Investigation of Long-term Corrosion of AA2024 and AA5119 Aluminum Alloys under chromate coating in Marine Atmosphere by Electrochemical Impedance Technology

2022 ◽  
pp. ArticleID:22014
Author(s):  
Yan Li ◽  
Keyword(s):  
Aluminum Alloys ◽  
Electrochemical Impedance ◽  
Marine Atmosphere ◽  
Chromate Coating

Corrosion Evaluation of Rust Converter and Microcrystalline Wax on Cannon Balls from San Juan de Ulua Fortress

2014 ◽  
Vol 1618 ◽  
pp. 227-232
Author(s):  
R. Orozco-Cruz ◽  
M. Ambros-Peralta ◽  
R. Galvan-Martinez ◽  
J. Reyes-Trujeque
Keyword(s):  
Electrochemical Impedance ◽  
Electrochemical Techniques ◽  
Metallic Surface ◽  
Marine Atmosphere ◽  
Efficient Tool ◽  
Corrosion Evaluation ◽  
Historical Heritage ◽  
New Compounds ◽  
Metallic Artifacts

ABSTRACTOne of the main problems encountered by curators and conservators in charge of metallic collections from Historical Heritage is related to their long-term conservation, since metallic artifacts undergo corrosion phenomena, which are the result of the interaction between the metal and its environment. The use of rust converters and microcrystalline waxes can be an ecological alternative to the traditional and more aggressive conservation techniques. Although the mechanism of action of these compounds is not clear, it is assumed that they react with iron oxides and generate new compounds that may have a passivation effect on the metallic surface. This paper proposes to show how simple electrochemical techniques can be used as an efficient tool to contribute to the diagnosis of the conservation state of cannon balls and to monitor the restoration treatment. The objective of the present work is to evaluate the effectiveness of a rust converter based on tannins and phosphoric acid, and one microcrystalline wax applied on cannon balls samples exposed to a marine atmosphere. The protection properties of the oxide or conversion layer are evaluated by electrochemical impedance spectroscopy (EIS) technique. The results obtained suggest that the use of the rust converter and microcrystalline wax protects the cannon balls, even though its effect is less evident when the deterioration degree is larger.

Electrochemical Impedance Characteristics of Sintered 7075 Aluminum Alloy Under Ssrt Condition

2013 ◽  
Vol 58 (2) ◽  
pp. 505-508 ◽  
Author(s):  
S. Sunada ◽  
N. Nunomura
Keyword(s):  
Aluminum Alloys ◽  
Complex Shape ◽  
Electrochemical Impedance ◽  
Ingot Metallurgy ◽  
View Point ◽  
Corrosion Properties ◽  
Electrochemical Tests ◽  
Impedance Characteristics ◽  
Polarization Test ◽  
Conventional Ingot

Powder metallurgy (P/M) process has the advantage of better formability to fabricate complex shape products without machining and welding. And recently this P/M process has been applied to the production of aluminum alloys. The P/M aluminum alloys thus produced also have received considerable interest because of their fine and homogeneous structure. Many papers have been published on the mechanical properties of the aluminum alloys produced by P/M process while there have been few on their corrosion properties from the view point of electrochemistry. In this experiment, therefore, two kinds of 7075 aluminum alloys prepared by the conventional ingot metallurgy (I/M) process and P/M process were used, I/M material is commercially available. and their corrosion behavior were investigated through the electrochemical tests such as potentiodynamic polarization test, slow rate strain tensile (SSRT) test and electrochemical impedance spectroscopy (EIS) measurement under SSRT test in the corrosion solution and the deionized water.

scholarly journals Surface Modification of Aluminum 6061-O Alloy by Plasma Electrolytic Oxidation to Improve Corrosion Resistance Properties

Coatings ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 4
Author(s):  
Dmitry V. Dzhurinskiy ◽  
Stanislav S. Dautov ◽  
Petr G. Shornikov ◽  
Iskander Sh. Akhatov
Keyword(s):  
Corrosion Resistance ◽  
Aluminum Alloy ◽  
Aluminum Alloys ◽  
Plasma Electrolytic Oxidation ◽  
Electrochemical Impedance ◽  
High Strength ◽  
Electrolytic Oxidation ◽  
Coating Layers ◽  
Plasma Electrolytic ◽  
High Strength Aluminum Alloys

In the present investigation, the plasma electrolytic oxidation (PEO) process was employed to form aluminum oxide coating layers to enhance corrosion resistance properties of high-strength aluminum alloys. The formed protective coating layers were examined by means of scanning electron microscopy (SEM) and characterized by several electrochemical techniques, including open circuit potential (OCP), linear potentiodynamic polarization (LP) and electrochemical impedance spectroscopy (EIS). The results were reported in comparison with the bare 6061-O aluminum alloy to determine the corrosion performance of the coated 6061-O alloy. The PEO-treated aluminum alloy showed substantially higher corrosion resistance in comparison with the untreated substrate material. A relationship was found between the coating formation stage, process parameters and the thickness of the oxide-formed layers, which has a measurable influence on enhancing corrosion resistance properties. This study demonstrates promising results of utilizing PEO process to enhance corrosion resistance properties of high-strength aluminum alloys and could be recommended as a method used in industrial applications.

Effects of the Rolling Directions on Wear of the Aluminum Alloys

2021 ◽  
Vol 901 ◽  
pp. 193-198
Author(s):  
Yuh Ping Chang ◽  
Li Ming Chu ◽  
Chien Te Liu ◽  
Jin Chi Wang ◽  
Gao Wei Chen
Keyword(s):  
Wear Resistance ◽  
Aluminum Alloys ◽  
Rolling Direction ◽  
Optical Microscope ◽  
Operating Conditions ◽  
Crystal Phase ◽  
Transportation Industry ◽  
Key Technology ◽  
Crystal Grains

Due to the booming development of the automation industry and the transportation industry, the mechanical components are prone to wear under long-term operating conditions. To improve the wear resistance, effects of the rolling directions on wear of the aluminum alloys are studied. An optical microscope is used to analyze the crystal phase, and the correlation between the crystal grains and the rolling direction is studied. This study can therefore establish a key technology for improving the wear resistance of aluminum alloys.

PROSPECTS FOR THE USE OF HOT ISOSTATIC PRESSING IN CAST ALUMINUM ALLOYS (review)

2021 ◽  
pp. 17-26
Author(s):  
E.A. Prokhorchuk ◽  
◽  
K.A. Vlasova ◽  
A.V. Trapeznikov ◽  
Yu.V. Reshetnikov ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Aluminum Alloys ◽  
Hot Isostatic Pressing ◽  
Term Strength ◽  
Cast Aluminum ◽  
Dense Structure ◽  
Isostatic Pressing ◽  
Cast Aluminum Alloys ◽  
Strength Tests

The article provides an overview of studies on the influence of HIP on the density, roughness and mechanical properties of cast aluminum alloys. As a result of HIP, the density of the alloy, its ductility, and cyclic characteristics increase, and the scatter of mechanical properties determined during tensile and long-term strength tests decreases. The use of HIP increases the yield of good casting due to the reduction of rejects due to unacceptable porosity detected during х-ray inspection. Thus, the casting acquires a homogeneous, completely dense structure.

Creep–rupture model of aluminum alloys: Cohesive zone approach

2014 ◽  
Vol 229 (8) ◽  
pp. 1343-1347 ◽  
Author(s):  
Kyungmok Kim
Keyword(s):  
Aluminum Alloys ◽  
Cohesive Zone ◽  
Rupture Life ◽  
Stress Rupture ◽  
Creep Rupture ◽  
Time Dependent ◽  
Element Analysis ◽  
Rupture Model ◽  
Term Creep

In this article, a creep–rupture model of aluminum alloys is developed using a time-dependent cohesive zone law. For long-term creep rupture, a time jump strategy is used in a cohesive zone law. Stress–rupture scatter of aluminum alloy 4032-T6 is fitted with a power law form. Then, change in the slope of a stress-rupture line is identified on a log–log scale. Implicit finite element analysis is employed with a model containing a cohesive zone. Stress–rupture curves at various given temperatures are calculated and compared with experimental ones. Results show that a proposed method allows predicting creep–rupture life of aluminum alloys.

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