Catalytic production of low-carbon footprint sustainable natural gas

Natural gas is one of the foremost basic energy sources on earth. Although biological process appears as promising valorization routes to transfer biomass to sustainable methane, the recalcitrance of lignocellulosic biomass is the major limitation for the production of mixing gas to meet the natural gas composition of pipeline transportation. Here we develop a catalytic-drive approach to directly transfer solid biomass to bio-natural gas which can be suitable for the current infrastructure. A catalyst with Ni2Al3 alloy phase enables nearly complete conversion of various agricultural and forestry residues, the total carbon yield of gas products reaches up to 93% after several hours at relative low-temperature (300 degrees Celsius). And the catalyst shows powerful processing capability for the production of natural gas during thirty cycles. A low-carbon footprint is estimated by a preliminary life cycle assessment, especially for the low hydrogen pressure and non-fossil hydrogen, and technical economic analysis predicts that this process is an economically competitive production process.

A Review on Utilization Routes of the Leather Industry Biomass

The use of biomass to produce bioenergy and biomaterials is considered a sustainable alternative to depleting fossil fuel resources. The world tanneries consume 8–9 MT of skin and hide every year producing 1.4 MT of solid waste. Most of the solid biomass generated from tanneries is disposed of as waste in the environment using either landfilling or thermal incineration. Disposal of this waste into the environment affects the ecosystem, causing bad odor (air pollution) and has an antagonistic impact on the environment. Due to this, European Union legislation bans the landfilling of biomass. This study aims to comprehensively review the possible valorization routes of leather processing industry biomass into high-value biomaterials. Leather biomass (trimmings, shaving, splitting, and buffing dust) mainly contain 30%–35% collagen protein, which is produced by acid or alkali hydrolysis. The biopolymers obtained from leather industry biomass can be utilized in the production of several high-value materials. In addition, leather processing industry biomass also contains fat, which can be converted into a bio-surfactant, and other useful biomaterials. Keratin protein can also be extracted from the hair waste of hides and skins. The increased demand for biomaterials makes the using of leather industry biomass very attractive. From this study, it can be concluded that the conversions of leather processing industry waste to valuable biomaterial can protect the environment, generate additional income for leather industries, and pave way for sustainable and renewable biomaterials production.

Study of Solid Biomass Combustion Modeling Using Openfoam

Biomass is an important renewable energy source that has great potential as a substitute for fossil fuels in the short and medium-term, which has led to the development of various methods for its energy conversion, of which combustion is the most widely used. This process has several environmental advantages compared to traditional energy sources, however, there is still a long way to go in terms of process efficiency and emission reduction. In this context, CFD computational models are a powerful tool that allows to study and improve the performance of combustion systems in a safe, fast and economical way, compared to experimental studies. OpenFoam is one of the most important CFD software currently available, however, there are few works that use it to simulate the combustion of solid biomass. In this work an application of the software in modeling of a biomass boiler fueled by grape marc is reported, this model allows predict important parameters like CO, H2O and velocity fields in a 2D domain.

Nitrogen Gas Adsorption Filter (NgAF) to enhance producer gas quality

Biomass gasification is a thermochemical conversion process of solid biomass into a gaseous fuel called producer gas that can be used to generate power and electricity. The producer gas consists of around 47% of Nitrogen (N2), 24% Carbon Monoxide (CO), 16% Carbon Dioxide (CO2), 12% Hydrogen (H2), and 1% Methane (CH4). However, Nitrogen (N2) content in the producer gas reduces its heating values as N2 acts as a diluent because of the low calorific value (LCV) of gas. This study aims to design a Nitrogen gas filter for capturing nitrogen gas from producer gas to increase the heating value of producer gas as fuel in combustion. The method to increase the heating value of producer gas will increase the number of combustible gases or reduce the composition of non-combustible gases in producer gas. The use of material name zeolite with its microporous structures able to adsorb nitrogen molecules and act as catalysts to chemical reactions. Zeolites 5A have a small pore highly efficient to adsorb nitrogen gas because pore diameter is relatively similar to the size of nitrogen molecules. The quality of the producer gas depends on the design and operating parameters of the zeolite catalyst. Nitrogen Gas Adsorption Filter is a new method that has to be designed to improve the previous producer gas quality. Nitrogen Gas Adsorption Filter consists of a cylindrical shape body packed with crushed zeolites 5A. When this method of adsorption process is applied, the heating value of the producer gas is increased by observing the quantity of blue flame colour produced by NgAF.

A Study of Socio-Economic Impact of Soft Approaches of Climate Adaptation using Changing Fuel Practice in Indoor Air at Rural Sites in India

Majority of India’s rural population depends on biomass burning for cooking and heating purposes on traditional cook stoves called Chullah which results into indoor air pollution. The sampling for this study was carried out in two villages of India viz. Budhwada, Madhya Pradesh (M.P.) and Baggi, Himachal Pradesh (H.P.). Both the regions are significantly different in terms of culture, traditions, topography and daily practices and hence this study helped in understanding the contrast between these regions. The concentrations of carbonaceous aerosols viz. OC (Organic Carbon) and EC (Elemental Carbon) were evaluated for different fuel use in four different houses of each village. Introducing the concept of soft approaches, the residents were asked to bring certain changes in their practices by cooking either with solid biomass or Liquefied Petroleum Gas (LPG) as fuel. The overall average concentration of OC was found to be higher for Budhwada (M.P.) at 124.34 ± 34.68 µg/m3 than at Baggi, (H.P.) with value 105.26 ± 35.63 µg/m3 whereas the reverse was true for the average concentration of EC with value 62.98 ± 20.75 µg/m3 at Baggi, (H.P.) and 55.51 ± 15.51 µg/m3 at Budhwada (M.P.). The average OC and EC concentrations from solid biomass fuel (dung cake) burning at Budhwada (M.P.) was respectively higher by 56.14% and 33.57% as compared to the LPG usage. Similarly, in Baggi (H.P.) village with LPG usage, a significant reduction was observed in OC and EC concentrations (76.69% and 70.10% respectively) when compared with fuelwood burning. House-wise and time-wise variations of carbonaceous aerosols at both the sites confirmed that their concentrations are lower in houses with greater ventilation and higher in cooking times (morning and evening). In Budhwada (M.P.), the concentrations of K+, Ca2+ and SO42- ions decreased significantly from dung cake to LPG use by 67.91%, 76.98% and 51.85% respectively. In Baggi (H.P.), K+ ion concentration was decreased by 63.4% from fuelwood to LPG use. A questionnaire survey conducted on the residents also corroborated the above findings where the residents agreed that LPG use has health benefits over solid biomass fuel usage but the challenges such as supply of LPG into rural interiors, financial feasibility, etc. were of serious concern. Also, changing the contemporary mindset of rural population is a challenging task.

Valorization of Vine Tendrils Resulted from Pruning as Densified Solid Biomass Fuel (Briquettes)

Concerns over the past few decades have focused, more than ever, on finding and implementing efficient, handy, and renewable sources to reduce pollution. Biomass, in general, and biomass from annual vine cuttings, are renewable sources that can be used by a large amount of the population. Biomass densification in the form of briquettes is an efficient method of obtaining a biofuel with the same characteristics as wood. The production of densified material as a briquette consists of sampling, drying naturally, chopping, grinding and briquetting the vine cuttings. The obtained results showed that the size of the briquettes met the requirements imposed by the standard, with a length between 185 mm and 400 mm and a diameter of 58 ± 0.75 mm, the humidity of the briquettes varying between 5.42%, at Sauvignon Blanc and 7.98% for Pinot Noir, while the durability of the briquettes registered minimum values of 98.17% for Muscat Ottonel and a maximum of 99.14% for Feteasca Neagra, and a unit density with values between 1227 kg/m3 for Feteasca Alba and 1389 kg/m3 for Pinot Noir. The conclusions of these experiments are promising, showing that the densification of biomass from vines cuttings qualifies within the standard requirements for obtaining a valuable biofuel.