In a typical multipath propagation environment, there exists a strong direct path signal accompanying with several weak multipath signals. Due to the strong direct path interference and other masking effects, the Direction-of-Arrival (DOA) of a weak multipath signal is hard to be estimated. In this paper, a novel method is proposed to estimate the DOA of multipath signals with ultralow signal-to-noise ratio (SNR). The main idea is to increase the SNR and signal-to-interference ratio (SIR) of the desired multipath signal in time-delay domain before DOA estimation processing. Firstly, the cross-correlation functions of the direct path signal and the received array signal are calculated. Then, they are combined and constructed to an enhanced array signal. Under certain conditions, the SNR and SIR of the desired signal can be significantly increased. Finally, the DOAs of multipath signals can be estimated by conventional technologies, and the associated time delays can be measured on the DOA-time-shift map. The SNR and SIR gains of the desired signal are analyzed theoretically, and theoretical analysis also indicates that the Cramer–Rao bound can be reduced. Simulation examples are presented to verify the advantages of the proposed method.