scholarly journals Biomarkers and C and S Isotopes of the Permian to Triassic Solid Bitumen and Its Potential Source Rocks in NE Sichuan Basin

Geofluids ◽  
2017 ◽  
Vol 2017 ◽  
pp. 1-14 ◽  
Author(s):  
Chunfang Cai ◽  
Chenlu Xu ◽  
Wenxiang He ◽  
Chunming Zhang ◽  
Hongxia Li

The potential parent source rocks except from Upper Permian Dalong Formation (P3d) for Upper Permian and Lower Triassic solid bitumen show high maturity to overmaturity with equivalent vitrinite reflectance (ERo) from 1.7% to 3.1% but have extractable organic matter likely not contaminated by younger source rocks. P3d source rocks were deposited under euxinic environments as indicated by the pyrite δ34S values as light as -34.5‰ and distribution of aryl isoprenoids, which were also detected from the Lower Silurian (S1l) source rock and the solid bitumen in the gas fields in the west not in the east. All the solid bitumen not altered by thermochemical sulfate reduction (TSR) has δ13C and δ34S values similar to part of the P3l kerogens and within the S1l kerogens. Thus, the eastern solid bitumen may have been derived from the P3l kerogens, and the western solid bitumen was likely to have precracking oils from P3l kerogens mixed with the S1l or P3d kerogens. This case-study tentatively shows that δ13C and δ34S values along with biomarkers have the potential to be used for the purpose of solid bitumen and source rock correlation in a rapidly buried basin, although further work should be done to confirm it.

Author(s):  
S., R. Muthasyabiha

Geochemical analysis is necessary to enable the optimization of hydrocarbon exploration. In this research, it is used to determine the oil characteristics and the type of source rock candidates that produces hydrocarbon in the “KITKAT” Field and also to understand the quality, quantity and maturity of proven source rocks. The evaluation of source rock was obtained from Rock-Eval Pyrolysis (REP) to determine the hydrocarbon type and analysis of the value of Total Organic Carbon (TOC) was performed to know the quantity of its organic content. Analysis of Tmax value and Vitrinite Reflectance (Ro) was also performed to know the maturity level of the source rock samples. Then the oil characteristics such as the depositional environment of source rock candidate and where the oil sample develops were obtained from pattern matching and fingerprinting analysis of Biomarker data GC/GCMS. Moreover, these data are used to know the correlation of oil to source rock. The result of source rock evaluation shows that the Talangakar Formation (TAF) has all these parameters as a source rock. Organic material from Upper Talangakar Formation (UTAF) comes from kerogen type II/III that is capable of producing oil and gas (Espitalie, 1985) and Lower Talangakar Formation (LTAF) comes from kerogen type III that is capable of producing gas. All intervals of TAF have a quantity value from very good–excellent considerable from the amount of TOC > 1% (Peters and Cassa, 1994). Source rock maturity level (Ro > 0.6) in UTAF is mature–late mature and LTAF is late mature–over mature (Peters and Cassa, 1994). Source rock from UTAF has deposited in the transition environment, and source rock from LTAF has deposited in the terrestrial environment. The correlation of oil to source rock shows that oil sample is positively correlated with the UTAF.


2005 ◽  
Vol 45 (1) ◽  
pp. 253
Author(s):  
D. Dawson ◽  
K. Grice ◽  
R. Alexander

A relationship has been identified between the maturity level of source rocks and the stable hydrogen isotopic compositions (δD) of extracted saturated hydrocarbons, based on the analysis of nine sediments and five crude oils from the Perth Basin (WA). The sediments cover the immature to late mature range. Distinct δD signatures are observed for the immature sediments where pristane and phytane are significantly depleted in deuterium (D) relative to the n-alkanes. With increasing maturity the difference between the δD values of n-alkanes and isoprenoids reduces as pristane and phytane become progressively enriched in D. The n-alkane–isoprenoid δD signature of the crude oils, including one from a different source facies, is similar to mature–late mature sediments representative of the peak oil–generative window. Enrichment of D in isoprenoids is attributed to isotopic exchange associated with thermal maturation. Average δD values of pristane and phytane correlate well with vitrinite reflectance, as does the biomarker maturity parameter Ts/Tm. The limited data set suggests that δD values of aliphatic hydrocarbons may be useful for establishing thermal maturity, particularly when other maturity parameters are not appropriate. Furthermore, we suggest δD values may be useful over a wider maturity range than traditional parameters, particularly at very high maturity where biomarker parameters are no longer effective.


2016 ◽  
Vol 56 (1) ◽  
pp. 173 ◽  
Author(s):  
Stephen Molyneux ◽  
Jeff Goodall ◽  
Roisin McGee ◽  
George Mills ◽  
Birgitta Hartung-Kagi

Why are the only commercial hydrocarbon discoveries in Lower Triassic and Permian sediments of the western margin of Australia restricted to the Perth Basin and the Petrel Sub-basin? Recent regional analysis by Carnarvon Petroleum has sought to address some key questions about the Lower Triassic Locker Shale and Upper Permian Chinty and Kennedy formations petroleum systems along the shallow water margin of the Carnarvon and offshore Canning (Roebuck/Bedout) basins. This paper aims to address the following questions:Source: Is there evidence in the wells drilled to date of a working petroleum system tied to the Locker Shale or other pre-Jurassic source rocks? Reservoir: What is the palaeogeography and sedimentology of the stratigraphic units and what are the implications for the petroleum systems?The authors believed that a fresh look at the Lower Triassic to Upper Permian petroleum prospectivity of the North West Shelf would be beneficial, and key observations arising from the regional study undertaken are highlighted:Few wells along a 2,000 km area have drilled into Lower Triassic Locker Shale or older stratigraphy. Several of these wells have been geochemically and isotopically typed to potentially non Jurassic source rocks. The basal Triassic Hovea Member of the Kockatea Shale in the Perth Basin is a proven commercial oil source rock and a Hovea Member Equivalent has been identified through palynology and a distinctive sapropelic/algal kerogen facies in nearly 16 wells that penetrate the full Lower Triassic interval on the North West Shelf. Samples from the Upper Permian, the Hovea Member Equivalent and the Locker Shale have been analysed isotopically indicating –28, –34 and –30 delta C13 averages, respectively. Lower Triassic and Upper Permian reservoirs are often high net to gross sands with up to 1,000 mD permeability and around 20% porosity. Depositional processes are varied, from Locker Shale submarine canyon systems to a mixed carbonate clastic marine coastline/shelf of the Upper Permian Chinty and Kennedy formations.


2020 ◽  
Vol 10 (8) ◽  
pp. 3191-3206
Author(s):  
Olusola J. Ojo ◽  
Ayoola Y. Jimoh ◽  
Juliet C. Umelo ◽  
Samuel O. Akande

Abstract The Patti Formation which consists of sandstone and shale offers the best potential source beds in the Bida Basin. This inland basin is one of the basins currently being tested for hydrocarbon prospectivity in Nigeria. Fresh samples of shale from Agbaja borehole, Ahoko quarry and Geheku road cut were analysed using organic geochemical and palynological techniques to unravel their age, paleoecology, palynofacies and source bed hydrocarbon potential. Palynological data suggest Maastrichtian age for the sediments based on the abundance of microfloral assemblage; Retidiporites magdalenensis, Echitriporites trianguliformis and Buttinia andreevi. Dinocysts belonging to the Spiniferites, Deflandrea and Dinogymnium genera from some of the analysed intervals are indicative of freshwater swamp and normal sea conditions. Palynological evidence further suggests mangrove paleovegetation and humid climate. Relatively high total organic carbon TOC (0.77–8.95 wt%) was obtained for the shales which implies substantial concentration of organic matter in the source beds. Hydrocarbon source rock potential ranges from 0.19 to 0.70 mgHC/g.rock except for a certain source rock interval in the Agbaja borehole with high yield of 25.18 mgHC/g.rock. This interval also presents exceptionally high HI of 274 mgHC/g.TOC and moderate amount of amorphous organic matter. The data suggests that in spite of the favourable organic matter quantity, the thermal maturity is low as indicated by vitrinite reflectance and Tmax (0.46 to 0.48 Ro% and 413 to 475 °C, respectively). The hydrocarbon extracts show abundance of odd number alkanes C27–C33, low sterane/hopane ratio and Pr/Ph > 2. We conclude that the source rocks were terrestrially derived under oxic condition and dominated by type III kerogen. Type II organic matter with oil and gas potential is a possibility in Agbaja area of Bida Basin. Thermal maturity is low and little, or no hydrocarbon has been generated from the source rocks.


Energies ◽  
2019 ◽  
Vol 12 (4) ◽  
pp. 650 ◽  
Author(s):  
Jinliang Zhang ◽  
Jiaqi Guo ◽  
Jinshui Liu ◽  
Wenlong Shen ◽  
Na Li ◽  
...  

The Lishui Sag is located in the southeastern part of the Taibei Depression, in the East China Sea basin, where the sag is the major hydrocarbon accumulation zone. A three dimensional modelling approach was used to estimate the mass of petroleum generation and accumulated during the evolution of the basin. Calibration of the model, based on measured maturity (vitrinite reflectance) and borehole temperatures, took into consideration two main periods of erosion events: a late Cretaceous to early Paleocene event, and an Oligocene erosion event. The maturation histories of the main source rock formations were reconstructed and show that the peak maturities have been reached in the west central part of the basin. Our study included source rock analysis, measurement of fluid inclusion homogenization temperatures, and basin history modelling to define the source rock properties, the thermal evolution and hydrocarbon generation history, and possible hydrocarbon accumulation processes in the Lishui Sag. The study found that the main hydrocarbon source for the Lishui Sag are argillaceous source rocks in the Yueguifeng Formation. The hydrocarbon generation period lasted from 58 Ma to 32 Ma. The first period of hydrocarbon accumulation lasted from 51.8 Ma to 32 Ma, and the second period lasted from 23 Ma to the present. The accumulation zones mainly located in the structural high and lithologic-fault screened reservoir filling with the hydrocarbon migrated from the deep sag in the south west direction.


2021 ◽  
pp. 1-31
Author(s):  
Zhenglu Xiao ◽  
Shijia Chen ◽  
Xiangdong Yin ◽  
Pan Wang ◽  
Jiang Zhu ◽  
...  

There are three sets of potential source rocks in the Yanchang Formation in the east part of the Shanbei Slope in the Ordos Basin. Based on the experimental results of total organic carbon, vitrinite reflectance, rock organic matter extraction, and saturated hydrocarbon chromatography (GC-MS), we have analyzed the geochemical and biomarker characteristics of the Chang 7, Chang 8, and Chang 9 source rocks, and the Chang 8 reservoir extracts and find that the Chang 7, Chang 8, and Chang 9 source rocks were deposited in the sedimentary environment of weak oxidation and weak reduction. Higher plants contribute more in the parent materials of the Chang 7 and Chang 9 source rocks, whereas lower aquatic organisms contribute more to the Chang 8 source rock. However, the source of the Chang 8 crude oil in the east part of Shanbei Slope does not match the chemical fingerprint of the Chang 8 source rock. To address this problem, we examined samples taken from the Zhidan oilfield, where our results show that the Chang 7, Chang 8, and Chang 9 source rocks all have hydrocarbon-supplying capacity. The relative abundance of regular steranes (C27, C28, C29) and hopane (17α(H), 21β(H)-hopane, 17β(H)-rearranged hopane, 18α(H)-22,29,30-trinorhopane) provides a means to assign the crude oil components to a given. Further analysis of the biomarkers of the three source rocks and those of the Chang 8 crude oil indicate that crude oil in the Chang 8 reservoir was not generated in situ; rather, it was supplied by the underlying Chang 9 source rock.


2019 ◽  
Vol 27 (1) ◽  
pp. petgeo2019-050
Author(s):  
Tesfamariam Berhane Abay ◽  
Katrine Fossum ◽  
Dag Arild Karlsen ◽  
Henning Dypvik ◽  
Lars Jonas Jørgensen Narvhus ◽  
...  

The shallow-marine Upper Jurassic–Lower Cretaceous sedimentary successions of the Mandawa Basin, coastal Tanzania, are located about 80 km away from the offshore gas discoveries of Block 2, Tanzania. In this paper we present petroleum geochemical data, including bitumen extracted from outcrop samples which are relevant to the understanding of the onshore ‘Petroleum System’ and possibly also to the offshore basin. Despite some biodegradation and weathering, common to all outcrop samples, most bitumen samples analysed contain mature migrated oil. The maturity span of geomarkers (C13–C15 range) covers the entire oil and condensate/wet gas window (Rc = 0.7–2% Rc, where Rc is the calculated vitrinite reflectance), with the biomarkers generally indicating the oil window (Rc = 0.7–1.3% Rc). This suggests that the bitumen extracts represent several phases of migrated oil and condensate, which shows that the samples are part of an active or recently active migration regime or ‘Petroleum System’. The source-rock facies inferred for the bitumen is Type II/III kerogen of siliciclastic to carbonate facies. This is oil-prone kerogen, typical for a marine depositional system with an influx of proximal-derived terrigenous material blended in with in situ marine algal organic matter (OM). Application of age-specific biomarkers such as the C28/C29-steranes, extended tricyclic terpane ratio (ETR), nordiacholestanes and the aromatic steroids suggest that more than one source rock have contributed to the bitumen. Possible ages are limited to the Mesozoic (i.e. excluding the Late Paleozoic), with the most likely source rock belonging to the Early Jurassic. More geochemical and geological studies should be undertaken to further develop the general understanding of the petroleum system of the Mandawa Basin and its implications to the ‘Petroleum Systems’ both offshore and onshore. This paper also presents a reinterpretation of published gas composition and isotope data on the Pande, Temane and Inhassoro gas fields (Mozambique) with implications for possible oil discoveries in the gas-dominated region.


2020 ◽  
Vol 4 (2) ◽  
pp. 35-47
Author(s):  
Rzger Abdula ◽  
Hema Hassan ◽  
Maryam Sliwa

The petroleum system of the Akri-Bijeel oil field shows that the Palaeogene formations such as the Kolosh Formation seem to be immature. However, the Jurassic–Lower Cretaceous source rocks such as those from the Chia Gara, Naokelekan, and Sargelu formations are thermally mature and within the main oil window because their vitrinite reflectance (Ro%) values are >0.55%. The Triassic Kurra Chine and Geli Khana formations are thought to be in the high maturity stage with Ro values ≥1.3% and within the wet and dry gas windows, whereas the older formations are either within the dry gas zone or completely generated hydrocarbon stage and depleted after the hydrocarbons were expelled with subsequent migration to the reservoir rock of the structural traps.


1986 ◽  
Vol 128 ◽  
pp. 103-121
Author(s):  
F Surlyk ◽  
S Piasecki ◽  
F Rolle

Active petroleum exploration in East Greenland is of fairly recent date and was preceded by a much longer history of scientific work and mineral exploration. The discovery in 1948 of lead-zinc mineralisation at Mestersvig resulted in the formation of Nordisk Mineselskab AIS in 1952. In the beginning of the seventies Nordisk Mineselskab initiated cooperation with the American oil company Atlantic Richfield (ARCO) in order to undertake petroleum exploration in Jameson Land. The Jameson Land basin contains a very thick Upper Palaeozoic - Mesozoic sedimentary sequence. Important potential source rocks are Lower Permian lacustrine mudstone, Upper Permian black marine mudstone, Middle Triassic dark marine limestone, uppermost Triassic black marginal marine mudstone, Lower Jurassic black mudstone and Upper Jurassic deep shelf black mudstone. Tbe Upper Permian mudstone, which is the most promising source rock, is immature to weakly mature along the western basin margin and is expected to be in the oil or gas-generating zone when deeply buried in the central part of the basin. Potential reservoir rocks include Upper Permian bank and mound limestones, uppermost Permian fan delta sandstones, Lower Triassic aeolian and braided river sandstones, and Lower, Middle and Upper Jurassic sandstones. The most important trap types are expected to be stratigraphic, such as Upper Permian limestone bodies, or combination stratigraphic-structural such as uppermost Permian or Lower Triassic sandstones in Early Triassic tilted fault blocks. In the offshore areas additional play types are probably to be found in tilted Jurassic fault blocks containing thick Lower, Middle and Upper Jurassic sandstones and lowermost Cretaceous sandstones and conglomerates. The recognition of the potential of the Upper Permian in petroleum exploration in East Greenland has important implications for petroleum exploration on the Norwegian shelf.


2016 ◽  
Author(s):  
Samuel Salufu ◽  
Rita Onolemhemhen ◽  
Sunday Isehunwa

ABSTRACT This paper sought to use information from outcrop sections to characterize the source and reservoir rocks in a basin in order to give indication(s) for hydrocarbon generation potential in a basin in minimizing uncertainty and risk that are allied with exploration and field development of oil and gas, using subsurface data from well logs, well sections, seismic and core. The methods of study includes detailed geological, stratigraphical, geochemical, structural,, petro-graphical, and sedimentological studies of rock units from outcrop sections within two basins; Anambra Basin and Abakaliki Basin were used as case studies. Thirty eight samples of shale were collected from these Basins; geochemical analysis (rockeval) was performed on the samples to determine the total organic content (TOC) and to assess the oil generating window. The results were analyzed using Rock wares, Origin, and Surfer software in order to properly characterize the potential source rock(s) and reservoir rock(s) in the basins, and factor(s) that can favour hydrocarbon traps. The results of the geological, stratigraphical, sedimentological, geochemical, and structural, were used to developed a new model for hydrocarbon generation in the Basins. The result of the geochemical analysis of shale samples from the Anambra Basin shows that the TOC values are ≥ 1wt%, Tmax ≥ 431°C, Vitrinite reflectance values are ≥ 0.6%, and S1+S2 values are > 2.5mg/g for Mamu Formation while shale samples from other formations within Anambra Basin fall out of these ranges. The shale unit in the Mamu Formation is the major source rock for oil generation in the Anambra Basin while others have potential for gas generation with very little oil generation. The shale samples from Abakaliki Basin shows that S1+S2 values range from< 1 – 20mg/g, TOC values range from 0.31-4.55wt%, vitrinite reflectance ranges from 0.41-1.24% and Tmax ranges from423°C – 466°C. This result also shows that there is no source rock for oil generation in Abakaliki Basin; it is either gas or graphite. This observation indicates that all the source rocks within Abakaliki Basin have exceeded petroleum generating stage due to high geothermal heat resulting from deep depth or the shale units have not attained catagenesis stage as a result of S1+S2 values lesser than 2.5mg/g despite TOC values of ≥ 0.5wt% and vitrinite reflectance values of ≥ 0.6%. The novelty of this study is that the study has been able to show that here there is much more oil than the previous authors claimed, and the distribution of this oil and gas in the basins is controlled by two major factors; the pattern of distribution of the materials of the source rock prior to subsidence and during the subsidence period in the basin, and the pattern and the rate of tectonic activities, and heat flow in the basin. If these factors are known, it would help to reduce the uncertainties associated with exploration for oil and gas in the two basins.


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