scholarly journals Improvement of the turn-down ratio of gas turbines by autothermal on board syngas generation

2017 ◽  
Vol 1 ◽  
pp. D0HPA5 ◽  
Author(s):  
Max H. Baumgärtner ◽  
Thomas Sattelmayer
Keyword(s):  
Natural Gas ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Equivalence Ratio ◽  
Burning Velocity ◽  
Combined Cycle ◽  
Sudden Increase ◽  
High Hydrogen ◽  
Fuel Processor ◽  
Burn Out

Abstract The low reactivity of natural gas leads to a sudden increase of carbon monoxide (CO) and unburned hydrocarbons (UHC) emissions below a certain load level, which limits the part load operation range of current utility gas turbines in combined cycle power plants (CCPP). The feasibility of catalytic autothermal syngas generation directly upstream of gas turbine burners to improve burn-out at low flame temperatures is studied in this paper. The adiabatic reformer is supplied with a mixture of natural gas, air and water and generates syngas with high reactivity, which results in better low-temperature combustion performance. Substitution of part of the natural gas by syngas provides the opportunity of lowering overall equivalence ratio in the combustion chamber and of extending the operation range towards lower minimum power output without violating emission limits. A generic gas turbine with a syngas generator is modelled by analytic equations to identify the possible operating window of a fuel processor constrained by pressure loss, low and high temperature limits and carbon formation. A kinetic study shows good conversion of methane to syngas with a high hydrogen share. A calculation of the one-dimensional laminar burning velocity of mixtures of syngas and methane and the assessment of the corresponding Damköhler number show the potential for lowering the minimum equivalence ratio with full burn-out by fuel processing. The study shows that such a fuel processor has a possible operating range despite the before mentioned constraints and it has potential to reduce the lowest possible load of gas turbines in terms of thermal power by 20%.

Low Load Operation Range Extension by Autothermal On-Board Syngas Generation

2017 ◽  
Author(s):  
Max H. Baumgärtner ◽  
Thomas Sattelmayer
Keyword(s):  
Natural Gas ◽  
Gas Turbines ◽  
Power Plants ◽  
Renewable Energy Sources ◽  
Flame Temperature ◽  
Combined Cycle ◽  
Sudden Increase ◽  
Gaseous Emissions ◽  
Fuel Processor ◽  
Burn Out

The increasing amount of volatile renewable energy sources drives the necessity of flexible conventional power plants to compensate for fluctuations of the power supply. Gas turbines in a combined cycle power plant (CCPP) adjust the power output quickly but a sudden increase of CO and UHC emissions limit their turn-down ratio. To extend the turn-down ratio, part of the fuel can be processed to syngas, which exerts a higher reactivity. An autothermal on-board syngas generator in combination with two different burner concepts for natural gas and syngas mixtures are presented in this study. A mixture of natural gas, water vapor and air reacts catalytically in an autothermal reactor test rig to form syngas. At atmospheric pressure, the fuel processor generates syngas with a hydrogen content of ∼30 vol% and a temperature of 800 K within a residence time of 200 ms. One concept for the combustion of natural gas and syngas mixtures comprises a generic swirl stage with a central lance injector for the syngas. The second concept includes a central swirl stage with an outer ring of jets. The combustion is analyzed for both concepts by OH*-chemiluminescence, lean blow out (LBO) limit and gaseous emissions. The central lance concept with syngas injection exhibits an LBO adiabatic flame temperature that is 150 K lower than in premixed natural gas operation. For the second concept an extension of almost 200 K with low CO emission levels can be reached. This study shows that autothermal on-board syngas generation is feasible and efficient in terms of turn-down ratio extension and CO burn-out.

Low Load Operation Range Extension by Autothermal On-Board Syngas Generation

2017 ◽  
Vol 140 (4) ◽  
Author(s):  
Max H. Baumgärtner ◽  
Thomas Sattelmayer
Keyword(s):  
Gas Turbines ◽  
Power Plants ◽  
Renewable Energy Sources ◽  
Flame Temperature ◽  
Combined Cycle ◽  
Sudden Increase ◽  
Gaseous Emissions ◽  
Fuel Processor ◽  
Burn Out ◽  
Unburned Hydrocarbons

The increasing amount of volatile renewable energy sources drives the necessity of flexible conventional power plants to compensate for fluctuations of the power supply. Gas turbines in a combined cycle power plant (CCPP) adjust the power output quickly but a sudden increase of CO and unburned hydrocarbons emissions limits their turn-down ratio. To extend the turn-down ratio, part of the fuel can be processed to syngas, which exerts a higher reactivity. An autothermal on-board syngas generator in combination with two different burner concepts for natural gas (NG) and syngas mixtures is presented in this study. A mixture of NG, water vapor, and air reacts catalytically in an autothermal reactor test rig to form syngas. At atmospheric pressure, the fuel processor generates syngas with a hydrogen content of −30 vol % and a temperature of 800 K within a residence time of 200 ms. One concept for the combustion of NG and syngas mixtures comprises a generic swirl stage with a central lance injector for the syngas. The second concept includes a central swirl stage with an outer ring of jets. The combustion is analyzed for both concepts by OH*-chemiluminescence, lean blow out (LBO) limit, and gaseous emissions. The central lance concept with syngas injection exhibits an LBO adiabatic flame temperature that is 150 K lower than in premixed NG operation. For the second concept, an extension of almost 200 K with low CO emission levels can be reached. This study shows that autothermal on-board syngas generation is feasible and efficient in terms of turn-down ratio extension and CO burn-out.

Efficiency Analysis of Gas Turbine Combined-Cycle Fed with Synthetic Natural Gas (SNG) and Mixture of Syngas and SNG

2015 ◽  
Vol 656-657 ◽  
pp. 113-118
Author(s):  
Hsiu Mei Chiu ◽  
Po Chuang Chen ◽  
Yau Pin Chyou ◽  
Ting Wang
Keyword(s):  
Natural Gas ◽  
Simulation Model ◽  
Steam Turbine ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Combined Cycle ◽  
System Level ◽  
Minimum Requirement ◽  
Synthetic Natural Gas ◽  
System Level Simulation

The effect of synthetic natural gas (SNG) and mixture of syngas and SNG fed to Natural Gas Combined-Cycle (NGCC) plants is presented in this study via a system-level simulation model. The commercial chemical process simulator, Pro/II®V8.1.1, was used in the study to build the analysis model. The NGCC plant consists of gas turbine (GT), heat recovery steam generator (HRSG) and steam turbine (ST). The study envisages two analyses as the basic and feasibility cases. The former is the benchmark case which is verified by the reference data with the GE 7FB gas turbine. According to vendor’s specification, the typical net plant efficiency of GE 7FB NGCC with two gas turbines to one steam turbine is 57.5% (LHV), and the efficiency is the benchmark in the simulation model built in the study. The latter introduces a feasibility study with actual parameters in Taiwan. The SNG-fed GE 7FB based combined-cycle is evaluated, and the mixture of SNG and syngas is also evaluated to compare the difference of overall performance between the two cases. The maximum ratio of syngas to SNG is 0.14 due to the constraint for keeping the composition of methane at a value of 80 mol%, to meet the minimum requirement of NG in Taiwan. The results show that the efficiency in either case of SNG or mixture of SNG and syngas is slightly lower than the counterpart in the benchmark one. Because the price of natural gas is much higher than that of coal, it results in higher idle capacity of NGCC. The advantage of adopting SNG in Taiwan is that it could increase the capacity factor of combined-cycles in Taiwan. The study shows a possible way to use coal and reduce the CO2emission, since coal provides nearly half of the electricity generation in Taiwan in recent years.

Sequential Combustion in Gas Turbines: The Key Technology for Burning High Hydrogen Contents With Low Emissions

2019 ◽  
Author(s):  
Mirko R. Bothien ◽  
Andrea Ciani ◽  
John P. Wood ◽  
Gerhard Fruechtel
Keyword(s):  
High Pressure ◽  
Natural Gas ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Tuning Parameter ◽  
High Hydrogen ◽  
Stable Combustion ◽  
Second Stage ◽  
In Series ◽  
Exit Temperature

Abstract Excess energy generation from renewables can be conveniently stored as hydrogen for later use as a gas turbine fuel. Also, the strategy to sequestrate CO2 from natural gas will require gas turbines to run with hydrogen-based fuels. In such scenarios, high temperature low emission combustion of hydrogen is a key requirement for the future gas turbine market. Ansaldo Energia’s gas turbines featuring sequential combustion have an intrinsic advantage when it comes to fuel flexibility and in particular hydrogen-based fuels. The sequential combustion system is composed of two complementary combustion stages in series: one premix stage followed by an auto-ignited second stage overcoming the limits of traditional premix combustion systems through a highly effective extra tuning parameter, i.e. the temperature between the first and the second stage. The standard Constant Pressure Sequential Combustion (CPSC) system as applied in the GT36 engine is tested, at high pressure, demonstrating that a modified operation concept allows stable combustion with no changes in combustor hardware for the whole range of natural gas and hydrogen blends. It is shown that in the range from 0% to 70% (vol.) hydrogen, stable combustion is achieved at full nominal exit temperature, i.e. without any derating and thus clearly outperforming other available conventional premixed combustors. Operation between 70% and 100% is possible as well and only requires a mild reduction of the combustor exit temperature. By proving the transferability of the single-can high pressure results to the engine, this paper demonstrates the practicality of operating the Ansaldo Energia GT36 H-Class gas turbine on fuels containing unprecedented concentrations of hydrogen while maintaining excellent performance and low emissions both in terms of NOx and CO2.

Performance and Cost Analysis of Advanced Gas Turbine Cycles With Precombustion CO2 Capture

2008 ◽  
Vol 131 (2) ◽  
Author(s):  
Stéphanie Hoffmann ◽  
Michael Bartlett ◽  
Matthias Finkenrath ◽  
Andrei Evulet ◽  
Tord Peter Ursin
Keyword(s):  
High Pressure ◽  
Power Plant ◽  
Natural Gas ◽  
Gas Turbine ◽  
Co2 Capture ◽  
Gas Turbines ◽  
High Efficiency ◽  
Combined Cycle ◽  
Co2 Separation ◽  
The Cost

This paper presents the results of an evaluation of advanced combined cycle gas turbine plants with precombustion capture of CO2 from natural gas. In particular, the designs are carried out with the objectives of high efficiency, low capital cost, and low emissions of carbon dioxide to the atmosphere. The novel cycles introduced in this paper are comprised of a high-pressure syngas generation island, in which an air-blown partial oxidation reformer is used to generate syngas from natural gas, and a power island, in which a CO2-lean syngas is burnt in a large frame machine. In order to reduce the efficiency penalty of natural gas reforming, a significant effort is spent evaluating and optimizing alternatives to recover the heat released during the process. CO2 is removed from the shifted syngas using either CO2 absorbing solvents or a CO2 membrane. CO2 separation membranes, in particular, have the potential for considerable cost or energy savings compared with conventional solvent-based separation and benefit from the high-pressure level of the syngas generation island. A feasibility analysis and a cycle performance evaluation are carried out for large frame gas turbines such as the 9FB. Both short-term and long-term solutions have been investigated. An analysis of the cost of CO2 avoided is presented, including an evaluation of the cost of modifying the combined cycle due to CO2 separation. The paper describes a power plant reaching the performance targets of 50% net cycle efficiency and 80% CO2 capture, as well as the cost target of 30$ per ton of CO2 avoided (2006 Q1 basis). This paper indicates a development path to this power plant that minimizes technical risks by incremental implementation of new technology.

Aeroderivative Combined Heat and Power Fundementals and Applications

2012 ◽  
Author(s):  
James DiCampli
Keyword(s):  
Natural Gas ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Energy System ◽  
Combined Heat And Power ◽  
Combined Cycle ◽  
Draft Guidance ◽  
Distributed Energy ◽  
Improve Energy Efficiency ◽  
Exhaust Heat

Combined heat and power (CHP), is an application that utilizes the exhaust heat generated from a gas turbine and converts it into a useful energy source for heating & cooling, or additional electric generation in combined cycle configurations. Compared to simple-cycle plants with no heat recovery, CHP plants emit fewer greenhouse gasses and other emissions, while generating significantly more useful energy per unit of fuel consumed. Clean plants are easier to permit, build and operate. Because of these advantages, Aeroderivative gas turbines will be a major part of global CHP growth, particularly in China. In order to improve energy efficiency and reduce CO2 emissions, China is working to build ∼1000 new plants of Natural Gas Distributed Energy System (NG-DES) in the next five years. These plants will replace conventional coal-fired plants with combined cooling, heating and power (CCHP) systems. China power segments require an extensive steam supply for cooling, heating and industrial process steam demands, as well as higher peak loads due to high population densities and manufacturing growth rates. GE Energy Aero recently entered the CCHP segment in China, and supported the promotion of codes and standards for NG-DES policy, and is developing optimized CCHP gas turbine packages to meet requirements. This paper reviews those policies and requirements, and presents technical case studies on CCHP applications. Appendix B highlights China’s draft “Guidance Opinions on Developing Natural-Gas Distributed Energy.”

scholarly journals Prediction of Auto-Ignition Temperatures and Delays for Gas Turbine Applications

2015 ◽  
Vol 138 (2) ◽  
Author(s):  
Roda Bounaceur ◽  
Pierre-Alexandre Glaude ◽  
Baptiste Sirjean ◽  
René Fournet ◽  
Pierre Montagne ◽  
...  
Keyword(s):  
High Temperature ◽  
Natural Gas ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Equivalence Ratio ◽  
Process Conditions ◽  
Piping System ◽  
Gaseous Fuels ◽  
Auto Ignition ◽  
Wide Range

Gas turbines burn a large variety of gaseous fuels under elevated pressure and temperature conditions. During transient operations, variable gas/air mixtures are involved in the gas piping system. In order to predict the risk of auto-ignition events and ensure a safe operation of gas turbines, it is of the essence to know the lowest temperature at which spontaneous ignition of fuels may happen. Experimental auto-ignition data of hydrocarbon–air mixtures at elevated pressures are scarce and often not applicable in specific industrial conditions. Auto-ignition temperature (AIT) data correspond to temperature ranges in which fuels display an incipient reactivity, with timescales amounting in seconds or even in minutes instead of milliseconds in flames. In these conditions, the critical reactions are most often different from the ones governing the reactivity in a flame or in high temperature ignition. Some of the critical paths for AIT are similar to those encountered in slow oxidation. Therefore, the main available kinetic models that have been developed for fast combustion are unfortunately unable to represent properly these low temperature processes. A numerical approach addressing the influence of process conditions on the minimum AIT of different fuel/air mixtures has been developed. Several chemical models available in the literature have been tested, in order to identify the most robust ones. Based on previous works of our group, a model has been developed, which offers a fair reconciliation between experimental and calculated AIT data through a wide range of fuel compositions. This model has been validated against experimental auto-ignition delay times corresponding to high temperature in order to ensure its relevance not only for AIT aspects but also for the reactivity of gaseous fuels over the wide range of gas turbine operation conditions. In addition, the AITs of methane, of pure light alkanes, and of various blends representative of several natural gas and process-derived fuels were extensively covered. In particular, among alternative gas turbine fuels, hydrogen-rich gases are called to play an increasing part in the future so that their ignition characteristics have been addressed with particular care. Natural gas enriched with hydrogen, and different syngas fuels have been studied. AIT values have been evaluated in function of the equivalence ratio and pressure. All the results obtained have been fitted by means of a practical mathematical expression. The overall study leads to a simple correlation of AIT versus equivalence ratio/pressure.

scholarly journals Gas Turbines and Natural Gas Synergism

2013 ◽  
Vol 135 (02) ◽  
pp. 30-35
Author(s):  
Lee S. Langston
Keyword(s):  
Natural Gas ◽  
Electric Power ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Power Plants ◽  
Electrical Energy ◽  
Energy Markets ◽  
Combined Cycle ◽  
Energy Information Administration ◽  
Gas Fueled

This article presents a study on new electric power gas turbines and the advent of shale natural gas, which now are upending electrical energy markets. Energy Information Administration (EIA) results show that total electrical production cost for a conventional coal plant would be 9.8 cents/kWh, while a conventional natural gas fueled gas turbine combined cycle plant would be a much lower at 6.6 cents/kWh. Furthermore, EIA estimates that 70% of new US power plants will be fueled by natural gas. Gas turbines are the prime movers for the modern combined cycle power plant. On the natural gas side of the recently upended electrical energy markets, new shale gas production and the continued development of worldwide liquefied natural gas (LNG) facilities provide the other element of synergism. The US natural gas prices are now low enough to compete directly with coal. The study concludes that the natural gas fueled gas turbine will continue to be a growing part of the world’s electric power generation.

scholarly journals A boil-off gas utilization for improved performance of heavy duty gas turbines in combined cycle

2018 ◽  
Vol 233 (1) ◽  
pp. 96-110 ◽  
Author(s):  
Stefano Mazzoni ◽  
Srithar Rajoo ◽  
Alessandro Romagnoli
Keyword(s):  
Heat Transfer ◽  
Natural Gas ◽  
Ambient Temperature ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Liquefied Natural Gas ◽  
Combined Cycle ◽  
Cooling Power ◽  
Heavy Duty ◽  
Cold Energy

The storage of the natural gas under liquid phase is widely adopted and one of the intrinsic phenomena occurring in liquefied natural gas is the so-called boil-off gas; this consists of the regasification of the natural gas due to the ambient temperature and loss of adiabacity in the storage tank. As the boil-off occurs, the so-called cold energy is released to the surrounding environment; such a cold energy could potentially be recovered for several end-uses such as cooling power generation, air separation, air conditioning, dry-ice manufacturing and conditioning of inlet air at the compressor of gas turbine engines. This paper deals with the benefit corresponding to the cooling down of the inlet air temperature to the compressor, by means of internal heat transfer recovery from the liquefied natural gas boil-off gas cold energy availability. The lower the compressor inlet temperature, the higher the gas turbine performance (power and efficiency); the exploitation of the liquefied natural gas boil-off gas cold energy also corresponds to a higher amount of air flow rate entering the cycle which plays in favour of the bottoming heat recovery steam generator and the related steam cycle. Benefit of this solution, in terms of yearly work and gain increase have been established by means of ad hoc developed component models representing heat transfer device (air/boil-off gas) and heavy duty 300 MW gas turbine. For a given ambient temperature variability over a year, the results of the analysis have proven that the increase of electricity production and efficiency due to the boil-off gas cold energy recovery has finally yield a revenue increase of 600,000€/year.

A Comparative Analysis of Single Nozzle and Multiple Nozzles Arrangements for Syngas Combustion in Heavy Duty Gas Turbine

2016 ◽  
Vol 139 (2) ◽  
Author(s):  
Shi Liu ◽  
Hong Yin ◽  
Yan Xiong ◽  
Xiaoqing Xiao
Keyword(s):  
Natural Gas ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Combined Cycle ◽  
Heavy Duty ◽  
Gas Turbine Combustor ◽  
Integrated Gasification Combined Cycle ◽  
Wide Range ◽  
Heavy Duty Gas Turbine ◽  
Integrated Gasification

Heavy duty gas turbines are the core components in the integrated gasification combined cycle (IGCC) system. Different from the conventional fuel for gas turbine such as natural gas and light diesel, the combustible component acquired from the IGCC system is hydrogen-rich syngas fuel. It is important to modify the original gas turbine combustor or redesign a new combustor for syngas application since the fuel properties are featured with the wide range hydrogen and carbon monoxide mixture. First, one heavy duty gas turbine combustor which adopts natural gas and light diesel was selected as the original type. The redesign work mainly focused on the combustor head and nozzle arrangements. This paper investigated two feasible combustor arrangements for the syngas utilization including single nozzle and multiple nozzles. Numerical simulations are conducted to compare the flow field, temperature field, composition distributions, and overall performance of the two schemes. The obtained results show that the flow structure of the multiple nozzles scheme is better and the temperature distribution inside the combustor is more uniform, and the total pressure recovery is higher than the single nozzle scheme. Through the full scale test rig verification, the combustor redesign with multiple nozzles scheme is acceptable under middle and high pressure combustion test conditions. Besides, the numerical computations generally match with the experimental results.

Sign in / Sign up

Export Citation Format

Share Document