Influence of Elastic Modulus of Matrix on Conductivity of VGCF Dispersed in Plastic Matrix

2021 ◽  
Vol 1016 ◽  
pp. 243-249
Author(s):  
Toi Aoki ◽  
Noboru Nakayama ◽  
Masaomi Horita ◽  
Hiroaki Fukui

Pressure-sensitive conductive material is used for various pressure sensors consists of a polymer nanocomposite with carbon nanotubes (VGCF). And the resistance in it were changed by adding applied load. Recently, carbon nanotubes (VGCF) has drawn attention as a function filler that imparts various functions to a resin, including electrical properties. In polycarbonate (PC) composite with VGCF, the resistance decreases with increase in applied load. And increase of the addition amount of VGCF was enhanced the mechanical properties and electronic properties. In addition, this conclusion suggested that strain of PC/VGCF caused reducing the resistance. Therefore, changing matrix is predictably effective on electrical properties in pressure-conductive materials. In the present study, we used various matrix had different elastic modulus. The addition amount of VGCF was 12.5% volume rate. We made silicone/VGCF and polyethylene (PE)/VGCF and polycarbonate (PC)/VGCF by twin screw extruder and injection moldings. To clarify the influence of elastic modulus of matrix on conductivity of VGCF dispersed plastic matrix composites. The experimental results showed that conductive property of pressure-sensitive conductive materials is related to elastic modulus of them.

Proceedings ◽  
2021 ◽  
Vol 68 (1) ◽  
pp. 2
Author(s):  
Arash M. Shahidi ◽  
Theodore Hughes-Riley ◽  
Carlos Oliveira ◽  
Tilak Dias

Knitted electrodes are a key component to many electronic textiles including sensing devices, such as pressure sensors and heart rate monitors; therefore, it is essential to assess the electrical performance of these knitted electrodes under different mechanical loads to understand their performance during use. The electrical properties of the electrodes could change while deforming, due to an applied load, which could occur in the uniaxial direction (while stretched) or multiaxial direction (while compressed). The properties and performance of the electrodes could also change over time when rubbed against another surface due to the frictional force and generated heat. This work investigates the behavior of a knitted electrode under different loading conditions and after multiple abrasion cycles.


2006 ◽  
Vol 963 ◽  
Author(s):  
Guan Wang ◽  
Zhongkui Tan ◽  
Xueqing Liu ◽  
Vladimir Samuilov ◽  
Michael Dudley

ABSTRACTAn oxidation method has been applied to functionalize multiwalled carbon nanotubes with carboxylic acid (-COOH) group. Functionalized carbon nanotubes (f-MWNT) were used for the fabrication of conducting nanocomposite fibers by electrospinning, in comparison with the composite nanofibers made of un-functionalized carbon nanotubes (u-MWNT). Our results showed that the addition of f-MWNTs into polymer solution could increase the compatibility of MWNTs with the polymer matrix, and thus result in composite nanofibers with uniform diameters. Alignment of the composite nanofibers was achieved by using a rotating drum as the collector. F-MWNTs were found to align parallel to the axis direction of the nanofibers. Temperature-dependent DC electrical properties of a single composite fiber were investigated by a two-probe method. It was shown that the conductivity of the material could be significantly improved above a percolation threshold. The conductivity could be of ten orders of magnitude higher than the pure PVAc.


2013 ◽  
Vol 2013 ◽  
pp. 1-10 ◽  
Author(s):  
Roham Rafiee ◽  
Timon Rabczuk ◽  
Reza Pourazizi ◽  
Junhua Zhao ◽  
Yancheng Zhang

The interaction between the carbon nanotubes (CNT) and the polymer is a key factor for determining the mechanical, thermal, and electrical properties of the CNT/polymer nanocomposite. However, it is difficult to measure experimentally the interfacial bonding properties between the CNT and the surrounding polymer. Therefore, computational modeling is used to predict the interaction properties. Different scale models, from atomistic to continuum, are critically reviewed addressing the advantages, the disadvantages, and the future challenges. Various methods of improvement for measuring the interaction properties are described. Finally, it is concluded that the semicontinuum modeling may be the best candidate for modeling the interaction between the CNT and the polymer.


2014 ◽  
Vol 605 ◽  
pp. 335-339 ◽  
Author(s):  
Kie Yong Cho ◽  
A Ra Cho ◽  
Yun Jae Lee ◽  
Chong Min Koo ◽  
Soon Man Hong ◽  
...  

Carbon nanotubes (CNTs) coated by compatibilizer (P3HT-PMMA) imparted sta-ble dispersion in organic solvents and polymer matrix (P(VDF-TrFE)). The compatibility be-tween CNTs with P3HT-PMMA was con rmed by measuring Raman spectroscopy. CoatedCNTs were then blended with P(VDF-TrFE) (70:30 mol%) to obtain polymer nanocompositesby solution- casting process. Polymer nanocomposites showed enhanced electrical characteris-tics, as nanocomposites near the threshold of the transition between P(VDF-TrFE) insulatorand CNT conductor revealed great improvement of electrical conductivity up to 10-6 S/cmat 1 KHz. Electromechanical properties of the polymer nanocomposite were examined as afunction of electric eld.


Polymers ◽  
2021 ◽  
Vol 13 (21) ◽  
pp. 3655
Author(s):  
Rubén Caro-Briones ◽  
Blanca Estela García-Pérez ◽  
Eduardo San Martín-Martínez ◽  
Héctor Báez-Medina ◽  
Irlanda Grisel Cruz-Reyes ◽  
...  

In this work, the influence of carbon nanotubes (CNTs) content on the mechanical and electrical properties of four series of polymeric matrix were made and their cytotoxicity on cells was evaluated to consider their use as a possible artificial muscle. For that, polymer composite yarns were electrospun using polymeric solutions at 10 wt.%. of poly(styrene-co-acrylonitrile) P(S:AN) and P(S:AN-acrylic acid) P(S:AN-AA) at several monomeric concentrations, namely 0:100, 20:80, 40:60, 50:50 (wt.%:wt.%), and 1 wt.% of AA. Carbon nanotubes (CNTs) were added to the polymeric solutions at two concentrations, 0.5 and 1.0 wt.%. PMCs yarns were collected using a blade collector. Mechanical and electrical properties of polymeric yarns indicated a dependence of CNTs content into yarns. Three areas could be found in fibers: CNTs bundles zones, distributed and aligned CNTs zones, and polymer-only zones. PMCs yarns with 0.5 wt.% CNTs concentration were found with a homogenous nanotube dispersion and axial alignment in polymeric yarn, ensuring load transfer on the polymeric matrix to CNTs, increasing the elastic modulus up to 27 MPa, and a maximum electrical current of 1.8 mA due to a good polymer–nanotube interaction.


2018 ◽  
Vol 2018 ◽  
pp. 1-12 ◽  
Author(s):  
Asar Ali ◽  
Adam Khan ◽  
Kh. S. Karimov ◽  
Amjad Ali ◽  
Adnan Daud Khan

Carbon nanotubes (CNTs) and graphene have attracted a great deal of interest due to their outstanding mechanical, optical, electrical, and structural properties. Most of the scientists and researchers have investigated the optical and electrical properties of these materials. However, due to unique electromechanical properties of these materials, it is required to explore the piezoresistive properties of bulk nanostructured CNTs, graphene, and CNT-graphene composites. We investigated and compared the sensitivities and piezoresistive properties of sandwich-type pure CNT, pure graphene, and CNT-graphene composite pressure sensors. For all the samples, increase in pressure from 0 to 0.183 kNm−2 results in a decrease in the impedance and direct current (DC) resistance. Sensitivity and percentage decrease in resistance and impedance of CNT-graphene composite were lower than pure CNT while being higher than pure graphene based sample. Moreover, under the same external applied pressure, the sensitivity and percentage decrease in impedance for pure CNT, pure graphene, and CNT-graphene composite were smaller than the corresponding sensitivity and percentage decrease in resistance. The achieved experimental results of the composite sample were compared with simulated results which exhibit reasonable agreement with each other. The deviations of simulated resistance-pressure and impedance-pressure curves from experimental graphs were 0.029% and 0.105%, respectively.


2008 ◽  
Vol 59 (10) ◽  
pp. 1169-1171 ◽  
Author(s):  
Zoltan Borsos ◽  
Viorel-Puiu Paun ◽  
Irinel Casian Botez ◽  
Cristina-Maria Stoica ◽  
Petrica Vizureanu ◽  
...  

In this paper, the explicit connection between the high structural symmetry of the carbon nanotubes and the electrical properties is studied. An interesting path effect on the transport properties will be proved. For a bidimensional lattice, the conductivity sx depends on the structural form, which determines the shape of electron path, respectively it is direct proportional to the fractal dimension of this path.


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