Use of glass waste in the production of metakaolin-based geopolymer submitted to room temperature and thermal curing

Metakaolinis the principal raw material utilized in the synthesis of geopolymers, although its ratio of silica and alumina contents is not ideal. Normally, the SiO2 content is adjusted with the use of silicates present in the activating solution. An eco-efficient alternative would be the use of glass waste as an additional source of silica.This work evaluates the efficiency of the alkaline activation of metakaolin, using potassium hydroxide and silicate, with and without the substitution of 12.5% of metakaolin by microparticles of glass. The efficiency of the alkaline activation was evaluated by X ray diffractometry, spectroscopy in the infrared region with the Fourier transform, nuclear magnetic resonance spectroscopy of 27Al and 29Si, specific mass and compressive strength. The results indicate the occurrence of geopolymerization with and without the use of glass waste. It was observed that the substitution of 12.5% favors the mechanical performance of the compounds at 28 days, with increases by 37% and 47% in the mechanical strength of the material with thermal curing and ambient temperature curing, respectively.

Development of Novel Transparent Radiation Shielding Glasses by BaO Doping in Waste Soda Lime Silica (SLS) Glass

In the current study, BaO was doped in Bi2O3-ZnO-B2O3-SLS glass to develop lead-free radiation shielding glasses and to solve the dark brown of bismuth glass. The melt-quenching method was utilized to fabricate (x) BaO (1 − x)[0.3 ZnO 0.2 Bi2O3 0.2 B2O3 0.3 SLS] (where x are 0.01, 0.02, 0.03, 0.04, and 0.05 mol) at 1200 °C. Soda lime silica glass waste (SLS), which is mostly composed of 74.1% SiO2, was used to obtain SiO2. The mass attenuation coefficient (μm) was investigated utilizing X-ray fluorescence (XRF) at 16.61, 17.74, 21.17, and 25.27 keV and narrow beam geometry at 59.54, 662, and 1333 keV. Moreover, the other parameters related to gamma ray shielding properties such as half-value layer (HVL), mean free path (MFP), and effective atomic number (Zeff) were computed depending on μm values. The results indicated that HVL and MFP decreased, whereas μm increased with an increase in BaO concentration. According to these results, it can be concluded that BaO doped in Bi2O3-ZnO-B2O3-SLS glass is a nontoxic, transparent to visible light, and a good shielding material against radiation.

Behavior of sustainable Reactive Powder Concrete by Using Glass Powder as a Replacement of Cement

Every year, the world produces one million tons of glass garbage. Once the glass has been broken down, it is dumped in landfills, where it will remain inert for hundreds of years. glass is mainly made of silica. For long-term infrastructure development, ground glass as a partial cement substitute may be a major advance (environmentally friendly, energy-saving, and economic). Secondary calcium silicate hydrate is expected to be produced when glass waste is crushed into microscopic particles and then reacts with cement hydrate through pozzolanic interactions (C-S-H). There were experiments done on concrete utilizing (0-35 per cent) ground glass and superplasticizer, silica fume, fine sand and fibres, with the water to binder (cement + glass) ratio maintained constant for all degrees of replacement on compressive strength, modulus of elasticity and tensile strength. Steel is a fixed quantity that applies to all conceivable configurations. Concrete cube samples were made and tested for strength (28 days curing). It was discovered that the recycled glass concrete outperformed control samples in compressive strength tests. Compressive strength, tensile strength, and modulus of elasticity are all greatest in the 25 per cent glass powder. It was decided that using recycled glass trash in place of 25 per cent of the cement was a good idea because of the economic and environmental advantages.

RECYCLE GLASS WASTE AS A REPLACEMENT OF FINE AGGREGATE IN CONCRETE MIX STANDARD COMPARISON

Recycling is one way that is used to minimize the amount of waste that exists. Recycling is also a process to reduce the use of new raw materials, reduce energy use, reduce pollution, land degradation and greenhouse gas emissions. Materials that can be recycled consist of waste of glass, plastic, paper, metal, textiles and electronic goods. Glass has characteristics suitable as concrete aggregates, considering that glass is a material that does not absorb water. In addition, glass has high abrasion resistance. Meanwhile, the waste glass flux lowers the temperature to the temperature at which the formers will melt. Stabilizers in glass waste are made of calcium carbonate, which makes the glass waste solid and water-resistant. This glass waste is recycled by mixing it into the concrete mix. The recycling method is done by pounding the glass and putting it into the concrete mix stage. The purpose of mixing the glass waste is expected to increase the compressive strength of concrete. The use of glass waste as a mixed material affects the compressive strength of the concrete. The concrete with the most inferior to highest compressive strength is 4% variation concrete, 2% variation concrete, and traditional concrete. Optimal percentage addition of glass waste impacts on maximum concrete compressive strength is 2% mixture variation which obtained 11,88 Mpa & 11,32 Mpa.

Formulation of Compressed Earth Blocks Stabilized by Glass Waste Activated with NaOH Solution

Due to the increase in demand for building materials and their high prices in most developing countries, many researchers are trying to recycle waste for use as secondary raw materials. The aim of this study is the optimization of a mixture of compressed earth blocks based on two sediments. These sediments were tested through the Vicat test to determine the proportion of each one and the optimal water content. The mixtures were treated by adding 10% of blast furnace slag and different proportions of dissolved glass in a NaOH solution. The results indicated that the mixture of 70% Oran sediments with 30% Sidi Lakhdar sediments treated with 4% glass waste produced a CEB (compressed earth block) with high compressive strength with low porosity. In addition, formulated CEBs have a very good resistance to water immersion.

Granulated Expanded Glass Manufacturing Method Using Electromagnetic Waves

The paper presents experimental results obtained in the process of experimental manufacture in a microwave oven of lightweight granulated glass aggregates. The process was conducted to obtain the highest dimensional class (between 18-23 mm), the almost spherical shape of the aggregates being facilitated by cold processing of raw spherical pellets (between 11-15 mm) containing the powder mixture formed by glass waste, borax. calcium carbonate, aqueous sodium silicate solution and water addition and then rotation of the high electromagnetic wave susceptible ceramic crucible containing raw pellets during the heat treatment at temperatures between 822-835 ºC. In terms of quality, the expanded glass aggregate granules are almost similar to those manufactured in conventional rotary kilns heated by burning fuel, having the following characteristics: bulk density of 0.17 g/cm3, compressive strength of 2.2 MPa, thermal conductivity of 0.047 W/m·K, water absorption of 1 vol. % and pore size between 0.3-0.6 mm. The experimental product has not yet been tested as a raw material in the manufacture of some light weight concretes, but the use of similar granulated glass aggregates manufactured in the world confirms the ability of this aggregate type to produce light weight and energy efficient concretes for building construction.

Granulated Expanded Glass Manufacturing Method Using Electromagnetic Waves

The paper presents experimental results obtained in the process of experimental manufacture in a microwave oven of lightweight granulated glass aggregates. The process was conducted to obtain the highest dimensional class (between 18-23 mm), the almost spherical shape of the aggregates being facilitated by cold processing of raw spherical pellets (between 11-15 mm) containing the powder mixture formed by glass waste, borax. calcium carbonate, aqueous sodium silicate solution and water addition and then rotation of the high electromagnetic wave susceptible ceramic crucible containing raw pellets during the heat treatment at temperatures between 822-835 ºC. In terms of quality, the expanded glass aggregate granules are almost similar to those manufactured in conventional rotary kilns heated by burning fuel, having the following characteristics: bulk density of 0.17 g/cm3, compressive strength of 2.2 MPa, thermal conductivity of 0.047 W/m·K, water absorption of 1 vol. % and pore size between 0.3-0.6 mm. The experimental product has not yet been tested as a raw material in the manufacture of some light weight concretes, but the use of similar granulated glass aggregates manufactured in the world confirms the ability of this aggregate type to produce light weight and energy efficient concretes for building construction.