Hyper-crosslinked polymers with controlled multiscale porosity for effective removal of benzene from cigarette smoke

A series of hyper-crosslinked polymers (HCPs) with connected hierarchical porous structures were synthesized from phenyl-based precursors of benzene (BEN), benzyl alcohol, aniline, biphenyl, and 1,3,5-triphenylbenzene (TPB) via the knitting method. The porous structures of the HCPs were greatly influenced by substituent groups and BEN ring number in the precursors. HCPs prepared from TPB had the largest surface area and pore volume with multiscale porosity. The porous structure of the HCPs could also be adjusted by the crosslinker amount. Insufficient crosslinking led to incomplete pore architecture, while excessive crosslinking resulted in a considerable decrease in the pore volume. With these HCPs as adsorbents, the BEN yield in the cigarette smoke could be largely reduced due to the connected multiscale porosity and π–π aromatic stacking interaction that facilitated the smoke aerosol passing and the small aromatic molecules absorbing, showing great potential of these HCPs as adsorbents for effective removal of BEN from cigarette smoke.

Tracheid dimensions of Norway spruce in uneven-aged stands

Tracheid length and width patterns from pith to bark at a height of 0.6 m in uneven-aged Norway spruce (<i>Picea abies</i> L. (H.) Karst) trees were addressed. The identification of the main factors and a comparison with even-aged stands were also pursued. 96 trees were sampled from experimental stands in Southern Finland. The material encompassed the variation in tracheid properties from early years to silvicultural maturity, i.e. from corewood to outerwood up to a cambial age of 111 years. Data from 39 Norway spruce trees from even-aged stands we utilized for comparison. Models fitted to the data indicated that annual ring widths did not influence mean tracheid dimensions but the latewood proportion showed a significant influence on tracheid dimensions. Tracheids in uneven-aged stands were slightly wider and longer at the base of the stem with a similar tree diameter, cambial age, and annual ring number.

Free vibration and damping analysis of the cylindrical shell partially covered with equidistant multi-ring hard coating based on a unified Jacobi-Ritz method

In this study, the aim was to evaluate the vibration suppression performance of the partially covered equidistant multi-ring hard coating damping treatment for the cylindrical shell structure in aviation power equipment. A continuous rectangular pulse function was presented to describe the local thickness variation of arbitrary coating proportion and arbitrary number of coating rings. A semi-analytical unified solution procedure was established by combining the rectangular pulse function, the generalized Jacobi polynomials, and the Rayleigh-Ritz method. The stiffness coefficient k = 1013 N/m2 and the truncation number N = 8 were found to be large enough to achieve an accurate and efficient solution of the vibration analysis of the shell. The modal loss factor generally increased with the increase of the coating proportion ranging from 0.0 to 1.0 for all the circumferential wave numbers. The modal loss factor increased roughly linear with the coating proportion for all the circumferential wave numbers. And the modal loss factor was increased with the circumferential wave number, and the greater the number of circumferential waves, the greater the rate of change. The increase of the ring number was not always beneficial for vibration reduction of the shell, while the modal loss factor increased roughly linear with the coating proportion. The increased ring number and coating proportion tend more to exhibit an obvious incremental damping effect under larger circumferential wave number.

Ray properties in the stems of Dahurian larch (Larix gmelinii) and Japanese larch (Larix kaempferi)

The radial variation of rays within the stems of Dahurian larch and Japanese larch growing in Korea was studied to obtain valuable information to identify the two species and determine wood quality. Uniseriate ray height, fusiform ray height, ray number, ray spacing, and epithelial cell number were investigated by optical microscopy. The heights of uniseriate and fusiform rays and epithelial cell numbers in Dahurian larch were lower than those in Japanese larch. Dahurian larch wood had greater ray number and ray spacing than Japanese larch wood. In both species, the heights of uniseriate and fusiform rays and epithelial cell number increased with increasing growth ring number but then stabilized from a certain growth ring number. However, ray number and ray spacing decreased with age but were stable toward the bark. There were significant differences in all ray properties between the two species. Furthermore, in both species, the number and spacing of rays showed a significant negative correlation with uniseriate ray height. The relationships between uniseriate and fusiform ray height, and between ray spacing and ray number were significantly positive. In conclusion, the results from this study provide basic information that can be used to identify these species, and the quality indices from ray properties will improve the effective utilization of the two woody species.

Design and Test of a Microdestructive Tree-Ring Measurement System

Analysis of a tree ring is the primary method for determining the growth and age of a tree. In a microdestructive tree-ring measurement system, the tree under test is drilled with a microdrill at a constant rotating speed to detect the difference in density between the early and late wood, thereby realizing a microdestructive measurement of the tree-ring. The measurement system comprises a microdrill with a diameter of 3 mm, mechanical transmission, direct current (DC) servomotor, stepper motor, and control and detection circuit. The DC servomotor and stepper motor realize rotation and translation of the microdrill, respectively, through mechanical transmission. When the microdrill rotates and drills into the tree, the control and detection circuit samples and acquires the armature current of the DC servomotor, which is proportional to the resistance encountered by the drill bit and reflects the change in the density of the tree. The tree-ring number can be obtained by filtering the sampled original signals of the armature current using a finite impulse response (FIR) filtering algorithm. The annual rings of larch and fir tree discs were measured and tested using the designed system. It was observed that the average annual ring measurement accuracy of the larch discs reached 95.28%, while that of the fir discs was 84.16%. The diameter of the drill hole in the trunk was less than 3 mm after measuring the living wood, thereby achieving a microdestructive measurement of the tree-ring.

Anti-Diabetic Activity of 2,3,6-Tribromo-4,5-Dihydroxybenzyl Derivatives from Symphyocladia latiuscula through PTP1B Downregulation and α-Glucosidase Inhibition

The marine alga, Symphyocladia latiuscula (Harvey) Yamada, is a good source of bromophenols with numerous biological activities. This study aims to characterize the anti-diabetic potential of 2,3,6-tribromo-4,5-dihydroxybenzyl derivatives isolated from S. latiuscula via their inhibition of tyrosine phosphatase 1B (PTP1B) and α-glucosidase. Additionally, this study uses in silico modeling and glucose uptake potential analysis in insulin-resistant (IR) HepG2 cells to reveal the mechanism of anti-diabetic activity. This bioassay-guided isolation led to the discovery of three potent bromophenols that act against PTP1B and α-glucosidase: 2,3,6-tribromo-4,5-dihydroxybenzyl alcohol (1), 2,3,6-tribromo-4,5-dihydroxybenzyl methyl ether (2), and bis-(2,3,6-tribromo-4,5-dihydroxybenzyl methyl ether) (3). All compounds inhibited the target enzymes by 50% at concentrations below 10 μM. The activity of 1 and 2 was comparable to ursolic acid (IC50; 8.66 ± 0.82 μM); however, 3 was more potent (IC50; 5.29 ± 0.08 μM) against PTP1B. Interestingly, the activity of 1–3 against α-glucosidase was 30–110 times higher than acarbose (IC50; 212.66 ± 0.35 μM). Again, 3 was the most potent α-glucosidase inhibitor (IC50; 1.92 ± 0.02 μM). Similarly, 1–3 showed concentration-dependent glucose uptake in insulin-resistant HepG2 cells and downregulated PTP1B expression. Enzyme kinetics revealed different modes of inhibition. In silico molecular docking simulations demonstrated the importance of the 7–OH group for H-bond formation and bromine/phenyl ring number for halogen-bond interactions. These results suggest that bromophenols from S. latiuscula, especially highly brominated 3, are inhibitors of PTP1B and α-glucosidase, enhance insulin sensitivity and glucose uptake, and may represent a novel class of anti-diabetic drugs.

Molecular Simulation of Naphthalene, Phenanthrene, and Pyrene Adsorption on MCM-41

The adsorption of three typical polycyclic aromatic hydrocarbons (PAHs), naphthalene, phenanthrene, and pyrene with different ring numbers, on a common mesoporous material (MCM-41) was simulated based on a well-validated model. The adsorption equilibriums (isotherms), states (angle distributions and density profiles), and interactions (radial distribution functions) of three PAHs within the mesopores were studied in detail. The results show that the simulated isotherms agreed with previous experimental results. Each of the PAHs with flat molecules showed an adsorption configuration that was parallel to the surface of the pore, in the following order according to the degree of arrangement: pyrene (Pyr) > phenanthrene (Phe) > naphthalene (Nap). In terms of the interaction forces, there were no hydrogen bonds or other strong polar forces between the PAHs and MCM-41, and the O–H bond on the adsorbent surface had a unique angle in relation to the PAH molecular plane. The polarities of different H atoms on the PAHs were roughly the same, while those of the C atoms on the PAHs decreased from the molecular centers to the edges. The increasing area of the π-electron plane on the PAHs with the increasing ring number could lead to stronger adsorption interactions, and thus a shorter distance between the adsorbate and the adsorbent.