Effect of Cold Rolling on Cluster(1) Dissolvability during Artificial Aging and Formability during Natural Aging in Al-0.6Mg-1.0Si-0.5Cu Alloy

Natural aging after solution treatment has a negative effect on the precipitation strengthening of Al–Mg–Si alloys since Cluster(1) formed at a room temperature cannot be dissolved or transformed into precipitates during artificial aging at 170 °C. In this study, cold rolling is focused on as an alternative solution to pre-aging, which is a conventional method to prevent Cluster(1) formation. It is known that excess vacancies are necessary for cluster formation. Cold rolling suppresses cluster formation because excess vacancies disappear at dislocations introduced by cold rolling. In addition, it is expected that cold rolling accelerates the precipitation behavior because the diffusion of solute atoms is promoted by introduced lattice defects. The transition of Cluster(1) was evaluated by Micro Vickers hardness tests, tensile tests, electrical conductivity measurements and differential scanning calorimetry analyses. Results showed the negative effect of natural aging was almost suppressed in 10% cold-rolled samples and completely suppressed in 30% cold-rolled samples since Cluster(1) dissolved during artificial aging at 170 °C due to lowering of the temperature of Cluster(1) dissolution by cold rolling. It was found that the precipitation in cold-rolled samples was accelerated since the hardness peak of 10% cold-rolled samples appeared earlier than T6 and pre-aged samples.

Redox Cycling for SOFC Accelerated Degradation

This work aims at development of Accelerated Stress Tests for SOFC via artificial aging of the fuel electrode applying chemical and electrochemical (hydrogen starvation) redox cycling. In principle the degradation processes follows that of calendar aging (Ni coarsening and migration), but in addition it can bring to irreversible damages caused by the development of cracks at the interface anode/electrolyte due to the expansion/shrinkage of the Ni network. The challenge is to introduce conditions which will prevent the formation of cracks which can be done by partial oxidation. The advantage of the proposed methodology is that a mild level of oxidation can be regulated by direct impedance monitoring of the Ni network resistance changes during oxidation/reduction. Once the redox cycling conditions are fixed on bare anode and checked on anode/electrolyte sample for eventual cracks, the procedure can be introduced for AST in full cell configuration. The developed methodology is evaluated by comparative impedance analysis of artificially aged and calendar aged button cells. The results for 20 redox cycles which can be performed for 24 hours are comparable with those obtained for about 1600 hours operation in standard conditions which ensures more than 50 times acceleration.

Influence of the Solution and Artificial Aging Treatments on the Microstructure and Mechanical Properties of Die-Cast Al–Si–Mg Alloys

Heat treatment is widely used to improve the properties of Al–Si–Mg alloys and its outcomes are influenced by the parameters applied during the treatment. This study describes the effect of the solution and artificial aging treatments on the microstructure and mechanical properties of die-cast Al–Si–Mg alloys. The microstructure of the as-cast Al–Si–Mg alloy was mainly composed of α-Al, complex needle-type eutectic Si particles, Mg2Si, and α-AlFeMn. The complex needle-type eutectic Si particles disintegrated into spheroidal morphologies, while the Mg2Si was dissolved due to the solid solution treatment. The maximum yield strength (YS) and ultimate tensile strength (UTS) values were 126.06 and 245.90 MPa at 520 °C after 90 min of solution heat treatment, respectively. Although the YS and UTS values of the Al–Si–Mg alloys reduced due to the solution treatment, the elongation (EL) of the solid solution heat-treated Al–Si–Mg alloys was improved in comparison to that of the as-cast Al–Si–Mg alloy. The maximum YS and UTS of 239.50 and 290.93 MPa were obtained after performing artificial aging at 180 °C for 180 min, respectively. However, the EL of the aging heat-treated alloy was reduced by a minimal value.

The influence of accelerated aging on the physical and chemical properties of a composite material: a systematic overview

Relevance. Today, dental composite materials are very popular among dentists. The composite material is a filler in the form of particles of various sizes immersed in a polymer matrix. Polymer composites are used for direct filling of all groups of teeth and at different depths of the lesion. Composite materials have optimum mechanical, aesthetic and functional properties. They are simple and easy to use, provide long-term restoration service, and also have a wide price range. All these qualities allowed composite materials to firmly gain a foothold in the practice of dentists around the world. In this regard, clinicians and researchers are constantly trying to significantly improve their physical, mechanical, adaptive and aesthetic properties.Aim. Conduct a systematic assessment of the available scientific data on the effect of accelerated aging of the composite on its physicochemical properties.Materials and methods. In the course of a systematic review of the literature, a study was made of publications in electronic databases such as Google Scholar, PubMed, Research gate, Elibrary. The search results are formatted using the Prisma diagram.Results. Dental composites inevitably age over time and under the influence of environmental factors. To predict the long-term service life of composite restorations, scientists and clinicians are studying the aging behavior of the material. To simulate the clinical conditions of the oral cavity, various methods of artificial aging of dental composite materials have been developed.Conclusions. A study of scientific papers published over the past 10 years on the topic of artificial aging of dental composite materials has shown its unambiguous effect on the mechanical and morphological properties of polymers. The use of methods for simulating clinical conditions made it possible to reduce the study time and analyze the changes obtained.

Cyclopentasiloxane (D5) as a Non-Polar Masking Agent for Water-Sensitive Substrates During Polar Solvent Treatment

D5 (decamethylcyclopentasiloxane), a non-polar solvent that evaporates slowly, was tested for its suitability as a temporary masking agent for water-sensitive media on paper objects undergoing aqueous treatment. Three different treatment-related settings were tested on five different paper types, some prepared with water-soluble inks. In 10-min water immersion treatments, D5 proved largely ineffectual in protecting the water-soluble inks. In conjunction with melt-applications of cyclododecane, the addition of D5 enhanced its barrier function only in one case. To test the ability of D5 to prevent tideline formation, the test samples received applications of water, acetone, and a water-ethanol-mixture, creating an interface with freshly D5-impregnated areas. The papers were evaluated visually (VIS, UVA), some after artificial aging. D5 diminished the formation of visible tidelines in the two internally sized papers with low water absorbency in contact with acetone and the ethanol-water mixture, but did not prevent tidelines in contact with water. It also did not protect water-absorbent paper. The results indicate that D5, which is miscible with ethanol and acetone, may disperse tidelines caused by these solvents, but it proved largely insufficient for protecting media during water immersion.

Influence of Preheating Temperature on Changes in Properties in the HAZ during Multipass MIG Welding of Alloy AW 6061 and Possibilities of Their Restoration

Fusion welding of heat-treatable aluminum alloys is generally accompanied by a significant decrease in mechanical properties in the HAZ caused by the dissolution of the hardening phase. The intensity of this decrease in mechanical properties can be reduced by limiting the heat input value. However, this approach is in direct conflict with the principles for welding aluminum and its alloys. Due to the very high thermal conductivity of aluminum alloys, it is necessary to use preheating for thicknesses larger than 5 mm to eliminate non-penetration and cold joints. This paper aims to show the influence of multiple temperature cycles, performed at different preheating temperatures, on changes in the microstructure and mechanical properties. At the same time, the extent to which the original properties of the material can be restored by natural and artificial aging at 160, 175 and 190 °C is also investigated.