Determination of the lower boundaries of the natural gas hydrates stability zone in the subpermafrost horizons of the Yakut arch of the Vilyui syneclise, saturated with bicarbonate-sodium type waters

This paper considers the possibility of the underground gas storage facilities creating in a hydrate state on the north-western slope of the Yakut arch of the Vilyui syneclise. For this, the boundaries of the hydrate stability zone were determined for 6 promising areas of the considered geological structure. Equilibrium conditions of the natural gas hydrates formation in the model porous media containing bicarbonate-sodium type water (mineralization 20 g/l), characteristic for the subpermafrost horizons of the Yakut arch, have been studied by the method of differential thermal analysis. On the basis of the obtained results, the boundaries of the natural gas hydrates stability zone were determined. It was shown that the upper boundaries of the hydrate stability zone are located in the thickness of permafrost rocks. It was found that the lower boundaries of the natural gas hydrates stability zone in moist unsalted porous medium lie in the range from 930 to 1120 m. When the samples are saturated with mineralized water, the boundaries are located 80-360 m higher. The obtained experimental results allow us to conclude that in subpermafrost aquifers of the Yakut arch has favorable conditions for the formation of natural gas hydrates. Keywords: natural gas hydrates; aquifers; underground gas storage; hydrate stability zone; geothermal gradient; equilibrium conditions of the hydrate formation; bicarbonate-sodium type water.

Gas hydrate stability zone in Muri coalfield, Qinghai Province, China

ABSTRACT The gas hydrate stability zone (GHSZ) is the essential condition for gas hydrate accumulation, which is controlled by three main factors: gas component, geothermal gradient and permafrost thickness. Based on the gas component of hydrate samples from drilling in Muri coalfield, the gas hydrate phase equilibrium curve was calculated using Sloan's natural gas hydrate phase equilibrium procedure (CSMHYD) program. Through temperature data processing of coalfield boreholes, some important data such as thickness of permafrost and geothermal gradient were obtained. The GHSZ parameters of a single borehole were calculated by programming based on the above basic data. The average thickness of GHSZ of 85 boreholes in Muri coalfield amounted to approximately 1000 m, indicating very broad space for gas hydrate occurrence. The isogram of GHSZ bottom depth drawn from single borehole data in Muri coalfield demonstrated the regional distribution characteristics of GHSZ, and identified three favourable areas of gas hydrate occurrence where the bottom of GHSZ had a burial depth >1500 m – namely, the southern part of Juhugeng Mining Area, the middle part of Duosuogongma Mining Area and the eastern part of Xuehuoli Mining Area.

Zoning Control Technology of Gob-Side Roadway Driving with Small Coal Pillar Facing Mining in a Special Isolated Island Working Face: A Case Study

The gob-side roadway in an isolated island working face is a typical representative of a strong mining roadway, which seriously restricts the efficient and safe production of underground coal mines. With the engineering background of the main transportation roadway 1513 (MTR 1513) of the Xinyi Coal Mine, this paper introduces the engineering case of gob-side roadway driving with small coal-pillar facing mining in an isolated island working face under the alternate mining of wide and narrow working faces. Through comprehensive research methods, we studied zoning disturbance deformation characteristics and stress evolution law of gob-side roadway driving under face mining. Based on the characteristics of zoning disturbance, MTR 1513 is divided into three zones, which are the heading face mining zone, the mining influenced zone, and the mining stability zone. A collaborative control technology using pressure relief and anchoring is proposed, and the differentiated control method is formed for the three zones. For the heading face mining zone, the control method of anchoring first and then pressure relief is adopted; for the mining influenced zone, the control idea of synchronous coordination of pressure relief and anchorage is adopted; for the mining stability zone, the control method of anchoring without pressure relief is adopted. Engineering practices show that the disturbance influence distance of working face 1511 on MTR 1513 changes from 110 m advanced to 175 m delay. At this time, the surrounding rock deformation is effectively controlled, which verified the rationality of the division and the feasibility of three zoning control technology. The research results can provide reference for gob-side roadway driving with small coal pillar facing mining in a special isolated island working face.

A Geophysical Review of the Seabed Methane Seepage Features and Their Relationship with Gas Hydrate Systems

Seabed methane seepage has gained attention from all over the world in recent years as an important source of greenhouse gas emission, and gas hydrates are also regarded as a key factor affecting climate change or even global warming due to their shallow burial and poor stability. However, the relationship between seabed methane seepage and gas hydrate systems is not clear although they often coexist in continental margins. It is of significance to clarify their relationship and better understand the contribution of gas hydrate systems or the deeper hydrocarbon reservoirs for methane flux leaking to the seawater or even the atmosphere by natural seepages at the seabed. In this paper, a geophysical examination of the global seabed methane seepage events has been conducted, and nearby gas hydrate stability zone and relevant fluid migration pathways have been interpreted or modelled using seismic data, multibeam data, or underwater photos. Results show that seabed methane seepage sites are often manifested as methane flares, pockmarks, deep-water corals, authigenic carbonates, and gas hydrate pingoes at the seabed, most of which are closely related to vertical fluid migration structures like faults, gas chimneys, mud volcanoes, and unconformity surfaces or are located in the landward limit of gas hydrate stability zone (LLGHSZ) where hydrate dissociation may have released a great volume of methane. Based on a comprehensive analysis of these features, three major types of seabed methane seepage are classified according to their spatial relationship with the location of LLGHSZ, deeper than the LLGHSZ (A), around the LLGHSZ (B), and shallower than LLGHSZ (C). These three seabed methane seepage types can be further divided into five subtypes considering whether the gas source of seabed methane seepage is from the gas hydrate systems or not. We propose subtype B2 represents the most important seabed methane seepage type due to the high density of seepage sites and large volume of released methane from massive focused vigorous methane seepage sites around the LLGHSZ. Based on the classification result of this research, more measures should be taken for subtype B2 seabed methane seepage to predict or even prevent ocean warming or climate change.

Forecast of Distribution and Thickness of Gas Hydrate Stability Zone at the Bottom of the Caspian Sea

The Caspian Sea is a region of active hydrocarbon production, where apart from conventional accumulations, gas hydrates (GH) are known to exist. GH are a potential future source of energy, however, currently they pose danger for development of conventional fields. The goal of this research was to determine the area of GH distribution and thickness of their stability zone in the Caspian Sea using numerical modeling and to define how certain parameters affect the calculated thickness. As a result of the research, cartographic schemes were created for the South and Middle Caspian, where GH were predicted. For the South Caspian, conditions for methane hydrates formation exist at depths of more than 419–454 m, and for the Middle Caspian, more than 416–453 m. The maximal thicknesses of methane hydrates stability zones for the South Caspian can reach 900–956 m, and for the Middle Caspian, 226–676 m. Variations of parameters of seafloor depth, geothermal gradient and gas composition can significantly change the resulting thickness of GH stability zone.

The mutual repression between Pax2 and Snail factors regulates the epithelial/mesenchymal state during intermediate mesoderm differentiation

The pronephros is the first renal structure in the embryo, arising after mesenchymal to epithelial transition (MET) of the intermediate mesoderm, where Pax2 induces epithelialization of the mesenchyme. Here we show that, in the early embryo, Snail1 directly represses Pax2 transcription maintaining the intermediate mesoderm in an undifferentiated state. Reciprocally, Pax2 directly represses Snail1 expression to induce MET upon receiving differentiation signals. We also show that BMP7 acts as one such signal by downregulating Snail1 and upregulating Pax2 expression. This, together with the Snail1/Pax2 reciprocal repression, establish a regulatory loop in a defined region along the anteroposterior axis, the bi-stability domain within the transition zone, where differentiation of the neural tube and the somites is known to occur. Thus, we show that the antagonism between Snail1 and Pax2 determines the epithelial/mesenchymal state during the differentiation of the intermediate mesoderm and propose that the bi-stability zone extends to the intermediate mesoderm, synchronizing the differentiation of tissues aligned along the mediolateral embryonic axis.

Climatically driven instability of marine methane hydrate along a canyon-incised continental margin

Establishing how past climate change affected the stability of marine methane hydrate is important for our understanding of the impact of a future warmer world. As oceans shallow toward continental margins, the base of the hydrate stability zone also shallows, and this delineates the feather edge of marine methane hydrate. It is in these rarely documented settings that the base of the hydrate stability zone intersects the seabed and hydrate can crop out where it is close to being unstable and most susceptible to dissociation due to ocean warming. We show evidence for a seismically defined outcrop zone intersecting canyons on a canyon-incised margin offshore of Mauritania. We propose that climatic, and hence ocean, warming since the Last Glacial Maximum as well as lateral canyon migration, cutting, and filling caused multiple shifts of the hydrate stability field, and therefore hydrate instability and likely methane release into the ocean. This is particularly significant because the outcrop zone is longer on canyon-incised margins than on less bathymetrically complex submarine slopes. We propose considerably more hydrate will dissociate in these settings during future ocean warming, releasing methane into the world’s oceans.

Time Constraints on Seepage Through Fractured Regions on the Vestnesa Ridge off the W-Svalbard Coast

<p>Evidences of subsurface fluid flow-driven fractures (from seismic interpretation) are quite common at Vestnesa Ridge (around 79ºN in the Arctic Ocean), W-Svalbard margin. Ultimately, the fractured systems have led to the formation of pockmarks on the seafloor. At present day, the eastern segment of the ridge has active pockmarks with continuous methane seep observations in sonar data. The pockmarks in the western segment are considered inactive or to seep at a rate that is harder to identify. The ridge is at ~1200m water depth with the base of the gas hydrate stability zone (GHSZ) at ~200m below the seafloor. Considerable free gas zone is present below the hydrates. Besides the obvious concern of amount and rates of historic methane seeping into the ocean biosphere and its associated effects, significant gaps exist in the ability to model the processes of flow of methane through this faulted and fractured region. Our aim is to highlight the interactions between physical flow, geomechanics and geological control processes that govern the rates and timing of methane seepage.</p><p>For this purpose, we performed numerical fluid flow simulations. We integrate fundamental mass and component conservation equations with a phase equilibrium approach accounting for hydrate phase boundary effects to simulate the transport of gas from the base of the GHSZ through rock matrix and interconnected fractures until the seafloor. The relation between effective stress and fluid pressure is considered and fractures are activated once the effective stress exceeds the tensile limit. We use field data (seismic, oedometer tests on calypso cores, pore fluid pressure and temperature) to constrain the range of validity of various flow and geomechanical parameters in the simulation (such as vertical stress, porosity, permeability, saturations).</p><p>Preliminary results indicate fluid overpressure greater than 1.5 MPa is required to initiate fractures at the base of the gas hydrate stability zone for the investigated system. Focused fluid flow occurs through the narrow fracture networks and the gas reaches the seafloor within 1 day. The surrounding regions near the fracture network exhibit slower seepage towards the seafloor, but over a wider area. Advective flux through the less fractured surrounding regions, reaches the seafloor within 15 years and a diffusive flux reaches within 1200 years. These times are controlled by the permeability of the sediments and are retarded further due to considerable hydrate/carbonate formation during vertical migration. Next course of action includes constraining the methane availability at the base of the GHSZ and estimating its impact on seepage behavior.</p>