metal ion complexes. The ligand is prepared and its metal ion complexes are characterized by physic-chemical spectroscopic techniques such as: FT-IR, UV-Vis, spectra, mass spectrometer, molar conductivity, magnetic moment, metal content, chloride content and microanalysis (C.H.N) techniques. The results show the formation of the free Schiff base ligand (HL1). The fragments of the prepared free Schiff base ligand are identified by the mass spectrometer technique. All the analysis of ligand and its metal complexes are in good agreement with the theoretical values indicating the purity of Schiff base ligand and the metal complexes. From the above data, the molecular structures for all the metal complexes are proposed to be octahedral

scholarly journals Synthesis and crystal structures of transition metal ion complexes of di(2-thienyl)imide

Polyhedron ◽  
2017 ◽  
Vol 127 ◽  
pp. 505-511
Author(s):  
Ting Jiang ◽  
Tejal K. Naik ◽  
Cynthia S. Day ◽  
Ronald E. Noftle
Keyword(s):  
Transition Metal ◽  
Crystal Structures ◽  
Metal Ion ◽  
Metal Ion Complexes ◽  
Transition Metal Ion
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